无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (11): 43-.

• 论文 • 上一篇    下一篇

三段氨吸法回收硫酸尾气副产固体亚硫酸铵

吴雨龙1,周超2   

  1. 1.武汉软件工程职业学院环境与生化工程系,湖北武汉 430205;2.武汉中东化工有限公司
  • 发布日期:2011-11-09

Co-production of solid ammonium sulfite by three-stage absorption of SO2 in sulphuric acid tail gas with ammonia

Wu Yulong1,Zhou Chao2   

  1. 1.Department of Environmental and Bio-Chemical Engineering,Wuhan Vocational College of Software and Engineering,Wuhan 430205,China;2.Wuhan Zhongdong Chemical Engineering Limited Corporation
  • Published:2011-11-09

摘要: 接触法硫铁矿制酸工艺排出的尾气中二氧化硫一般为0.2%~0.5%(体积分数,下同),酸雾一般为0.004%~0.008%,目前中国普遍采用一转一吸或两转两吸流程来吸收硫酸尾气,可使二氧化硫含量降至0.01%~0.1%。但随着硫酸产能的增大或企业扩产,二氧化硫排放总量仍然大大超过环保部门的控制要求。结合武汉中东化工有限公司硫酸车间的实际生产情况,总结了采取三段氨吸法处理硫酸尾气的技术改造。

关键词: 硫酸, 尾气, 三段氨吸法, 亚硫酸铵

Abstract: The offgas discharged during the preparation of acids from pyrite by contacting method contains generally 0.2%~0.5% (volume fraction,same below) SO2 and 0.004%~0.008% acid mist.At present,‘one conversion and one absorption’ process or ‘two conversions and two absorptions’ process are commonly used in China to absorb sulphuric acid tail gas such that the SO2 content thereof is as low as about 0.01%~0.1%.With the increase of sulphuric acid producti-vityor the capacity expansion of enterprises,however,the total emission of SO2 still overpasses significantly the requirement of Environmental Protection Department.Technical improvement on treating sulphuric acid tail gas by three-stage amine absorption process was summarized,based on the practice carried out in the sulphuric acid workshop of Zhongdong Chemical Engineering Limited Corporation of Wuhan.

Key words:  , sulphuric acid, tail gas, three-stage amine absorption process, ammonium sulphite

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