micropore structure,chiral sodium zincophosphate,template,chiral control,"/> 微孔结构手性磷酸锌钠的制备及影响手性结构的研究
无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (12): 41-.

• 论文 • 上一篇    下一篇

微孔结构手性磷酸锌钠的制备及影响手性结构的研究

孙雅博,李 璟,赵志才,何晓云,田克情   

  1. 河北化工医药职业技术学院化学与环境工程系,河北石家庄 050026
  • 出版日期:2014-12-10 发布日期:2014-12-08

Synthesis of chiral sodium zincophosphate with micropore structure and study on effect of chiral structure

 SUN  Ya-Bo, LI   Jing, ZHAO  Zhi-Cai, HE  Xiao-Yun, TIAN  Ke-Qing   

  1. Department of Chemical and Environment Engineering,Hebei Chemical and Pharmaceutical College,Shijiazhuang 050026,China
  • Online:2014-12-10 Published:2014-12-08

摘要: 以十二水磷酸钠和七水硫酸锌为原料,以聚乙二醇-400(PEG-400)为模板剂,采用室温固相法得到具有微孔结构的P6122 空间群的手性磷酸锌钠。考察了磷与锌物质的量比、晶化时间及加入不同模板剂对产物手性的影响。得到的产物用X射线衍射(XRD)、扫描电镜(SEM)、傅里叶变换红外分光光度计(IR)对晶体的形貌和组成进行表征。实验结果表明:磷与锌物质的量比以及模板剂的结构是控制手性产物的关键因素,而晶化时间只影响晶体的结晶度。

关键词: 微孔结构, 手性磷酸锌钠, 模板剂, 手性控制

Abstract: Chiral sodium zincophosphate with  micropore structure and P6122 space group was prepared by room temperature solid phase method with Na3PO4·12H2O and ZnSO4·7H2O as raw materials and with PEG-400 as template.The influence of amount-of-substance ratio of P/Zn,crystallization time,and different templates on the chiral performance of product was investigated.The morphology and composition of product were characterized by XRD,SEM,and IR.Experimental results indicated that the amount-of-substance ratio of P/Zn and template′s structure were the key factors to control the chiral product,and the crystallization time only influenced the crystallization degree.

Key words: micropore structure')">

micropore structure, chiral sodium zincophosphate, template, chiral control