无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2019, Vol. 51 ›› Issue (7): 100-103.doi: 10.11962/1006-4990.2018-0466

• 无机盐工业 • 上一篇    

两种AgX改性吸附剂的烷烃/烯烃的分离技术

赵 闯1,苏文利2,臧甲忠1,孙 磊2,范景新1,马浴铭1,李 犇1,李 滨1,于海斌1   

  1. 1.中海油天津化工研究设计院有限公司,催化技术重点实验室,天津 300131;2.山东滨化滨阳燃化有限公司
  • 出版日期:2019-07-23 发布日期:2019-08-23
  • 作者简介:赵闯(1989— ),男,硕士,工程师,主要从事吸附分离材料及工艺的研究;E-mail:zc731364717@163.com。

Separation technology of alkane/olefin of two AgX modified adsorbents

Zhao Chuang1,Su Wenli2,Zang Jiazhong1,Sun Lei2,Fan Jingxin1,Ma Yuming1,Li Ben1,Li Bin1,Yu Haibin1   

  1. 1.Key Laboratory of Catalysis Technology,CenerTech Tianjin Chemical Research & Design Institute Co.,Ltd.,Tianjin 300131,China;2.Shangdong BinYang Gasification Co.,Ltd.
  • Online:2019-07-23 Published:2019-08-23

摘要: 分别采用等体积浸渍法和离子交换法制备一系列AgX吸附剂。通过化学吸附仪(CO-TPR)、傅里叶变换红外光谱仪(FT-IR)、 固体紫外可见漫反射光谱仪、X射线衍射仪(XRD)和X射线荧光光谱仪(XRF)等对吸附剂进行了表征;以模拟油品为原料,在小型固定床吸附与脱附器(200 mL)上考察了吸附剂的烷烃/烯烃分离性能。结果显示,与离子交换方法相比,浸渍法制备AgX吸附剂的烯烃分离性能更好,烷烃/烯烃分离度最高且不存在拖尾现象。与新鲜剂相比,再生后吸附剂的烯烃分离效果没有明显下降。

关键词: 等体积浸渍;离子交换;AgX;烷烃/烯烃分离度

Abstract: A series of AgX adsorbents were prepared by equal volume impregnation and ion exchange,respectively.The ad?鄄sorbent was characterized by chemical adsorption instrument(CO-TPR),Fourier transform infrared spectroscopy(FT-IR),solid ultraviolet visible(UV) diffuse reflectance spectrometer,X-ray diffractometer(XRD) and X-ray fluorescence spectro?鄄meter(XRF).The alkane/olefin separation performance of the adsorbent was investigated on a small fixed bed adsorption and desorption reactor(200 mL) using simulated oil as the raw material.The results showed that compared with the ion exchangemethod,the olefin separation performance of the AgX adsorbent prepared by the impregnation method was better,the alkane/olefin separation degree was the highest and there was no tailing phenomenon.The olefin separation effect of the regenerated adsorbent was not significantly reduced as compared with the fresh adsorbent.

Key words: equal volume impregnation;ion exchange;AgX;separation degree of alkane/olefin

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