Inorganic Chemicals Industry >
Study on highly active FCC matrix materials prepared by suspended solids and catalytic performance
Received date: 2024-05-07
Online published: 2024-07-30
In order to develop low-cost and highly active matrix materials in the field of catalytic cracking to improve the reaction performance of catalysts，the suspended solids generated in the in-situ crystallization catalytic cracking catalysts process are studied.XRD，SEM，NH3-TPD，nitrogen adsorption，particle size and other characterization methods were used to characterize the suspended solids before and after modification，and their catalytic performance was studied when applied to semi-synthetic catalytic cracking catalysts.The system verification and evaluation results indicated that the suspension was a mixture of Y-shaped molecular sieve and amorphous silicon aluminum material，with elemental composition mainly composed of silicon oxide，aluminum oxide，etc.After modification，the suspension had the Brunauer-Emmett-Teller（BET） surface area of 490 m2/g and pore volume of 0.42 cm3/g.It had excellent structural stability and a high total acid content.The micro reactivity reached 35% at 800 ℃ for 17 hours，significantly higher than that of the matrix material in use.Compared with catalysts without suspended solids，catalysts containing suspended solids showed that the conversion yield was increased from 83.9% to 81.1%，the slurry yield was decreased from 6.17% to 5.06% and gasoline yield was increased from 52.10% to 53.95%，total liquid yields was increased from 85.37% to 86.59%，without increasing dry gas and coke.It demonstrated that suspended sludge had excellent heavy oil conversion ability and product selectivity，and could be used as a low-cost，high-performance matrix material in the field of fluid catalytic cracking.
Key words： fluid catalytic cracking; suspended sludge; matrix material
ZHANG Li , HU Qingxun , CHEN Jun , LIU Huangfei , FANG Hua , WANG Jiujiang , LIU Honghai , CAO Gengzhen . Study on highly active FCC matrix materials prepared by suspended solids and catalytic performance[J]. Inorganic Chemicals Industry, 2025 , 57(7) : 127 -133 . DOI: 10.19964/j.issn.1006-4990.2024-0254
| [1] | 陈俊武.催化裂化工艺与工程［M］.2版.北京：中国石化出版社，2005：312-313. |
| [2] | LI Tao， ZHANG Ling， TAO Zhichao，et al.Synthesis and characterization of amorphous silica-alumina with enhanced acidity and its application in hydro-isomerization/cracking［J］.Fuel，2020，279：118487. |
| [3] | Zhipeng QIE， RABBANI A， LIANG Yan，et al.Multiscale investigation of pore network heterogeneity and permeability of fluid catalytic cracking（FCC） particles［J］.Chemical Engineering Journal，2022，440：135843. |
| [4] | 王斌，张强，李春义，等.催化裂化催化剂基质表面强弱Br?nsted酸性位数目对小分子烯烃收率的影响［J］.石油炼制与化工，2016，47（3）：10-15. |
| WANG Bin， ZHANG Qiang， LI Chunyi，et al.Effect of Br?nsted acid number on matrix of FCC catalyst on yield of light olefins［J］.Petroleum Processing and Petrochemicals，2016，47（3）：10-15. | |
| [5] | 于善青，刘雨晴，郭硕，等.半合成催化裂化催化剂主要组分对其孔结构的影响［J］.石油学报（石油加工），2024，40（2）：327-337. |
| YU Shanqing， LIU Yuqing， GUO Shuo，et al.Influence of main components of FCC catalyst prepared by semi synthetic method on its pore structure［J］.Acta Petrolei Sinica（Petroleum Processing Section），2024，40（2）：327-337. | |
| [6] | 高明军，徐荣霞，谭映临，等.不同产地高岭土所制催化裂化催化剂的性能差异［J］.石油炼制与化工，2022，53（7）：64-69. |
| GAO Mingjun， XU Rongxia， TAN Yinglin，et al.Performance difference of catalytic cracking catalysts made of Kaolin from different regions［J］.Petroleum Processing and Petrochemicals，2022，53（7）：64-69. | |
| [7] | 闫涛.高性能氧化铝催化材料的合成、表征与应用研究［D］.淄博：山东理工大学，2023. |
| YAN Tao.Study on synthesis，characterization and application of high performance alumina catalytic materials［D］.Zibo：Shandong University of Technology，2023. | |
| [8] | LI Tao， TAO Zhichao， ZHANG Ling，et al.Facile and cost-effective synthesis of acidity-enhanced amorphous silica-alumina for high-performance isomerization［J］.Journal of Solid State Chemistry，2021，300：122249. |
| [9] | 李雪礼，袁程远，王启飞，等.抗铁污染催化裂化催化剂的制备及性能评价［J］.石油炼制与化工，2020，51（6）：42-46. |
| LI Xueli， YUAN Chengyuan， WANG Qifei，et al.Preparation and performance evaluation of anti-iron contamination FCC catalyst［J］.Petroleum Processing and Petrochemicals，2020，51（6）：42-46. | |
| [10] | 鲍俊，曾双亲，杨清河，等.无定形硅铝材料的制备及应用研究进展［J］.石油炼制与化工，2024，55（3）：154-161. |
| BAO Jun， ZENG Shuangqin， YANG Qinghe，et al.Research progress on preparation and application of amorphous silica-alumina materials［J］.Petroleum Processing and Petrochemicals，2024，55（3）：154-161. | |
| [11] | 金俊良，吕国诚，冯杰，等.热酸结合改性高岭石及流化催化裂化催化剂载体性能［J］.硅酸盐学报，2022，50（1）：226- 235. |
| JIN Junliang， Guocheng Lü， FENG Jie，et al.Thermal acid modification of kaolinite and performance of fluidized catalytic cracking catalyst support［J］.Journal of the Chinese Ceramic Society，2022，50（1）：226-235. | |
| [12] | 张莉，胡清勋，王久江，等.凹凸棒石黏土在催化裂化催化剂中的应用研究［J］.无机盐工业，2017，49（12）：69-71. |
| ZHANG Li， HU Qingxun， WANG Jiujiang，et al.Research on application of attapulgite clay in catalytic cracking catalyst［J］.Inorganic Chemicals Industry，2017，49（12）：69-71. | |
| [13] | 刘涛，柳召永，郝帅，等.硅藻土在催化裂化催化剂重油转化中的应用［J］.石化技术与应用，2021，39（3）：177-180. |
| LIU Tao， LIU Zhaoyong， HAO Shuai，et al.Application of diatomite in catalytic cracking catalyst′s heavy oil conversion［J］.Petrochemical Technology & Application，2021，39（3）：177-180. | |
| [14] | 汪博，包建国，文彬，等.不同产地高岭土作裂化催化剂载体可行性研究［J］.非金属矿，2020，43（3）：30-32. |
| WANG Bo， BAO Jianguo， WEN Bin，et al.The feasibility study of Kaolin from different regions as the cracking catalyst carrier［J］.Non-Metallic Mines，2020，43（3）：30-32. | |
| [15] | ALEKSEEVA T V， ALEKSEEV A O.Rectorite as a syngenetic component of a Soddy-podzolic soil［J］.Eurasian Soil Science，2020，53（10）：1502-1508. |
| [16] | 刘小荷.稀土与硅改性氧化铝基质的制备及其重油催化裂化性能研究［D］.东营：中国石油大学（华东），2019. |
| LIU Xiaohe.Preparation of alumina matrix modified by rare earth and silicon and its catalytic cracking performance for heavy oil［D］.Dongying：China University of Petroleum（Huadong），2019. | |
| [17] | MA Zhi， DONG Junjie， LI Yingqian，et al.Modification of halloysite inner surface and its performance［J］.Bulletin of the Chinese Ceramic Society，2017，36（8）：2850-2854. |
| [18] | JOUSSEIN E， PETIT S， CHURCHMAN J，et al.Halloysite clay minerals：A review［J］.Clay Minerals，2005，40（4）：383-426. |
| [19] | 李忠，刘勇文.高岭土对流化催化裂化（FCC）催化剂性能的影响［J］.无机盐工业，2017，49（8）：81-84. |
| LI Zhong， LIU Yongwen.Effects of Kaolin on properties of fluidized catalytic cracking catalyst［J］.Inorganic Chemicals Industry，2017，49（8）：81-84. | |
| [20] | 闫光奇，高传成，孟晓静，等.FCC催化剂新型载体的探索：皂石基复合材料［J］.山东化工，2014，43（5）：20-22. |
| YAN Guangqi， GAO Chuancheng， MENG Xiaojing，et al.Study of the new support for FCC catalyst-saponite-based composite［J］.Shandong Chemical Industry，2014，43（5）：20-22. | |
| [21] | 熊晓云，曹庚振，杜学敏，等.炭黑模板法制备大孔原位晶化型催化裂化催化剂［J］.无机盐工业，2023，55（9）：134- 139. |
| XIONG Xiaoyun， CAO Gengzhen， DU Xuemin，et al.Preparation of macroporous in situ crystallized FCC catalyst by carbon black template method［J］.Inorganic Chemicals Industry，2023，55（9）：134-139. | |
| [22] | 袁程远，陈强，赵倩，等.炼油FCC废催化剂硅掺杂拟薄水铝石原位构筑改性复活研究［J］.山东理工大学学报（自然科学版），2023，37（2）：20-23. |
| YUAN Chengyuan， CHEN Qiang， ZHAO Qian，et al.Study on the regeneration for refining waste FCC catalyst by in situ construction of silica-doped pseudo boehmite［J］.Journal of Shandong University of Technology（Natural Science Edition），2023，37（2）：20-23. | |
| [23] | 姜山，赵亮.重质油催化裂化催化剂基质材料制备及应用研究［J］.辽宁化工，2022，51（5）：599-601，608. |
| JIANG Shan， ZHAO Liang.Preparation and application of heavy oil catalytic cracking catalyst matrix materials［J］.Liaoning Che- | |
| Industry mical，2022，51（5）：599-601，608. | |
| [24] | 苗鹏杰，陈自娇，李守柱，等.利用废渣制备催化裂化催化剂及其催化性能研究［J］.石油炼制与化工，2022，53（9）：72-77. |
| MIAO Pengjie， CHEN Zijiao， LI Shouzhu，et al.Preparation and catalytic performance of FCC catalyst from waste residue［J］.Petroleum Processing and Petrochemicals，2022，53（9）：72-77. | |
| [25] | 冯锐，方舟，周鹏，等.基质 Lewis 酸性调控及其催化轻烃裂化反应性能［J］.燃料化学学报，2024，52（2）：218-233. |
| FENG Rui， FANG Zhou， ZHOU Peng，et al.Regulation of the Lewis acidity on matrix and their performance in the catalytic cracking of light hydrocarbons［J］.Journal of Fuel Chemistry and | |
| Technology，2024，52（2）：218-233. | |
| [26] | 闫涛，袁程远，柴军军，等.硅改性拟薄水铝石的合成及其在FCC催化剂中的应用［J］.石油化工，2021，50（11）：1115-1120. |
| YAN Tao， YUAN Chengyuan， CHAI Junjun，et al.Synthesis of silica-modified pseudo boehmite and its application in FCC catalyst［J］.Petrochemical Technology，2021，50（11）：1115-1120. |
/
| 〈 |
|
〉 |