无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2012, Vol. 44 ›› Issue (4): 35-.

• 论文 • 上一篇    下一篇

用弗雷德盐去除土壤淋洗液中的镉

张珍明1,章兴华2,陆 洋3,周丽芸4,舒海霞3,段 琴3,林昌虎5,何腾兵1   

  1. 1.贵州大学农学院,贵州贵阳550025;2.贵州省黔新企业集团有限公司;3.贵州省理化检测分析研究中心;
    4.贵州省环保局;5.贵州科学院
  • 发布日期:2012-04-06

Removal of cadmium from soil leaching liquid by Friedel′s salts

Zhang Zhenming1,Zhang Xinghua2,Lu Yang3,Zhou Liyun4,Shu Haixia3,Duan Qin3,Lin Changhu5,He Tengbing1   

  1. 1.School of Agriculture,Guizhou University,Guiyang 550025,China;2.Guizhou Qian-Xin Enterprise Group Limited Company;
    3.Guizhou Province Research Center of Physical and Chemical Testing;4.Guizhou Administrative Bureau of
    Environment Protection;5.Guizhou Academy of Sciences
  • Published:2012-04-06

摘要: 用模拟酸雨(pH=4)对高镉土壤(全镉为10.590 mg/kg)进行浸取。实验结果表明,模拟酸雨对土壤中镉的浸出率仅为其总镉的1%左右,但浸出液中镉的含量(0.108 mg/L)仍远高出GB 3838—2002地表水Ⅴ类水质的要求,也高于GB 18918—2002城镇污水处理厂污染物排放标准(<0.01 mg/L),必须予以处理。弗雷德盐是以聚合铝为主要原料人工合成的层状双羟合物,它能以同晶取代、吸附或共沉淀形式去除水体中的重金属镉离子。研究表明,土壤浸出液中大量的Al3+、Fe3+会影响弗雷德盐对淋洗液中镉的去除,但处理后的镉含量仍可达到GB 18918—2002城镇污水处理厂污染物排放标准。

关键词: 弗雷德盐, 酸雨, 土壤淋洗, 浸镉, 除镉

Abstract: Simulated acid rain (pH=4) was taken to leach high-cadmium contained soil (total cadmium content is 10.590 mg/kg).Results showed that the simulated acid rain′s leaching rate of cadmium from soil was only about 1% of total cadmium.But the content (0.108 mg/L) of cadmium in leaching solution was still much higher than allowable ejection wastewater standards of GB 3838—2002 and GB 18918—2002( <0.01 mg/L).Therefore it must be treated.Friedel′s salts is an artificially synthesized layered double-hydroxylated complex with polyaluminum as raw material.It can remove the ions of cadmium in leaching solution with the forms of isomorphous substitution,adsorption,or coprecipitation.Results showed large amount of Al3+ and Fe3+ will affact the Friedel′s salt′s removing effect of cadmium in leaching solution.However,the cadmium content in the treated leaching solution can still reach the town sewage treatment plant emission standard of GB 18918—2002.

Key words: Friedel&prime, s salts;acid rain;soil flushing;leaching of cadmium;removal of cadmium

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