无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2013, Vol. 45 ›› Issue (12): 17-.

• 论文 • 上一篇    下一篇

马海盐湖低品位钾矿溶采卤水 蒸发过程相图分析及计算

李建国1,关云山1,戴 杰2,余明祥3,程芳琴4   

  1. 1.青海大学化工学院,青海西宁810016;2.青海盐湖工业集团股份有限公司;
    3.青海中信国安科技发展有限公司;4.山西大学资源与环境工程研究所
  • 出版日期:2013-12-10 发布日期:2013-12-09

Phase diagram analysis and computation for the process of brine evaporation of dissolution mining of low grade solid potassium deposit in Mahai salt lake

Li Jianguo1,Guan Yunshan1,Dai Jie2,Yu Mingxiang3,Cheng Fangqin1   

  1. 1.School of Chemical Engineering,Qinghai University,Xining 810016,China;2.Qinghai Salt Lake Industry Group Co,,Ltd.;
    3.Qinghai CITIC Guoan Technology Co.,Ltd.;4.Institute of Resources and Environment Engineering,Shanxi University
  • Online:2013-12-10 Published:2013-12-09

摘要: 依据K+,Na+,Mg2+∥Cl-,SO42--H2O体系15 ℃介稳相图,对青海马海盐湖低品位钾矿溶采卤水进行了等温蒸发过程相图分析,揭示了该盐湖卤水蒸发过程中盐类富集行为和析出规律。依据相图通过计算得出:该盐湖卤水在等温蒸发时应采取分段蒸发,且给出了各个蒸发结晶池终了时刻应控制的母液组成,为该盐湖卤水的综合开发利用提供了理论依据。

关键词: 马海盐湖, 溶采卤水, 相图分析及计算

Abstract: According to the metastable phase diagram of K+,Na+,Mg2+∥Cl-,SO42--H2O system at 15 ℃,the isothermal evaporation process of the brine of dissolution mining of the low grade solid potassium deposit from Mahai salt lake in Qinghai province was analyzed,and the enrichment behaviors and precipitation rules of salts from brine in process of evaporation were discovered.Results showed that a process of stage evaporation should be applied;and the compositions of mother liquor in each crystalline pond at terminal point were also given.This work provided theoretical foundation for the comprehensive utilization of Mahai salt lake brine in Qinghai province.

Key words: Mahai salt lake, dissolved brine, phase diagram analysis and computation

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