Inorganic Chemicals Industry >
Study on controlled synthesis of magadiite and its metal ion exchange properties
Received date: 2022-09-06
Online published: 2023-02-16
At present，the development of green and efficient heavy metal adsorption materials has attracted extensive attention.Using diatomite as raw material，two kinds of silicate materials，namely，magadiite and analcime，were selectively prepared by hydrothermal method.The Na+ between the layers of wheat hydroxysodalite could exchange cations with Li+，Mg2+，Zn2+，Co2+，Ni2+，Cu2+，etc.，and maintain the stability of the layered parent framework.The adsorption kinetics and mechanisms were detailedly studied by using Co2+ and Ni2+ adsorption.It is indicated that the distance of magadiite lamellar structure was reduced from 1.56 nm to 0.24 nm（Co2+）and 0.23 nm（Ni2+）.The maximum adsorption capacity towards Co2+ and Ni2+ reached 45 mg/g and 39 mg/g at room temperature，respectively.The adsorption processes were fitted with the Langmuir model.The released Na+ was approximate double of the adsorbed divalent Co2+ and Ni2+，showing that cation exchange dominated the adsorption processes.Thus，the prepared magadiite materials demonstrated great potentials for constructing multi-metal silicates and environmental purification applications.
Key words： diatomite; magadiite; cation exchange; layer structure
Zhanzhan GUO , Wenyuan ZHOU , Yunfei YANG , Junshu WU , Jinshu WANG , Lingmin SUN , Zhigang ZHANG , Yucheng DU . Study on controlled synthesis of magadiite and its metal ion exchange properties[J]. Inorganic Chemicals Industry, 2023 , 55(2) : 45 -54 . DOI: 10.19964/j.issn.1006-4990.2022-0537
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