无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2012, Vol. 44 ›› Issue (7): 41-.

• 论文 • 上一篇    下一篇

尾矿酸浸液除硅以及制备高纯铁红的研究

廖 攀1,陈学安1,常新安1,肖卫强2,王少华3   

  1. 1.北京工业大学材料科学与工程学院,北京100124;2.北京工业大学固体微结构与性能研究所;3.金川集团公司化工厂
  • 发布日期:2012-07-11

Study on removal of silicon and preparation of high purity ferric oxide red from acid leaching filtrate of tailings

Liao Pan1,Chen Xuean1,Chang Xin′an1,Xiao Weiqiang2,Wang Shaohua3   

  1. 1.School of Materials Science and Engineering,Beijing University of Technology,Beijing 100124,China;2.Institute of
    Microstructure and Property of Advanced Materials,Beijing University of Technology;3.Chemical Plant of Jinchuan Group Co.,Ltd.
  • Published:2012-07-11

摘要: 金川公司尾矿酸浸液中除含有较高含量的铁之外,还含有一定量的杂质硅。以氧化钙为中和剂,聚丙烯酰胺为絮凝剂,通过正交设计与实验,得出了从该酸浸液中除硅的较佳工艺条件;随后,以氧化镁为中和剂,空气和双氧水为氧化剂,将除硅后滤液在85 ℃搅拌加热,制得针铁矿沉淀;最后将沉淀在800 ℃煅烧2 h并经过5%稀硝酸洗涤得到了高纯铁红,其主成分质量分数为99.2%,符合HG/T 2574—2009工业氧化铁国家标准。

关键词: 尾矿酸浸液, 絮凝, 除硅, 铁红

Abstract: Acid leaching filtrate of tailings from Jinchuan Company contains not only large amount of Fe2+ but also small amount of Si4+.Using CaO as neutralizer and polyacrylamide as flocculation reagent,the optimum technological conditions of removal of silicon from the acid leaching filtrate were obtained by orthogonal experiments.After silicon was removed,goethite was prepared under the conditions of 85 ℃ and stirring by using MgO as neutralizer and air together with H2O2 as oxidant.Finally the high purity ferric oxide red(α-Fe2O3) was prepared by calcining goethite at calcining temperature of 800 ℃ for 2 h followed by washing with 5% dilute HNO3. The mass fraction of main content of the as-prepared iron red was 99.2%,which could be classified as the qualified product according to the national standard of HG/T 2574—2009.

Key words: acid leaching filtrate of tailings, flocculation, removal of silicon, ferric oxide red

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