Inorganic Chemicals Industry >

2022 , Vol. 54 >Issue 3: 38 - 44

DOI: https://doi.org/10.19964/j.issn.1006-4990.2021-0337

Reviews and Special Topics

Research progress on preparation of Li3V2（PO4）3 cathode material for lithium-ion batteries

  • Xinyi ZHANG ,
  • Yuli DI ,
  • Qi DONG ,
  • Xingyu CHEN ,
  • Zhengdong ZHANG
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  • 1. College of Materials and Chemistry & Chemical Engineering,Chengdu University of Technology,Chengdu 610059,China
    2. School of Science,Xichang University

Received date: 2021-05-24

  Online published: 2022-03-18

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Abstract

Compared with other lithium-ion battery cathode material,lithium vanadium phosphate[Li3V2（PO4）3] material with monoclinic structure has higher working voltage（3.0~4.8 V）,good ion mobility and excellent thermal stability.It is a high-power lithium-ion battery cathode material with competitive advantages and development prospects,and has become a research hotspot in recent years.The structural characteristics of lithium vanadium phosphate and its charging and discharging mechanism were reviewed.The common synthesis methods of lithium vanadium phosphate included carbothermic reduction,hydrothermal method,sol-gel method and fluidization method,and the influence of different synthesis methods and processes of lithium vanadium phosphate on the different morphologies and electrochemical properties of the prepared samples was emphasized.The improvement methods of different synthesis methods are analyzed and summarized to improve the shortco-mings and defects of low electronic conductivity and lithium ion diffusion coefficient of lithium vanadium phosphate cathode materials.Finally,In view of the problems existing in the application of vanadium lithium phosphate cathode material in lithium ion battery,the possible development direction and research focus of this material in the future were prospected.It was pointed out that the preparation method of materials needed to be optimized to improve the particle morphology,electronic conductivity and diffusion coefficient of materials,so as to improve the cycle performance,rate performance and charge/dis-charge performance of materials.It was necessary to improve the preparation process,improve the safety of the experiment,simplify the reaction process and reduce the preparation cost in order to realize the industrial application of lithium vanadium phosphate cathode materials.

Key words： lithium-ion battery; Li3V2（PO4）3; synthesis methods; electrochemical performance

Cite this article

Xinyi ZHANG , Yuli DI , Qi DONG , Xingyu CHEN , Zhengdong ZHANG . Research progress on preparation of Li3V2（PO4）3 cathode material for lithium-ion batteries[J]. Inorganic Chemicals Industry, 2022 , 54(3) : 38 -44 . DOI: 10.19964/j.issn.1006-4990.2021-0337

References

[1] LEE H S, RAMAR V, KUPPAN S, et al. Key design considerations for synjournal of mesoporous α-Li3V2(PO4)3/C for high power lithium batteries[J]. Electrochimica Acta, 2021, 372.Doi: 10.1016/j.electacta.2021.137831.
[2] QI N, MA Y Y, REN B, et al. Comparison of the La-doped and Gd-doped Li3V2(PO4)3/C via electrochemical tests and first-principle calculations for lithium-ion batteries[J]. Journal of Physics and Che-mistry of Solids, 2021, 150.Doi: 10.1016/j.jpcs.2020.109889.
[3] WANG X, ZHAO X, WANG J, et al. Electrospun Li3V2(PO4)3 nano-belts:Synjournal and electrochemical properties as cathode materials of lithium-ion batteries[J]. Journal of the Chinese Chemical Society, 2017, 64(7):557-564.
[4] CHEN Y, CHEN H, XIAO L, et al. Preparation for honeycombed Li3V2(PO4)3/C composites via vacuum-assisted immersion method and their high-rates performance in lithium-ion batteries[J]. Vacu-um, 2020, 172.Doi: 10.1016/j.vacuum.2019.108926.
[5] GUO Y, HUANG Y, JIA D, et al. Preparation and electrochemical properties of high-capacity LiFePO4-Li3V2(PO4)3/C composite for li-thium-ion batteries[J]. Journal of Power Sources, 2014, 246:912-917.
[6] SØRENSEN D R, MATHIESEN J K, RAVNSBÆK D B, et al. Dyna-mic charge-discharge phase transitions in Li3V2(PO4)3 cathodes[J]. Journal of Power Sources, 2018, 396:437-443.
[7] ZHANG X, GUO H, LI X, et al. High tap-density Li3V2(PO4)3/C co-mposite material synthesized by sol spray-drying and post-calcining method[J]. Electrochimica Acta, 2012, 64:65-70.
[8] LI L, FAN C, HUANG X, et al. The influence of different carbon so-urces on Li3V2(PO4)3/C synthesized by a hybrid sol-gel method as cathode for lithium-ion batteries[J]. Energy Technology, 2015, 3(9):955-960.
[9] XIA Y, YU L, LU C, et al. Passion fruit-like structure endows Li3V2(PO4)3@C/CNT composite with superior cyclic stability and rate performance[J]. Journal of Alloys and Compounds, 2021, 859.Doi: 10.1016/j.jallcom.2020.157806.
[10] 刘艺培. 磷酸钒锂正极材料的制备及电化学性能研究[D]. 马鞍山:安徽工业大学, 2018.
[11] 邓玲, 陈善华, 吴骏, 等. 聚阴离子型锂离子电池正极材料Li3V2(PO4)3的研究进展[J]. 应用化工, 2014, 43(3):522-526.
[12] GUO S, BAI Y, GENG Z, et al. Facile synjournal of Li3V2(PO4)3/C cathode material for lithium-ion battery via freeze-drying[J]. Jour-nal of Energy Chemistry, 2019, 32:159-165.
[13] LEE S, PARK S S. Atomistic simulation study of monoclinic Li3V2(PO4)3 as a cathode material for lithium ion battery:Structure, defect chemistry,lithium ion transport pathway,and dynamics[J]. Journal of Physical Chemistry C, 2012, 116(48):25190-25197.
[14] KUGANATHAN N, CHRONEOS A. Defects and dopant properties of Li3V2(PO4)3[J]. Scientific Reports, 2019, 9(1).Doi: 10.1038/s41598-018-36398-w.
[15] RAI A K, THI T V, GIM J, et al. Li3V2(PO4)3/graphene nanocompo-site as a high performance cathode material for lithium ion ba-ttery[J]. Ceramics International, 2015, 41(1):389-396.
[16] LUO Y, SHUI M, SHU J. Understanding the lithium transport me-chanism in monoclinic Li3V2(PO4)3 cathode material by atomistic simulation[J]. Results in Physics, 2019, 14.Doi: 10.1016/j.rinp.2019.102490.
[17] DING M, CHENG C, WEI Q, et al. Carbon decorated Li3V2(PO4)3 for high-rate lithium-ion batteries:Electrochemical performance and charge compensation mechanism[J]. Journal of Energy Che-mistry, 2020, 53:124-131.
[18] LIN X, SHEN Z, HAN T, et al. Hydrogel assisted synjournal of Li3V2(PO4)3 composite as high energy density and low-tempera-ture stable secondary battery cathode[J]. Journal of Alloys and Co-mpounds, 2018, 739:837-847.
[19] QIAO Y Q, TU J P, XIANG J Y, et al. Effects of synthetic route on structure and electrochemical performance of Li3V2(PO4)3/C catho-de materials[J]. Electrochimica Acta, 2011, 56(11):4139-4145.
[20] LI Y, XIN L, JIE Y. Study on synjournal routes and their influences on chemical and electrochemical performances of Li3V2(PO4)3/car-bon[J]. Electrochimica Acta, 2007, 53(2):474-479.
[21] HUANG H, FAULKNER T, BARKER J, et al. Lithium metal pho-sphates,power and automotive applications[J]. Journal of Power Sources, 2009, 189(1):748-751.
[22] BARKER J, SAIDI M Y, SWOYER J L. Lithium iron(Ⅱ) phospho-olivines prepared by a novel carbothermal reduction method[J]. Electrochemical and Solid-State Letters, 2003, 6(3):53-55.
[23] 姜霖琳, 田彦文, 刘丽英. 碳热还原法制备锂离子电池正极材料Li3V2(PO4)3的研究[J]. 材料与冶金学报, 2006, 5(2):115-118.
[24] 李娜丽, 同艳维, 崔旭梅, 等. 烧结工艺对锂离子电池正极材料磷酸钒锂结构和电化学性能的影响[J]. 钢铁钒钛, 2018, 39(6):59-64.
[25] SECCHIAROLI M, NOBILI F, TOSSICI R, et al. Synjournal and elec-trochemical characterization of high rate capability Li3V2(PO4)3/C prepared by using poly(acrylic acid) and d-(+)-glucose as carbon sources[J]. Journal of Power Sources, 2015, 275:792-798.
[26] SAÏDI M Y, BARKER J, HUANG H, et al. Performance character-istics of lithium vanadium phosphate as a cathode material for lithi-um-ion batteries[J]. Journal of Power Sources, 2003, 119-121(6):266-272.
[27] LIU L, XIAO W, CHEN M, et al. Improved rate and cycle perfor-mance of nano-sized 5LiFePO4·Li3V2(PO4)3/C via high-energy ball milling assisted carbothermal reduction[J]. Journal of Alloys and Compounds, 2017, 719(30):281-287.
[28] HUANG B, FAN X, ZHENG X, et al. Synjournal and rate performa-nce of lithium vanadium phosphate as cathode material for Li-ion batteries[J]. Journal of Alloys and Compounds, 2011, 509(14):4765-4768.
[29] DUAN W, HU Z, ZHANG K, et al. Li3V2(PO4)3@C core-shell nano-composite as a superior cathode material for lithium-ion batteri-es[J]. Nanoscale, 2013, 5(14):6485-6490.
[30] CHANG C, XIANG J, SHI X, et al. Hydrothermal synjournal of car-bon-coated lithium vanadium phosphate[J]. Electrochimica Acta, 2009, 54(2):623-627.
[31] REN M, ZHEN Z, LI Y, et al. Preparation and electrochemical stu-dies of Fe-doped Li3V2(PO4)3 cathode materials for lithium-ion ba-tteries[J]. Journal of Power Sources, 2006, 162(2):1357-1362.
[32] TENG F, HU Z H, MA X H, et al. Hydrothermal synjournal of plate-like carbon-coated Li3V2(PO4)3 and its low temperature performa-nce for high power lithium ion batteries[J]. Electrochimica Acta, 2013, 91:43-49.
[33] LIU H, CHENG C, HUANG X, et al. Hydrothermal synjournal and rate capacity studies of Li3V2(PO4)3 nanorods as cathode material for lithium-ion batteries[J]. Electrochimica Acta, 2010, 55(28):8461-8465.
[34] REN M M, ZHOU Z, GAO X P, et al. Core-Shell Li3V2(PO4)3@C composites as cathode materials for lithium-ion batteries[J]. The Journal of Physical Chemistry C, 2008, 112(14):5689-5693.
[35] MOSHURCHAK L M, BUHRMESTER C, WANG R L, et al. Com-parative studies of three redox shuttle molecule classes for over-charge protection of LiFePO4-based Li-ion cells[J]. Electrochimi-ca Acta, 2007, 52(11):3779-3784.
[36] DOEFF M M, HU Yaoqin, MCLARNON F, et al. Effect of surface carbon structure on the electrochemical performance of LiFePO4[J]. Office of Scientific & Technical Information Technical Reports, 2003, 3(3):311-313.
[37] ZHUANG B, GUO Z, CHU W, et al. Mesoporous carbon film inlaid with Li3V2(PO4)3 nanoclusters through delaying sol-gel method for high performance lithium-ion hybrid supercapacitors[J]. Electro-chimica Acta, 2018, 283:1589-1599.
[38] LI Y, ZHEN Z, REN M, et al. Electrochemical performance of nano-crystalline Li3V2(PO4)3/carbon composite material synthesized by a novel sol-gel method[J]. Electrochimica Acta, 2006, 51(28):6498-6502.
[39] ZHANG Q, LI Y H, ZHONG S K, et al. Synjournal and electrochemi-cal performance of Li3V2(PO4)3 by optimized sol-gel synjournal rou-tine[J]. Transactions of Nonferrous Metals Society of China, 2010, 20(8):1545-1549.
[40] RUI X H, LI C, LIU J, et al. The Li3V2(PO4)3/C composites with high-rate capability prepared by a maltose-based sol-gel route[J]. Electrochimica Acta, 2010, 55(22):6761-6767.
[41] CAO X, ZHAN H, XIE J. Synjournal of Ag2V4O11 as a cathode mate-rial for lithium battery via a rheological phase method[J]. Materi-als Letters, 2006, 60(4):435-438.
[42] XIE L, CAO X, LIU C, et al. Rheological phase synjournal and cha-racterization of micro-sized Li4Ti5O12[J]. Journal of the Chilean Chemical Society, 2010, 55(3):343-346.
[43] XIE L L, XU Y D, ZHANG J J, et al. Rheological phase synjournal of Er-doped LiV3O8 as electroactive material for a cathode of sec-ondary lithium storage[J]. Electronic Materials Letters, 2013, 9(4):549-553.
[44] CHANG C, XIANG J, SHI X, et al. Rheological phase reaction synjournal and electrochemical performance of Li3V2(PO4)3/carbon cathode for lithium ion batteries[J]. Electrochimica Acta, 2008, 53(5):2232-2237.
[45] 李丽, 李国华, 王石泉, 等. 磷酸钒锂正极材料的合成与性能研究[J]. 无机化学学报, 2010, 26(1):126-131.
[46] CAO X, ZHANG J. Rheological phase synjournal and characteriza-tion of Li3V2(PO4)3/C composites as cathode materials for lithium ion batteries[J]. Electrochimica Acta, 2014, 129:305-311.
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