无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (4): 18-.

• 论文 • 上一篇    下一篇

P(BA-FA)原位聚合法改性重质碳酸钙微粒的研究

周国永1,曾一文1,黄志强1,汤 泉1,成 琳2   

  1. 1.贺州学院化学与生物工程学院,广西贺州 542899;2.贺州学院学工处
  • 出版日期:2013-04-10 发布日期:2013-04-07

Study on  heavy calcium carbonate particles modified by P(BA- FA) in situ polymerization

Zhou Guoyong1,Zeng Yiwen1,Huang Zhiqiang1,Tang Quan1,Cheng Lin2   

  1. 1.School of Chemical and Biological Engineering,Hezhou University,Hezhou 542899,China;
    2.Department of the Students′ Affairs,Hezhou University
  • Online:2013-04-10 Published:2013-04-07

摘要: 采用单因素法考察了改性剂聚(丙烯酸丁酯-反丁烯二酸)[P(BA-FA)]对重质碳酸钙(重钙)微粒进行表面改性的工艺条件,重点考察了P(BA-FA)改性剂中偶氮二异丁腈(AIBN)用量和叔十二碳硫醇(TDDM)用量对改性效果的影响,并测定改性前后重钙微粒的吸油值、黏度、沉降体积。通过SEM电镜观察发现改性剂对重钙的包覆效果明显,改性后的重钙微粒吸油值、黏度和沉降体积均比改性前有明显降低。较佳的改性条件为每5 g重钙微粒AIBN用量为0.047 6 g,TDDM用量为0.01 mL,在此条件下沉降体积为2.921 mL/g,吸油值为0.359 0 mL/g,黏度为33 mPa·s。

关键词: P(BA-FA), 重钙微粒, 表面改性, 单因素

Abstract: The technological conditions for surface modification of heavy calcium carbonate particles with poly(butyl acrylate-fumaric acid)[P(BA-FA)]as modifier were investigated by single-factor method.Influences of the dosages of AIBNand TDDM in P(BA-FA) on the modification effect were studied emphatically.The oil absorption value,viscosity,and sedimenta- tion volume of heavy calcium carbonate particles before and after the modification were determined.SEM results showed that,the modifier had a good doping effect on the heavy calcium carbonate,and the oil absorption value,viscosity,and sedimentation volume of the modified particles were all significantly reduced than those that unmodified.The optimum modification conditions were:AIBN amount was 0.047 6 g per 5 g heavy calcium carbonate,and the amount of TDDM was 0.01 mL.Under these conditions,the settlement volume,oil absorption value,and viscosity were 2.921 mL/g,0.359 0 mL/g,and 33 mPa·s,respectively.

Key words: P(BA-FA), heavy calcium carbonate particles, surface modification, single factor

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