高掺量改性半水磷石膏墙体材料力学性能研究

doi:10.19964/j.issn.1006-4990.2024-0287

Abstract

Abstract:

In order to improve the resource utilization rate of phosphogypsum，the modified hemihydrate phosphogypsum wall materials（MPGWM） was prepared by adding quicklime and melamine water reducing agent（SM） to hemihydrate phosphogypsum（HPG）.The control variable method was used to study the effect of water-cement ratio and water reducing agent content on the mechanical properties of MPGWM，combined with the multiple regression model to analyze the variation rule of the mechanical properties of MPGWM under the action of two-factor coupling，and to obtain the optimal ratio of the high content modified hemihydrate phosphogypsum wall materials.The results showed that the main failure characteristics of the cubic compressive strength test of high content MPGWM specimens were splitting failure and conical failure，and the failure pattern of the cubic splitting tensile test was typical splitting failure.The apparent density of the specimens was mainly derived from HPG and quicklime.The apparent density and mechanical properties of MPGWM specimens were greatly affected by water-cement ratio，followed by the amount of water reducing agent.When the content of SM was 1.0% and the water-cement mass ratio was 0.29，the cube compressive strength of the specimens could reach 27.87 MPa.When the content of SM was 1.0% and the water-cement mass ratio was 0.32，the splitting tensile strength could reach 1.92 MPa.Through regression analysis，the optimal mix ratio of MPGWM was predicted to be 97%（mass fraction） HPG，3% quicklime，water-cement mass ratio of 0.27，and water reducer dosage of 1.2% of the HPG and quicklime mixture.The research results could provide reference for the resource utilization of phosphogypsum and promote the sustainable development of phosphorus chemical enterprises.

Key words: hemihydrate phosphogypsum, collaborative modification, water reducing agent, mechanical properties

CLC Number:

TQ177.37

LONG Qijun, WU Qin, TAO Jia, CHEN Chuanxiang, WANG Jianxiang, YU Fang. Study on mechanical properties of high content modified hemihydrate phosphogypsum wall materials[J]. Inorganic Chemicals Industry, 2025, 57(4): 89-96.

Figures/Tables 12

Table 1

Fig.1

Fig.2

Fig.3

Table 2

Table 3

Fig.4

Fig.5

Fig.6

Fig.7

Fig.8

Fig.9

References 32

[1]	SAADAOUI E， GHAZEL N， ROMDHANE C BEN，et al.Phosphogypsum：Potential uses and problems：A review［J］.International Journal of Environmental Studies，2017，74（4）：558-567.
[2]	邹文敏，陈志华，李志刚，等.新型半水-二水法磷酸工艺的技术优势［J］.磷肥与复肥，2016，31（8）：34-38.
	ZOU Wenmin， CHEN Zhihua， LI Zhigang，et al.Technical advantages of hemi-dihydrate process phosphoric acid technology［J］.Phosphate & Compound Fertilizer，2016，31（8）：34-38.
[3]	GUAN Qingjun， WANG Zhuang， ZHOU Fujia，et al.The impurity removal and comprehensive utilization of phosphogypsum：A review［J］.Materials，2024，17（9）：2067.
[4]	崔荣政，白海丹，高永峰，等.磷石膏综合利用现状及“十四五” 发展趋势［J］.无机盐工业，2022，54（4）：1-4.
	CUI Rongzheng， BAI Haidan， GAO Yongfeng，et al.Current situation of comprehensive utilization of phosphogypsum and its development trend of 14th Five-Year Plan［J］.Inorganic Chemicals Industry，2022，54（4）：1-4.
[5]	张峻，解维闵，董雄波，等.磷石膏材料化综合利用研究进展［J］.材料导报，2023，37（16）：167-178.
	ZHANG Jun， XIE Weimin， DONG Xiongbo，et al.Research progress on comprehensive utilization of phosphogypsum for materials：A review［J］.Materials Reports，2023，37（16）：167-178.
[6]	LI Bing， SHU Jiancheng， YANG Lu，et al.An innovative method for simultaneous stabilization/solidification of PO₄ ^3- and F^- from phosphogypsum using phosphorus ore flotation tailings［J］.Journal of Cleaner Production，2019，235：308-316.
[7]	叶婷婷，丁坚平，褚学伟.乌江34号泉磷污染预测［J］.贵州大学学报（自然科学版），2017，34（3）：115-120.
	YE Tingting， DING Jianping， ZHU Xuewei.Phosphorus pollution prediction of No.34 spring in Wujiang Town［J］.Journal of Guizhou University（Natural Sciences），2017，34（3）：115-120.
[8]	WU Fenghui， CHEN Bangjin， QU Guangfei，et al.Harmless treatment technology of phosphogypsum：Directional stabilization of toxic and harmful substances［J］.Journal of Environmental Management，2022，311：114827.
[9]	邓华，侯硕旻，李中军，等.磷石膏综合利用现状及展望［J］.无机盐工业，2024，56（1）：1-8，22.
	DENG Hua， HOU Shuomin， LI Zhongjun，et al.Update and future of phosphogypsum reuse［J］.Inorganic Chemicals Industry，2024，56（1）：1-8，22.
[10]	CHERNYSH Y， YAKHNENKO O， CHUBUR V，et al.Phosphogypsum recycling：A review of environmental issues，current trends，and prospects［J］.Applied Sciences，2021，11（4）：1575.
[11]	MURALI G， AZAB M.Recent research in utilization of phosphogypsum as building materials：Review［J］.Journal of Materials Research and Technology，2023，25：960-987.
[12]	LV Xinfeng， XIANG Lan.The generation process，impurity removal and high-value utilization of phosphogypsum material［J］.Nanomaterials，2022，12（17）：3021.
[13]	郭泽，张鹏飞，杨帆，等.磷石膏焙烧法制备β-半水石膏［J］.无机盐工业，2023，55（10）：106-113.
	GUO Ze， ZHANG Pengfei， YANG Fan，et al.Preparation of β-hemihydrate gypsum by phosphogypsum roasting［J］.Inorganic Chemicals Industry，2023，55（10）：106-113.
[14]	朱干宇，孟子衡，李会泉，等.磷资源高效利用制备磷酸技术现状探讨［J］.磷肥与复肥，2023，38（7）：24-30，35.
	ZHU Ganyu， MENG Ziheng， LI Huiquan，et al.Current status of phosphoric acid preparation technology for efficient utilization of phosphorus resources［J］.Phosphate & Compound Fertilizer，2023，38（7）：24-30，35.
[15]	WING J，陈靖宇.半水法湿法磷酸工艺技术的节能优点［J］.化肥设计，2009，47（4）：56-59.
	WING J， CHEN Jingyu.Energy-conservation advantages for phosphoric acid process technology by semi-water method and wet method［J］.Chemical Fertilizer Design，2009，47（4）：56-59.
[16]	CHEN Xuemei， GAO Jianming， ZHAO Yasong.Investigation on the hydration of hemihydrate phosphogypsum after post treatme-nt［J］.Construction and Building Materials，2019，229：116864.
[17]	WANG Qiang， CUI Yong， XUE Junfeng.Study on the improvement of the waterproof and mechanical properties of hemihydrate phosphogypsum-based foam insulation materials［J］.Construction and Building Materials，2020，230：117014.
[18]	苗训，孔德文，付汝宾，等.轻质泡沫磷石膏墙体材料制备与性能研究［J］.非金属矿，2021，44（6）：34-37.
	MIAO Xun， KONG Dewen， FU Rubin，et al.Preparation and properties of light foam phosphogypsum wall materials［J］.Non-Metallic Mines，2021，44（6）：34-37.
[19]	李兵兵，李建锡，陈思功，等.磷石膏制备轻质墙体材料试验研究［J］.硅酸盐通报，2012，31（2）：362-365，376.
	LI Bingbing， LI Jianxi， CHEN Sigong，et al.Experimental study on lightweight mural material with phosphogypsum［J］.Bulletin of the Chinese Ceramic Society，2012，31（2）：362-365，376.
[20]	袁书成，刘香玲，梁危，等.磷石膏填充墙研究现状与应用进展［J］.无机盐工业，2021，53（4）：8-13.
	YUAN Shucheng， LIU Xiangling， LIANG Wei，et al.Research status and application progress of phosphogypsum infilled walls［J］.Inorganic Chemicals Industry，2021，53（4）：8-13.
[21]	熊有为.基于半水磷石膏自胶凝充填材料膏体特性实验研究［J］.矿业研究与开发，2018，38（1）：15-19.
	XIONG Youwei.Experimental study on paste characteristics of selfgelling filling materials based on the semi-water phosphogypsum［J］.Mining Research and Development，2018，38（1）：15- 19.
[22]	JIANG Guanzhao， WU Aixiang， WANG Yiming，et al.Low cost and high efficiency utilization of hemihydrate phosphogypsum：Used as binder to prepare filling material［J］.Construction and Building Materials，2018，167：263-270.
[23]	吴爱祥，王勇，王洪江.膏体充填技术现状及趋势［J］.金属矿山，2016（7）：1-9.
	WU Aixiang， WANG Yong， WANG Hongjiang.Status and prospects of the paste backfill technology［J］.Metal Mine，2016（7）：1-9.
[24]	姜关照，吴爱祥，王贻明，等.生石灰对半水磷石膏充填胶凝材料性能影响［J］.硅酸盐学报，2020，48（1）：86-93.
	JIANG Guanzhao， WU Aixiang， WANG Yiming，et al.Effect of lime on properties of filling cementitious material prepared by hemihydrate phosphogypsum［J］.Journal of the Chinese Ceramic Society，2020，48（1）：86-93.
[25]	朱雪涛，杜兵，阿曼角，等.半水磷石膏地下充填材料的磷和氟浸出特性及地球化学模拟［J］.中国环境科学，2022，42（2）：680-687.
	ZHU Xuetao， DU Bing， Manjiao A，et al.Leaching properties of phosphorus and fluorine in hemihydrate phosphogypsum as underground filiing materials and geochemical simulation［J］.China Environmental Science，2022，42（2）：680-687.
[26]	杨林，曹建新，刘亚明.半水磷石膏的矿物学特征［J］.岩石矿物学杂志，2015，34（6）：827-834.
	YANG Lin， CAO Jianxin， LIU Yaming.Mineralogical characteristics of hemi-hydrate phosphogypsum［J］.Acta Petrologica et Mineralogica，2015，34（6）：827-834.
[27]	QI Huahui， TANG Dongjie， MA Baoguo，et al.Influence of H₃PO₄ and H₂PO₄ ^- on the performance of PCE in hemihydrate gypsum pastes［J］.Construction and Building Materials，2023，394：132062.
[28]	CHEN Xuemei， WANG Qingyuan， WU Qihong，et al.Hydration reaction and microstructural characteristics of hemihydrate phosphogypsum with variable pH［J］.Construction and Building Materials，2022，316：125891.
[29]	DUAN Shuqian， ZHANG Minghuan， XU Dingping，et al.Mechanical response and data-driven fatigue model of interlayer soils in track-bed considering multi-factor coupling effect［J］.Computers and Geotechnics，2023，163：105749.
[30]	于蕾，张金喜.多因素耦合作用下水泥胶凝材料劣化试验方法和评价指标的探讨［J］.混凝土，2013（1）：58-62.
	YU Lei， ZHANG Jinxi.Study on experimental method and evaluation indexes for cement binders corroded by environment［J］.Concrete，2013（1）：58-62.
[31]	孟文清，冀昊，刘金堂，等.石灰-钢渣-煤矸石混合料力学性能试验研究［J］.粉煤灰综合利用，2023，37（6）：99-104.
	MENG Wenqing， JI Hao， LIU Jintang，et al.Experimental study on mechanical properties of lime-steel slag-coal gangue mixtu-re［J］.Fly Ash Comprehensive Utilization，2023，37（6）：99-104.
[32]	YU Lei， ZHOU Cuiying， LIU Zhen，et al.Scouring abrasion properties of nanomodified concrete under the action of chloride diffusion［J］.Construction and Building Materials，2019，208：296- 303.

试件编号	混合物各成分质量分数/%		影响因素
试件编号	HPG	生石灰	水灰比	减水剂掺量/%
PD1	97	3	0.27	0
PD2	97	3	0.28	0.5
PD3	97	3	0.29	1.0
PD4	97	3	0.32	1.5
PD5	97	3	0.36	2.0
PD6	97	3	0.40	1.5
PD7	97	3	0.42	1.0
PD8	97	3	0.50	0.5

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on mechanical properties of high content modified hemihydrate phosphogypsum wall materials

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 12

References 32

Related Articles 15

Metrics

Comments

Recommended 0

[1]	HAN Yingming, SUN Ruize, SUN Yining, SONG Xingfei. Study on properties of modified magnesia sulfide cement by calcined coal gangue powder [J]. Inorganic Chemicals Industry, 2025, 57(4): 97-104.
[2]	LIU Cijun, WU Ziyang, CHENG Shukai, CHEN Xuyong. Effect of recycled fine aggregate on mechanical properties and autogenous shrinkage of ultra-high performance concrete [J]. Inorganic Chemicals Industry, 2024, 56(9): 75-81.
[3]	ZHANG Ruijun, CHEN Guoliang, SONG Chuncao, ZHU Yafei. Effects of graphene oxide on mechanical properties and chloride penetration resistance of ultra⁃high performance concrete incorporating recycled sand [J]. Inorganic Chemicals Industry, 2024, 56(8): 54-59.
[4]	YU Zhou, HE Zhaoyi, TANG Liang, HE Sheng, XIAO Haixin, XIAO Yixun. Study on preparation and microscopic properties of typical sulfate solid waste composite cementitious materials [J]. Inorganic Chemicals Industry, 2024, 56(4): 90-97.
[5]	LI Keke, XUE Jiangwei, WANG Luwei, GUAN Xuemao. Effect of MgAl-layered double hydroxides on properties of high-iron low-calcium portland cement [J]. Inorganic Chemicals Industry, 2024, 56(4): 57-63.
[6]	CUI Gengyin, XIE Lang, LU Yuexian, KONG Dewen, WANG Lingling. Optimization of mechanical properties of basalt fiber reinforced phosphogypsum-based composites based on RSM [J]. Inorganic Chemicals Industry, 2023, 55(8): 116-123.
[7]	WANG Yue, FANG Guoxiang, ZHANG Daoming, WANG Weicheng. Effect of nanosilica on gelling properties of hydraulic lime [J]. Inorganic Chemicals Industry, 2023, 55(7): 75-80.
[8]	XU Li, FANG Keneng, BI Yongxiang, YANG Min, CHEN Qianlin. Preparation of modified granular-like CaSO4 and its application in polyvinyl chloride [J]. Inorganic Chemicals Industry, 2023, 55(3): 104-112.
[9]	ZHANG Yanru, REN Changzai, SONG Zhanlong, ZHU Jianjun, ZHAO Baofeng, XIE Hongzhang, WANG Zhenjiang, QI Xiaole. Study on performance of biomass power plant ash as alternative to cement clinker in blended cements [J]. Inorganic Chemicals Industry, 2023, 55(10): 128-135.
[10]	CHEN Mingsheng,LIU Peng,KONG Dewen,LI Yuan,YU Ke,HUANG Yansen,WU Ningbo,CHANG Juanjuan. Effect of external admixtures on mechanical and thermal conductivity of phosphogypsum composite cementitious materials [J]. Inorganic Chemicals Industry, 2022, 54(9): 113-118.
[11]	XU Lihua,HUANG Zheng,ZHANG Xing,DU Huaiming,CHEN Xiaochao,HUANG Bin. Preparation and properties of composite materials from natural gas?based acetylene process produced carbon black and silica [J]. Inorganic Chemicals Industry, 2022, 54(5): 121-125.
[12]	MIAO Xun,LU Yuexian,FU Rusong,KONG Dewen,FU Rubin,HU Qun. Hemihydrate phosphogypsum as used to solidify the raw phosphogypsum to prepare composite cementitious material [J]. Inorganic Chemicals Industry, 2022, 54(4): 10-16.
[13]	WANG Yuan,WANG Zhi,QIN Hongyi. Study on properties of wet detoxification Fe-Cr slag as concrete admixture [J]. Inorganic Chemicals Industry, 2022, 54(3): 87-90.
[14]	LÜ Fangtao,ZHOU Yinsheng,KONG Dewen,CHEN Sihan,AN Hongfang,WANG Lingling. Effect of hybrid fiber on properties of desulfurized gypsum based composite cementitious material [J]. Inorganic Chemicals Industry, 2022, 54(10): 127-132.
[15]	Liu Yuhong,Yin Chunlin,Ma Shunyou,Yan Xin,Yuan Xiaochao,Leng Jianjun,Zhang Jin. Preparation of colored zirconia ceramics by adding alumina-chrome slag from aluminothermic reduction [J]. Inorganic Chemicals Industry, 2021, 53(3): 78-83.