Inorganic Chemicals Industry ›› 2022, Vol. 54 ›› Issue (5): 138-143.doi: 10.19964/j.issn.1006-4990.2021-0583
• Catalytic Materials • Previous Articles Next Articles
Study on analysis of activation process of pre?sulfurized catalysts by X-ray photoelectron spectroscopy depth profiling technology
ZHANG Dandan(
)
- CNOOC Research Institute of Refining and Petrochemicals，Beijing 102209，China
-
Received:2021-09-26Online:2022-05-10Published:2022-05-31
CLC Number:
Cite this article
ZHANG Dandan. Study on analysis of activation process of pre?sulfurized catalysts by X-ray photoelectron spectroscopy depth profiling technology[J]. Inorganic Chemicals Industry, 2022, 54(5): 138-143.
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Fig.1
Diagram of double?layer stacking for catalyst samples"
Fig.1
Fig.2
Shift relationship between etching rate of SO42- andbinding energy of Mo4+ peak under different etching conditions"
Fig.2
Fig.3
Mo 3d peak of pre?sulfurized catalyst underetching condition of 20 keV/500Ar/60s"
Fig.3
Fig.4
Ni 2p peak of pre?sulfurized catalyst underetching condition of 20 keV/500Ar/60s"
Fig.4
Fig.5
Peak fitting result of Mo 3d of pre?sulfurized catalyst"
Fig.5
Fig.6
Peak fitting result of Ni 2p of pre?sulfurized catalyst"
Fig.6
Fig.7
Peak fitting result of S 2p of pre?sulfurized catalyst"
Fig.7
Fig.8
Powder diffraction analysis of pre?sulfurizedcatalysts with different activation time"
Fig.8
Fig.9
Element distribution in cross section of pre?sulfurized catalysts（SEM-EDS-mapping）"
Fig.9
Fig.10
Chemical state analysis of Mo and Ni of pre?sulfurized catalysts powder samples with different activation time"
Fig.10
Fig.11
Changes of SO42- content during particle depth profiling of pre?sulfurized catalysts with different activation time"
Fig.11
Fig.12
Changes of Mo6+ content during particle depth profiling of pre?sulfurized catalysts with different activation time"
Fig.12
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