无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2012, Vol. 44 ›› Issue (9): 48-.

• 论文 • 上一篇    下一篇

低品位菱镁矿与硅石制备镁橄榄石的研究

王 闯,罗旭东,曲殿利,张国栋,钟鑫宇   

  1. 辽宁科技大学高温材料与镁资源工程学院,辽宁鞍山 114051
  • 发布日期:2012-09-11

Preparation of forsterite materials from low-grade magnesit and natural silica

 WANG   Chuang, LUO  Xu-Dong, QU  Dian-Li, ZHANG  Guo-Dong, ZHONG  Xin-Yu   

  1. School of High Temperature Materials and Magnesium Resource Engineering,Liaoning University of
    Science and Technology,Anshan 114051,China
  • Published:2012-09-11

摘要: 以低品位菱镁矿与天然硅石为原料制备镁橄榄石材料。研究了低品位菱镁矿轻烧氧化镁粉引入量对制备的镁橄榄石材料中镁橄榄石的晶胞常数、微观结构及常温性能的影响。用X射线衍射(XRD)和扫描电镜(SEM)对试样的相组成和显微结构进行了研究。利用X′ pert plus软件对试样中镁橄榄石相的晶胞常数进行分析。结构与性能分析结果表明:低品位菱镁矿中氧化镁与天然硅石中二氧化硅在高温条件下通过固相反应可以制备出以镁橄榄石为主晶相的镁橄榄石材料。随着低品位菱镁矿轻烧氧化镁粉引入量的增加,镁橄榄石材料中镁橄榄石相的晶胞常数和晶胞体积有增加趋势。同时,随着方镁石相在镁橄榄石材料中的脱溶作用,镁橄榄石材料的体积密度和强度逐渐降低,显气孔率和吸水率逐渐增加。

关键词: 低品位菱镁矿, 硅石, 镁橄榄石, 固相反应

Abstract: Forsterite material was prepared with low-grade magnesite and natural silica as raw materials.Effect of the adoption amount of light calcined magnesia powder from low-grade magnesite on lattice constant,microstructure,and room temperature performance of forsterite material was studied.XRD and SEM were used to characterize the sample′s phase composition and microstructure.The lattice constant of the forsterite phase in the sample was analyzed by X′Pert plus software. Structure and properties analysis results showed,forsterite material with forsterite as the main crystal phase could be prepared through solid reaction at high temperature between magnesia in low-grade magnesite and silica from natural silica.With the increase of light calcined magnesia powder from low-grade magnesite,the lattice constant and lattice volume of forsterite phase in the forsterite material presented increasing trend.Meanwhile,the bulk density and cold crush strength of the samples were gradually on the decline, yet the apparent porosity and water absorption of the samples were gradually increasing due to the periclase′s desolvation role in the forsterite material.

Key words: low-grade magnesite, natural silica, forsterite, solid reaction

中图分类号: