无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (8): 5-.

• 论文 • 上一篇    下一篇

酸碱法生产活性氧化锌经济性差异对比分析

蔡建国   

  1. 江苏银茂控股集团有限公司,江苏南京 210033
  • 出版日期:2013-08-10 发布日期:2013-08-14

Comparative analysis on economical difference of activated zinc oxide production by acid/base methods

 CAI  Jian-Guo   

  1. Jiangsu Yinmao Holding Group Co.,Ltd.,Nanjing 210033,China
  • Online:2013-08-10 Published:2013-08-14

摘要: 通过对4种生产活性氧化锌工艺,即酸法的加纯碱(Na2CO3)法和加碳酸氢氨(NH4HCO3)法,氨浸法的加热蒸氨让氨挥发法和通入二氧化碳碳化法的差异部分的经济性进行分析,对比发现碱法总体优于酸法,其中以氨浸蒸氨法经济性最佳。酸法不仅存在浸出剂和合成剂消耗成本高,而且酸法生产活性氧化锌会产生大量的废水,废水处理成本高于回收产品的收入,经济性较差。因此推荐用氨浸蒸氨法生产活性氧化锌,不仅经济而且环保。

关键词: 活性氧化锌, 浸出成本, 合成成本, 废水处理成本, 回收产品收入

Abstract:  By analyzing the economical efficiency of the differences of four methods of manufacturing activated zinc oxide,which are the acid method of adding soda(Na2CO3),the acid method of adding ammonium hydrogen carbonate (NH4HCO3),the ammonia leaching-ammonia distillation method(evaporating ammonia by heating),and carbonization method(by inletting carbon dioxide),it′s found that the alkali methods are superior to the acid methods,and the ammonia leaching-ammonia distillation method is the most cost-effective one.Acid methods have higher consumption costs of leaching reagent and synthesizing agent.Furthermore,the acid methods produce a large amount of wastewater during the manufacture process of activated zinc oxide.Since the treatment cost of wastewater is higher than the revenue of product recovery,their economical efficiency is poor. In conclusion,it is recommended to use the ammonia leaching-ammonia distillation method to manufacture activated zinc oxide,because it is not only economical,but also environmentally friendly.

Key words: activated zinc oxide, leaching cost, synthesis cost, wastewater treatment cost, product recovery

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