无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (4): 27-.

• 论文 • 上一篇    下一篇

镧对碳化硅超细粉合成温度与粒度的影响

龙海波1,张宁1,侯晶2,梁斌1   

  1. 1.沈阳大学辽宁省先进材料制备技术重点实验室,辽宁沈阳 110044;2.辽宁东联工程造价咨询事务所有限责任公司
  • 发布日期:2011-04-19

Effect of lanthanum on synthesis temperature and particle size of ultrafine SiC

Long Haibo1,Zhang Ning1,Hou Jing2,Liang Bin1   

  1. 1.Liaoning Key Laboratory of Advanced Materials Technology,Shenyang University, Shenyang 110044,China;2.Liaoning Donglian Project Cost Consultation Institute Co.,Ltd.
  • Published:2011-04-19

摘要: 众多研究表明,提高反应物起始原料的均匀混合程度、添加适量的添加剂是改善碳热还原法制备碳化硅超细粉体的有效途径。由于稀土元素对众多的化学反应都能起到有效的促进作用,于是,以纳米二氧化硅和活性炭为起始原料,以稀土镧为添加剂,采用碳热还原法制备碳化硅超细粉体,并借助X射线衍射仪和激光粒度仪分别对合成的粉体进行物相和粒度分析,实验结果表明:添加一定量的稀土镧有助于降低碳化硅超细粉的合成温度及粉体粒度。

关键词: 碳化硅, 稀土, 碳热还原反应

Abstract: Many researches indicated that improving the homogeneous mixing extent of the starting materials and adding appropriate additives were effective ways to improve the preparation of ultrafine SiC by carbothermal reduction reaction.Because rare earth elements can play an effective role in promoting a large number of chemical reactions,ultrafine SiC powder was prepared by carbonthermal reduction method with nano-sized SiO2 and activated carbon as starting materials and with rare earth lanthanum as additive.Phase and particle size of the prepared powder were analyzed by XRD and ZetaPALS.Experiment results showed that the reaction temperature and particle size were both reduced by adding some rare earth lanthanum to the mixture of SiO2 and activated carbon.

Key words: SiC, rare earths, carbothermal reduction reaction

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