无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (2): 30-.

• 论文 • 上一篇    下一篇

铝矾土制备活性氧化铝掺合料的研究

王晓燕,候桂芹,吕朝霞   

  1. 河北联合大学轻工学院,河北唐山 063000
  • 发布日期:2011-04-19

Preparation of activated alumina admixture by bauxite

Wang Xiaoyan,Hou Guiqin, Lü Zhaoxia   

  1. School of Light Industry,Hebei United University,Tangshan 063000,China
  • Published:2011-04-19

摘要: 研究了煅烧铝矾土制备活性氧化铝掺合料的过程。结合产物种类、结晶状态和比表面积,研究煅烧温度和煅烧时间对氧化铝活性的影响。采用XRD检测煅烧后铝矾土产物的种类及结晶状态,用激光粒度仪对产品进行比表面积的测定,并通过快速砂浆棒法检测煅烧所得活性掺合料对碱骨料膨胀反应的抑制效果。结果表明,获得活性氧化铝掺合料的最佳煅烧温度和煅烧时间分别为500 ℃和1.0 h,在此条件下制备的活性氧化铝掺合料对碱骨料膨胀反应的抑制效果较好,掺加质量分数为30%的活性氧化铝掺合料能使砂浆棒养护14 d的膨胀率从0.32%降至0.087%,其膨胀率低于0.1%,已经被控制在安全范围内。

关键词: 铝矾土, 煅烧条件, 活性氧化铝掺合料

Abstract: Preparation process of activated alumina admixture by calcining bauxite was studied.Combining with the species of product,crystalline state,and specific surface area,the effects of calcination temperature,and time on activity of Al2O3 were studied.Species and crystalline state of calcined product were detected by XRD.Specific surface area was detected by laser particle size analyzer.Inhibition effect of the obtained alumina admixture on alkali-aggregate expansion reaction was examined by accelerated mortar bar test (AMBT).Results showed that the best calcination temperature and time were 500 ℃ and 1.0 h,respectively.Inhibition effect of the obtained alumina admixture under those conditions on alkali-aggregate expansion reaction was the best.Activated alumina admixture with mass fraction of 30% could reduce the expansion rate of mortar bar of 14 d from 0.32% to 0.087% and the expansion rate was lower than 0.1% and had been controlled within the safe range.

Key words: bauxite, calcination condition, activated alumina admixture

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