Inorganic Chemicals Industry >
Controlled-synthesis of nanometer zinc phosphate
Received date: 2019-02-11
Online published: 2020-06-15
Particle size of zinc phosphate was controlled-synthetized by grinding reaction instead of stirring reaction and assisted surfactant in the solid-liquid reaction system between zinc oxide and phosphoric acid.The effects of grinding medium,grinding ball ratio,ball-to-material ratio,solid-liquid ratio and surfactant on the particle size distribution,morphology and agglomeration of zinc phosphate were investigated.Nano zinc phosphate was characterized by SEM,XRD,particle size distribution and TEM.Results showed that the non-aggregation granular nanometer zinc phosphate with particle size distribution between 59~79 nm and average particle size of 68 nm could be prepared under the technological conditions as follows:c（CTAB）=9×10-4mol/L,grinding time was 3 h,zirconium ball as grinding medium,mass ratio of ball to material was 150:1,grinding ball mass ratio of Φ10 mm and Φ6 mm was 1:4,rotating speed was 200 r/min and solid-liquid ratio[mass ratio of zinc oxide to（phosphoric acid+surfactant）] was 1:1.
Key words： zinc phosphate; nano-particle; controlled-synthesis
Xinyi Chen , Yunlong Huang , Aiqun Yuan , Zengwei Huang , Dongping Wei , Shaomei Ma . Controlled-synthesis of nanometer zinc phosphate[J]. Inorganic Chemicals Industry, 2019 , 51(8) : 20 -24 . DOI: 10.11962/1006-4990.2018-0524
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