无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2012, Vol. 44 ›› Issue (10): 44-.

• 论文 • 上一篇    下一篇

碳酸锶废渣酸浸尾气的处理研究

李玉龙1, 2,王树轩1,李 波1,李 宁1   

  1. 1.中国科学院青海盐湖研究所, 青海西宁810008; 2. 中国科学院研究生院
  • 出版日期:2012-10-10 发布日期:2012-10-12

Research on treating tail gas in strontium carbonate residue leaching process

Li Yulong1, 2,Wang Shuxuan1,Li Bo1,Li Ning1   

  1. 1.Qinghai Institute of Salt Lakes,Chinese Academy of Science,Xining 810008,China;
    2.Graduated University,Chinese Academy of Science
  • Online:2012-10-10 Published:2012-10-12

摘要: 将酸浸碳酸锶废渣时逸出的硫化氢气体和空气通入硝酸铁溶液中,硫化氢被氧化得到硫磺,硝酸铁溶液可重复使用。通过实验研究确定了较优实验条件:硝酸铁浓度为0.5 mol/L,实验温度为30 ℃,所得硫磺纯度为99.38%,每得到1 g硫磺时硝酸铁损失量(以Fe2O3计)为0.013 7 g。该方法具有条件容易控制、工艺流程简单等优点,适用于碳酸锶废渣酸浸过程中硫化氢气体的处理。

关键词: 碳酸锶废渣, 硫化氢, 硝酸铁, 选择性氧化

Abstract: Hydrogen sulfide was oxidized to sulfur selectively when the hydrogen sulfide,which escaped from acid leaching process of strontium carbonate residue,and air were absorbed by ferric nitrate solution.Ferric nitrate solution could be reused. After experiments,the preferable conditions were obtained:the concentration of ferric nitrate was 0.5 mol/L and temperature was 30 ℃.Under those conditions,the purity of sulfur was 99.38%,for per gram sulfur,the loss amount of ferric nitrate (calculated as Fe2O3) was 0.013 7 g.Because of simple process and easily-controllable conditions,this is a promising way to deal with hydrogen sulfide in acid leaching process of strontium carbonate residue.

Key words: strontium carbonate residue, hydrogen sulfide, ferric nitrate, selective oxidation

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