无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2021, Vol. 53 ›› Issue (10): 70-73.doi: 10.19964/j.issn.1006-4990.2021-0102

• 研究与开发 • 上一篇    下一篇

显微拉曼成像技术在钽酸锂晶体的成分、缺陷和应力分布表征中的应用研究

郭志峰()   

  1. 国家能源集团准能集团,内蒙古鄂尔多斯 010300
  • 收稿日期:2021-02-19 出版日期:2021-10-10 发布日期:2021-10-11
  • 作者简介:郭志峰(1984— ),男,硕士,高级工程师,主要研究方向为无机材料合成与检测;E-mail: 983645207@qq.com
  • 基金资助:
    神华集团煤炭开采水资源保护与利用国家重点实验室开放基金(20170514)

Study on application of Raman mapping technology in characterization of composition,defects and stress distribution of lithium tantalate crystal

Guo Zhifeng()   

  1. CHN ENERGY Zhungeer Energy Co.,Ltd.,Erdos 010300,China
  • Received:2021-02-19 Online:2021-10-10 Published:2021-10-11

摘要:

采用激光共聚焦显微拉曼光谱仪分别对钽酸锂晶体进行了显微拉曼成像测试研究,以865 cm-1特征峰峰强度对钽酸锂的成分分布进行了显微拉曼成像;以865 cm-1特征峰半高宽对晶体中锂含量分布进行了显微拉曼成像;以750 cm-1缺陷峰强度对晶体中的本征缺陷分布进行了显微拉曼成像;以865 cm-1特征峰峰位置对晶体中的应力分布进行了显微拉曼成像。测试结果表明,显微拉曼成像可以很好地对钽酸锂单晶片的化学成分和组分、本征缺陷、应力等化学物理性质的微观分布进行成像,未掺杂三氧化二铁比掺杂了三氧化二铁的钽酸锂晶体的成分和锂含量分布更加均匀,未掺杂三氧化二铁和掺杂了三氧化二铁的钽酸锂晶体的本征缺陷分布皆比较均匀且很少,未掺杂三氧化二铁比掺杂了三氧化二铁的钽酸锂晶体的应力分布更加均匀,掺杂了三氧化二铁的钽酸锂晶体存在明显的应力分布集中的区域。

关键词: 显微拉曼成像, 钽酸锂, 成分分布, 缺陷分布, 应力分布

Abstract:

The Raman mapping test of lithium tantalate crystal was studied by laser raman microscopy spectrometer.The com-position distribution of lithium tantalate crystal was imaged by Raman mapping in the characteristic peak intensity of 865 cm-1.The Li content distribution of crystal was imaged by Raman mapping in the characteristic peak FWHM of 865 cm-1.The de-fects distribution of crystal was imaged by Raman mapping in the defects peak intensity of 750 cm-1.The stress distribution of crystal was imaged by Raman mapping in the characteristic peak position of 865 cm-1.The test results showed the composi-tion,defects and stress distribution of lithium tantalate single crystal sheet could be well imaged by Raman mapping.The composition and Li content distribution of undoped lithium tantalate crystal were more uniform than that doped with Fe2O3.The distribution of intrinsic defects in undoped and doped lithium tantalate crystals with Fe2O3 was both relatively uniform and few.The stress distribution of undoped lithium tantalate crystal was more uniform than that doped with Fe2O3.There was an obvious stress concentration region in lithium tantalate crystal doped with Fe2O3.

Key words: Raman mapping, lithium tantalate, composition distribution, defects distribution, stress distribution

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