无机盐工业 ›› 2023, Vol. 55 ›› Issue (7): 89-96.doi: 10.19964/j.issn.1006-4990.2022-0598
收稿日期:
2022-10-10
出版日期:
2023-07-10
发布日期:
2023-07-13
作者简介:
张鹏(1982— ),男,博士,副教授,研究方向为混凝科学与技术;E-mail:zhangpeng388@126.com。
基金资助:
ZHANG Peng1,2,3(), DONG Shanshan1, WANG Yulu2, ZHAO Yuelong1
Received:
2022-10-10
Published:
2023-07-10
Online:
2023-07-13
摘要:
以壳聚糖、二硫化碳、四氧化三铁为原料,戊二醛为交联剂,采用超声波辅助合成了一种核-壳结构的磁性黄原酸化壳聚糖重金属捕集剂(FSiCS)。通过测定水溶液中Sb(Ⅲ)的去除率来评价FSiCS的性能。当CS2用量为3.0 mL、NaOH质量浓度为90 g/L、反应时间为60 min+60 min、超声功率为160 W、戊二醛用量为150 μL、反应温度为50 ℃时,合成的FSiCS性能最佳。通过傅里叶红外光谱仪(FTIR)、扫描电镜(SEM)对其进行结构表征。FTIR分析表明,FSiCS中含有—SH、N—C=S、C=S、C—S等含硫基团或化学键,能够与Sb(Ⅲ)发生配位作用;SEM分析表明,FSiCS的粒径为100~250 nm,呈圆球形或棱角分明的多边形。
中图分类号:
张鹏, 董珊珊, 王雨露, 赵月龙. 磁性黄原酸化壳聚糖合成及表征[J]. 无机盐工业, 2023, 55(7): 89-96.
ZHANG Peng, DONG Shanshan, WANG Yulu, ZHAO Yuelong. Synthesis and characterization of magnetic xanthogenated chitosan[J]. Inorganic Chemicals Industry, 2023, 55(7): 89-96.
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