无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (4): 38-.

• 论文 • 上一篇    下一篇

掺烧废硫酸亚铁制硫酸技术经济的讨论

唐文骞,杨同莲   

  1. 中海油山东化学工程有限责任公司,山东济南  250013
  • 出版日期:2013-04-10 发布日期:2013-04-07

Techno-economic discussion on roasting pyrite blended with waste ferrous sulfate to produce sulfuric acid

 TANG  Wen-Qian, YANG  Tong-Lian   

  1. CNOOC Shandong Chemical Engineering Co.,Ltd.,Jinan 250013, China
  • Online:2013-04-10 Published:2013-04-07

摘要: 硫酸法钛白配有废酸浓缩工序,废酸浓缩产生的废硫酸亚铁,绝大部分企业采用石灰中和处理,既造成资源浪费,又增加处理费用。介绍了采用掺烧新途径能使废硫酸亚铁中硫铁资源得到充分利用,并且取得显著的经济效益,以10万t/a钛白匹配30万t/a硫酸为例,年节省硫铁矿4.69万t,创产值2 292万元。

关键词: 废硫酸亚铁, 掺烧制酸, 一水硫酸亚铁, 七水硫酸亚铁

Abstract: There is a waste acid concentration process in the production of titanium dioxide with sulfuric acid process.The waste ferrous sulfate produced from the waste concentrated acid,was neutralized with lime by the most of enterprises.This disposal method not only wasted resources,but also increased treating cost. Introduced a new blending roasting way to fully use the sulfur and iron resources in the waste ferrous sulfate.Remarkable economic results have been achieved,and taking a 100 000 t/a titanium dioxide plant matching 300 000 t/a sulfuric acid as an example,46 900 t pyrite could be saved  annually,yielding 22 920 000 yuan(RMB) of output value.

Key words: waste ferrous sulfate, blending roasting to produce acid, ferrous sulfate monohydrate, ferrous sulfate heptahydrate

中图分类号: