无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (12): 53-.

• 论文 • 上一篇    下一篇

硝酸磷肥生产中酸不溶物的絮凝分离实验研究

赵中义1,张翔1,王洪飞1,周俊波1,张凌云2   

  1. 1.北京化工大学机电工程学院,北京 100029;2.山西天脊煤化工集团股份有限公司
  • 发布日期:2011-12-06

Experimental study on flocculated separation of acid-insoluble from nitrophosphate

Zhao Zhongyi1,Zhang Xiang1,Wang Hongfei1,Zhou Junbo1,Zhang Lingyun2   

  1. 1.School of Mechanical and Electrical Engineering,Beijing University of Chemical Technology,Beijing 100029,China;2.Shanxi Tianji Coal Chemical Industry Group Co.,Ltd.
  • Published:2011-12-06

摘要: 硝酸磷肥生产过程中产生的酸不溶物会给生产设备带来严重磨蚀,酸不溶物也易在设备和管道中沉积,造成堵塞。目前硝酸磷肥生产中的酸不溶物一般采用机械方法分离,但去除率不高,只能达到20%左右。采用絮凝沉降的方法对酸不溶物进行絮凝分离实验研究,通过对15种絮凝剂进行优选实验,筛选出沉降效果较好的4种絮凝剂,针对这4种絮凝剂进一步确定酸解液中絮凝剂的最佳用量为50 g/m3,并且絮凝沉降对酸不溶物的去除率达到90%以上。该方法可以简化工艺过程,节省成本,为硝酸磷肥生产中酸不溶物的分离开辟出一条新途径。

关键词: 酸不溶物, 絮凝剂, 絮凝分离

Abstract: Acid-insolubles often lead to serious erosion to equipment in the production of nitrophosphate.Besides,they frequently deposits in the equipment and pipelines and causes blockage.Presently,the acid-insolubles in nitrophosphate are generally separated by mechanical methods,by which,however,the removal percentage is remarkably low and only reaches about 20%.Therefore,flocculation method was adopted in the separation of acid-insolubles.Four flocculants with good deformation efficiencies were selected from 15 flocculants by optimization experiments.Experimental results showed that the optimal dosage for these four flocculants was 50 g/m3,and the removal percentage of the acid-insolubles reached more than 90%.The method can simplify the process,save the cost and will open up a new way for separation of acid-insolubles in the production of nitrophosphate.

Key words: acid-insolubles, flocculants, flocculated separation

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