无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (11): 37-.

• 论文 • 上一篇    下一篇

以高岭土和铝土矿制备4A沸石的研究

庞娟,朱岳麟,常增花   

  1. 北京航空航天大学材料科学与工程学院,空间先进材料与服役教育部重点实验室,北京 100191
  • 发布日期:2011-11-09

Study on preparation of 4A zeolite from kaolin and bauxite

 PANG  Juan, ZHU  Yue-Lin, CHANG  Zeng-Hua   

  1. Key Laboratory of  Space Advanced Materials and Serving,Ministry of Education,School of Material Science and Engineering,Beijing University of Aeronautics and Astronautics,Beijing 100191,China
  • Published:2011-11-09

摘要: 以高岭土和铝土矿为原料,经碱熔焙烧活化、水热合成制备了4A沸石。利用单因素实验,探索了活化焙烧温度和时间对合成4A沸石的影响;利用正交优选实验,考察了水热合成过程中胶化温度、胶化时间、晶化温度和晶化时间对合成4A沸石的影响。结果表明:活化焙烧的最佳温度为600 ℃、时间为2 h;水热法合成4A沸石的最佳工艺参数是胶化温度为75 ℃、胶化时间为4 h、晶化温度为95 ℃、晶化时间为4 h。利用X射线衍射(XRD)、场发射扫描电子显微镜(FESEM)和激光衍射散射式粒度分布测定仪对产物进行了分析。

关键词: 4A沸石, 活化焙烧, 高岭土, 铝土矿

Abstract: With kaolin and bauxite as raw materials,4A zeolite was synthesized under hydrothermal conditions after alkaline fusion and activated roasting.The influence of roasting activation temperature and time on synthesis of 4A zeolite was inspected by using single factor experiment.And the effect of gel temperature,gel time,crystallization temperature,and crystallization time on hydrothermal synthesis process was investigated by orthogonal optimization experiment.Results showed that the optimal roasting activation temperature was 600 ℃ and time was 2 h;the optimal hydrothermal parameters of 4A zeolite were as follows: gel temperature was 75 ℃,gel time was 4 h,crystallization temperature was 95 ℃,and crystallization time was 4 h.XRD,FESEM,and laser diffraction scattering type of particle size distribution tester were used for analyzing the product. 

Key words: 4A zeolite, activated roasting, kaolin, bauxite

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