Inorganic Chemicals Industry >
Treatment of methylene blue simulated wastewater by supported activated carbon particle with three-dimensional electrode method
Received date: 2023-07-04
Online published: 2024-05-15
To improve the effect of electrocatalytic oxidation on methylene blue（MB） simulated wastewater by particle electrode in three-dimensional electrode system，a particle electrode（M/AC） combining metal oxides with granular activated carbon was successfully synthesized with equal volume impregnation and sintering methods and characterized.The effects of the type and loading of metal components on the catalytic performance of the particle electrode were investigated.Moreover，the reaction mechanism of the synthesized particle electrode was discussed.The results indicated that：M/AC particle electrode had multi-channel porous network structure，which could provide a large number of surface active sites.The M/AC particle electrode showed good electrocatalytic degradation ability for high concentration MB simulated wastewater in three-dimensional electrode system.The optimal loading capacity of Mn/AC particle electrode was 5%（mass fraction），and its electrocatalytic oxidation performance was better than that of Fe/AC and Ni/AC particle electrode.The electrocatalytic degradation rate of Mn（5）/AC in the three-dimensional electrode system was 90% after 8 h，and could still reach more than 80% after 200 h.In the electrocatalytic oxidation process，Mn2+，Mn3+ and Mn4+ on the surface of Mn/AC particle electrode could achieve catalytic cycling and produce active substances（hydroxyl radical and superoxide radical）.Mn/AC particle electrode had the potential for long-term stable electrocatalytic degradation of organic pollutants in water.
XIE Jiang , GUO Ge , QIU Jie . Treatment of methylene blue simulated wastewater by supported activated carbon particle with three-dimensional electrode method[J]. Inorganic Chemicals Industry, 2024 , 56(5) : 78 -86 . DOI: 10.19964/j.issn.1006-4990.2023-0351
| 1 | LI Hongtao， YANG Haitao， CHENG Jiaxin，et al.Three-dimensional particle electrode system treatment of organic wastewater：A general review based on patents［J］.Journal of Cleaner Production，2021，308：127324. |
| 2 | 冯卓然，程平统，窦波林，等.泡沫镍三维电极电芬顿法预处理焦化废水效能研究［J］.给水排水，2020，56（S2）：114-119. |
| FENG Zhuoran， CHENG Pingtong， DOU Bolin，et al.Study on pretreatment of coking wastewater by three-dimensional electro-fenton with foam-nickel-electrode ［J］.Water & Wastewater Engineering，2020，56 （S2）：114-119 | |
| 3 | 李程，王洪彬，崔新安.三维电极法处理含钴、锰废水［J］.化工环保，2021，41（1）：43-48. |
| LI Cheng， WANG Hongbin， CUI Xin′an.Treatment of cobalt and manganese containing wastewater by three-dimensional electrode method［J］.Environmental Protection of Chemical Industry，2021，41（1）：43-48. | |
| 4 | WANG Tuo， SONG Yunqian， DING Haojie，et al.Insight into synergies between ozone and in situ regenerated granular activated carbon particle electrodes in a three-dimensional electrochemical reactor for highly efficient nitrobenzene degradation［J］.Chemical Engineering Journal，2020，394：124852. |
| 5 | 段海霞，包丽纳，张文正.紫外光-三维电极联合处理黑索金废水的实验研究［J］.山东化工，2021，50（4）：282-283，287. |
| DUAN Haixia， BAO Lina， ZHANG Wenzheng.The experimental study on the treatment of RDX wastewater by ultraviolet-light-three-dimensional electrode［J］.Shandong Chemical Industry，2021，50（4）：282-283，287. | |
| 6 | POURZAMANI H， MENGELIZADEH N， HAJIZADEH Y，et al.Electrochemical degradation of diclofenac using three-dimensional electrode reactor with multi-walled carbon nanotubes［J］.Environmental Science and Pollution Research International，2018，25（25）：24746-24763. |
| 7 | 余健，黄胜，李云桂，等.覆膜活性炭三维电极处理垃圾渗滤液［J］.工业水处理，2021，41（6）：232-237. |
| YU Jian， HUANG Sheng， LI Yungui，et al.Treatment landfill leachate with three-dimensional electrodes coated by activated carbon［J］.Industrial Water Treatment，2021，41（6）：232-237. | |
| 8 | 徐浩，乔丹，许志成，等.电催化氧化技术在有机废水处理中的应用［J］.工业水处理，2021，41（3）：1-9. |
| XU Hao， QIAO Dan， XU Zhicheng，et al.Application of electro-catalytic oxidation technology in organic wastewater treatment［J］.Industrial Water Treatment，2021，41（3）：1-9. | |
| 9 | SHEN Bo， WEN Xianghua， HUANG Xia.Enhanced removal performance of estriol by a three-dimensional electrode reactor［J］.Chemical Engineering Journal，2017，327：597-607. |
| 10 | YU Dayang， CUI Jun， LI Xiuqing，et al.Electrochemical treatment of organic pollutants in landfill leachate using a three-dimensional electrode system［J］.Chemosphere，2020，243：125438. |
| 11 | 丁红，王艺洁，武福平.废铁屑-Ti（RuO2）三维电极高效处理高氮磷低C/N污水［J］.环境工程学报，2021，15（3）：847- 856. |
| DING Hong， WANG Yijie， WU Fuping.High-nitrogen/phosphorus and low-C/N sewage treatment by iron-scarps and Ti（RuO2） based three-dimension electrode［J］.Chinese Journal of Environmental Engineering，2021，15（3）：847-856. | |
| 12 | 于晓明子，程琳，王嘉毅.复极性三维电极法与二维电极法处理苯酚废水的对比研究［J］.辽宁化工，2018，47（6）：490-492. |
| YU Xiaomingzi， CHENG Lin， WANG Jiayi.Comparative study on the treatment of phenolic wastewater by complex polarized three-dimensional electrode and two-dimensional electrode［J］.Liaoning Chemical Industry，2018，47（6）：490-492. | |
| 13 | DARGAHI A， VOSOUGHI M， AHMAD MOKHTARI S，et al.Electrochemical degradation of 2，4-Dinitrotoluene（DNT） from aqueous solutions using three-dimensional electrocatalytic reactor（3DER）：Degradation pathway，evaluation of toxicity and optimization using RSM-CCD［J］.Arabian Journal of Chemistry，2022，15（3）：103648. |
| 14 | RAHMANI A， LEILI M， SEID-MOHAMMADI A，et al.Improved degradation of diuron herbicide and pesticide wastewater treatment in a three-dimensional electrochemical reactor equipped with PbO2 anodes and granular activated carbon particle electrodes［J］.Journal of Cleaner Production，2021，322：129094. |
| 15 | 张嘉烜，赵宗彬，孙洋，等.FeOOH/石墨烯复合气凝胶三维电极氧化脱除污水有机物的研究［J］.现代化工，2020，40（3）：92-96，102. |
| ZHANG Jiaxuan， ZHAO Zongbin， SUN Yang，et al.Preparation of three-dimensional FeOOH/r-GO composite aerogel electrodes and their application in oxidation of organics in wastewater［J］.Modern Chemical Industry，2020，40（3）：92-96，102. | |
| 16 | 徐斌，张书陵，高月香，等.石墨烯三维电极-电Fenton系统降解甲基橙［J］.中国环境科学，2020，40（10）：4385-4394. |
| XU Bin， ZHANG Shuling， GAO Yuexiang，et al.Degradation of methyl orange by graphene three-dimensional electrode-electro Fenton system［J］.China Environmental Science，2020，40（10）：4385-4394. | |
| 17 | 傅金祥，徐坤，何祥，等.Ti-rGO/GAC粒子电极降解苯酚废水的影响因素试验研究［J］.安全与环境工程，2019，26（6）：101-107. |
| FU Jinxiang， XU Kun， HE Xiang，et al.Experimental study on factors affecting degradation of phenol wastewater by Ti-rGO/GAC particle electrode［J］.Safety and Environmental Engineering，2019，26（6）：101-107. | |
| 18 | WAN Jia， ZHAO Feiping， MENG Yong，et al.Three-dimensional electrochemical degradation of p-aminophenol with efficient honeycomb block AC@Ti-Cu-Ni-Zn-Sb-Mn particle electrodes［J］.Separation and Purification Technology，2021，267：118662. |
| 19 | YAN Yujie， XUE Fengjiao， MUHAMMAD F，et al.Application of iron-loaded activated carbon electrodes for electrokinetic remediation of chromium-contaminated soil in a three-dimensional electrode system［J］.Scientific Reports，2018，8（1）：5753. |
| 20 | WU Xinbo， YANG Xiaoqing， WU Dingcai，et al.Feasibility study of using carbon aerogel as particle electrodes for decoloration of RBRX dye solution in a three-dimensional electrode reactor［J］.Chemical Engineering Journal，2008，138（1/2/3）：47-54. |
| 21 | MALAKOOTIAN M， NASIRI A， HEIDARI M R.Removal of phenol from steel plant wastewater in three dimensional electrochemical（TDE） process using CoFe2O4@AC/H2O2 ［J］.Zeitschrift Für Physikalische Chemie，2020，234（10）：1661-1679. |
| 22 | SUN Wenquan， SUN Yongjun， SHAH K J，et al.Electrochemical degradation of oxytetracycline by Ti-Sn-Sb/γ-Al2O3 three-dimensional electrodes［J］.Journal of Environmental Management，2019，241：22-31. |
| 23 | WANG Zhaoyang， LI Junfeng， HE Xinlin，et al.Organic pollutants removal performance and enhanced mechanism investigation of surface-modified steel slag particle electrode［J］.Environmental Progress & Sustainable Energy，2019，38（s1）：S7-S14. |
| 24 | ZHAN Juhong， LI Zhaoxin， YU Gang，et al.Enhanced treatment of pharmaceutical wastewater by combining three-dimensional electrochemical process with ozonation to in situ regenerate granular activated carbon particle electrodes［J］.Separation and Purification Technology，2019，208：12-18. |
| 25 | 刘伟军，段平洲，胡翔，等.活性炭纤维三维电极电催化降解水中间甲酚：效能及影响因素研究［J］.中国环境科学，2019，39（1）：164-169. |
| LIU Weijun， DUAN Pingzhou， HU Xiang，et al.Efficacy and influencing factors of electrocatalytic degradation of m-cresol in wastewater by activated carbon fiber as three-dimensional electrodes［J］.China Environmental Science，2019，39（1）：164-169. | |
| 26 | 孙丰霞，孙超，王玉军，等.活性炭三维电极法处理阿莫西林模拟废水［J］.当代化工研究，2023（2）：94-98. |
| SUN Fengxia， SUN Chao， WANG Yujun，et al.Removing amoxicillin from simulated wastewater using three-dimensional electro-de of activated carbon［J］.Modern Chemical Research，2023（2）：94-98. | |
| 27 | LIU Shuan， WANG Zhaoyang， LI Junfeng，et al.Fabrication of slag particle three-dimensional electrode system for methylene blue degradation：Characterization，performance and mechanism study［J］.Chemosphere，2018，213：377-383. |
| 28 | MA Jinsong， GAO Ming， SHI Huimin，et al.Progress in research and development of particle electrodes for three-dimensional electrochemical treatment of wastewater：A review［J］.Environmental Science and Pollution Research International，2021，28（35）：47800-47824. |
/
| 〈 |
|
〉 |