无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (10): 12-.

• 论文 • 上一篇    下一篇

纳米氧化物与染土协同抗紫外性能研究

王志锋1,张艳辉2,余夙2,鲁闯1,李建伟3   

  1. 1. 中国兵器科学研究院宁波分院,浙江宁波 315103;2. 浙江大学宁波理工学院;3. 宁波天韵草艺有限公司
  • 发布日期:2011-10-19

Study on UV-shielding of nano-oxides and dyed earth

Wang Zhifeng1,Zhang Yanhui2,Yu Su2,Lu Chuang1,Li Jianwei3   

  1. 1.Ningbo Branch of Academy of Ordnance Science,Ningbo 315103,China;2.Ningbo Institute of Technology,Zhejiang University;3.Ningbo Tianyun Straw Art Co.,Ltd.
  • Published:2011-10-19

摘要: 通过研究不同纳米氧化物/染土体系、不同晶型纳米二氧化钛/染土体系以及不同比例的锐钛矿型纳米二氧化钛/染土体系等在紫外-可见光区的透射率,找到具有优异抗紫外性能的纳米氧化物/染土体系,以提高蔺草染土固色质量及保色效果。实验结果表明,添加具有抗紫外性能的纳米氧化物均有利于提高染泥的固色效果;在不同纳米氧化物与染土比例一定情况下,锐钛矿型二氧化钛/染土体系的透过率最低,抗紫外性能最好;无论是对于锐钛矿型纳米二氧化钛/染土体系,还是锐钛矿和金红石型两种晶型的纳米二氧化钛与染土的混合体系,随着体系中纳米二氧化钛含量的减少,体系的抗紫外性能降低;在纳米二氧化钛与染土比例一定情况下,不同晶型的纳米二氧化钛在不同波段的抗紫外性能也有所不同。

关键词: 纳米氧化物, 染土, 可见-紫外光区, 抗紫外性

Abstract: Transmissivities in ultraviolet-visible range of systems,such as different nano-oxides/dyed earth,nano-TiO2 with different crystal forms/dyed earth and different proportional of anatase nano-TiO2/dyed earth were studied in order to obtain the nano-oxides/dyed earth system with good UV-shielding,so that the effectiveness of color fixation and retention can been improved in the systems.Experimental results showed that adding nano-oxides with UV-shielding to dyed earth was beneficial to the color fixation;the transimissivity of the system of anatase nano-TiO2/dyed earth was the lowest,and UV-shielding was the best when mix ratio of different nano-oxides to dyed earth kept unchanged;with nano-TiO2 content decreased,the system′s UV-shielding behavior would be decreased,no matter the system was anatase nano-TiO2/dyed earth or the system was anatase and rutile nano-TiO2 mixture/dyed earth;under the certain proportion of nano-TiO2 and dyed earth,UV-shielding behavior of different nano-TiO2 with different crystal forms was also different in different bands.

Key words: nano-oxides, dyed earth, ultraviolet-visible range, UV-shielding ,  

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