无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2020, Vol. 52 ›› Issue (11): 52-55.doi: 10.11962/1006-4990.2020-0180

• 工业技术 • 上一篇    下一篇

年处理100万t中低品位磷矿高效清洁生产工艺

张富强1,卢玉莲1(),张澜曦1,韩瑜1,张娇1,张钦1,2   

  1. 1.贵州省化工研究院,贵州贵阳 550002
    2.贵州盛源新材料股份有限公司
  • 收稿日期:2020-05-13 出版日期:2020-11-10 发布日期:2020-12-01
  • 通讯作者: 卢玉莲
  • 作者简介:张富强(1969— )男,工程师,从事磷复肥、磷化工相关研究工作。
  • 基金资助:
    贵州省科技厅项目黔科合服企[2015]4009

Efficient and clean production process for treating 1×106 t/a of low and medium grade phosphate rock

Zhang Fuqiang1,Lu Yulian1(),Zhang Lanxi1,Han Yu1,Zhang Jiao1,Zhang Qin1,2   

  1. 1. Guizhou Chemical Research Institute,Guiyang 550002,China
    2. Guizhou Shengyuan New Material Co.,Ltd.
  • Received:2020-05-13 Online:2020-11-10 Published:2020-12-01
  • Contact: Lu Yulian

摘要:

中低品位磷矿高效清洁综合利用是中国基础磷化工产业发展中遇到的共性瓶颈问题。以中低品位磷矿磷-钙-镁一体化综合利用中试成果为基础,通过创新集成技术对中低品位磷矿直接进行处理,获得高品质磷精矿[w(P2O5)≥36%、w(MgO)≤0.5%]可用于任何湿法磷酸及热法黄磷生产工艺,同时回收高附加值的氢氧化镁和轻质碳酸钙。该工艺磷全部回收、无尾矿产生、实现了废水近零排放,项目的实施对推动中国磷化工产业可持续发展及从源头解决“三磷”问题具有重要意义。

关键词: 中低品位磷矿, 高效清洁利用, 创新集成技术, 磷化工可持续发展

Abstract:

Efficient and clean comprehensive utilization of low and medium grade phosphate rock is a common bottleneck in the development of basic phosphorus chemical industry in China. Based on the pilot results of integrated comprehensive uti-lization of phosphorus-calcium-magnesium in low-grade phosphate rock,the high-quality phosphate concentrate [w(P2O5)≥36%, w(MgO)≤0.5%] can be obtained by directly treated of low and medium grade phosphate rock through innovative integrated technology,which can be used in any wet-process phosphoric acid and thermal yellow phosphorous production process,and the high value-added magnesium hydroxide and light calcium carbonate can be recovered simultaneously.All phosphorus in this process were recovered,and no tailings or waste water were discharged.The implementation of the project is of great sig-nificance to promote the sustainable development of China′s phosphorus chemical industry and solve the Three Phosphorus problem from the source.

Key words: low and medium grade phosphate rock, efficient and clean utilization, innovative integrated technology, phosphorus chemical sustainable development

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