无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2019, Vol. 51 ›› Issue (12): 6-9.doi: 10.11962/1006-4990.2019-0079

• 无机盐工业 • 上一篇    下一篇

废水除氟技术研究现状

张小东,赵飞燕,王永旺,陈 东   

  1. 神华准能资源综合开发有限公司,内蒙古鄂尔多斯 010300
  • 出版日期:2019-12-10 发布日期:2019-12-20
  • 作者简介:张小东(1986— ),男,硕士,工程师,主要从事煤炭共伴生资源的综合利用研究;E-mail:357694203@qq.com。

Research status of wastewater defluoridation technology

Zhang Xiaodong,Zhao Feiyan,Wang Yongwang,Chen Dong   

  1. Shenhua Zhungeer Energy and Resources Comprehensive Development Co.,Ltd.,Erdos 010300,China
  • Online:2019-12-10 Published:2019-12-20

摘要: 工业进程的加快导致含氟废水逐年增加,对生物和环境造成极大危害,含氟废水的高效环保处理方法成为世界各国研究的热点。阐述了含氟废水的多种处理方法,包括:沉淀法、电化学法、吸附法、离子交换树脂法及微生物除氟法等。综述了中国最新的废水除氟专利技术方法,包括:流化床结晶法、以碳酸钙和氢氧化钙混合物为沉淀剂的沉淀法、以精馏釜-填料精馏塔-冷凝器-贮液器等设备组成的精馏系统的精馏法、以表面包覆有含氯-铝离子结构的氨基膦酸化合物的螯合树脂吸附法、以阴离子交换树脂与金属锂铝形成的杂化材料的离子交换法、电凝聚-吸附法、强化镁沉淀法等。指出在实际的含氟废水处理过程中,需针对不同性质的废水采取适当的方法。

关键词: 废水除氟技术;含氟废水;沉淀法;树脂法;吸附法

Abstract: The accelerated industrial process has led to an increase in the amount of fluorinecontaining wastewater,which The accelerated industrial process has led to an increase in the amount of fluorinecontaining wastewater,which has caused great harm to life and environment.The efficient and environmentally friendly treatment of fluorine containing wastewater has become a hot research topic in the world.Various treatment methods for fluorine containing wastewater,such as precipitation method,electrochemical method,adsorption method,ion exchange resin method and microbial fluorine remo val method,were described.The latest wastewater defluoridation technologies in China,such as fluidized bed crystallization method,precipitation method using a mixture of calcium carbonate and calcium hydroxide as precipitant,rectification method of a rectification system composed of rectification tank filler rectification column condenser storage device,chelating resin adsorption method of surface coated with aminophosphonic acid compound containing chlorine and aluminum ion structure,ion exchange method of hybrid material formed by anion exchange resin and lithium aluminum metal,electrocoagulation ad sorption method,enhanced magnesium precipitation method,were summarized respectively.In the actual treatment of fluo rine containing wastewater,appropriate methods should be adopted for wastewater of different natures.

Key words: wastewater defluoridation technology;fluorine containing wastewater;precipitation method;resin method;adsorp

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