基于表面改性石墨毡复合材料的超级电容器研究进展

doi:10.19964/j.issn.1006-4990.2024-0219

Abstract

Abstract:

As a traditional electrode material，graphite felt（GF） has a unique three-dimensional porous structure and good electrical conductivity，however，it has inherent defects such as poor surface wettability and insufficient electrochemical activity.To address these problems，the researchers focused on the activation of the graphite felt substrate by introducing specific functional groups or nanostructures using physical，chemical and electrochemical methods in order to develop composite electrode materials with superior properties for applications in the field of efficient energy storage.Based on the introduction of graphite felt characteristics and energy storage mechanism，the modification advantages of transition metal compounds，conducting polymers and carbonaceous materials on GF substrates，and doping with heteroatoms（O，S，N，etc.） to regulate the surface wettability，conductivity and electrocatalytic activity of GF were reviewed.Furthermore，the application prospect of GF composite materials in wearable devices and lightweight energy storage devices was highlighted.Meanwhile，it was also pointed out the challenges of GF composites in the precise regulation of the preparation process.In the future，with the continuous development of material science，surface treatment technology and electrochemical theory，GF surface modification was expected to emerge more innovative technologies and provide theoretical support for the commercial application of supercapacitors.

Key words: graphite felts, surface modification, supercapacitors, carbon materials

CLC Number:

TM53

WANG Zhiyu, SONG Kun, SHEN Miao, SHEN Ping, XIAO Peiyao, YANG Chunming. Research progress of supercapacitors based on surface modified graphite felt composite materials[J]. Inorganic Chemicals Industry, 2025, 57(4): 11-21.

Figures/Tables 10

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Table 1

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掺杂物质	电流密度	比电容
O原子^［32］	15 mA/cm²	3.34 F/cm²
O原子^［33］	23 mA/g	205 F/g
N原子^［34］	0.1 A/g	222 F/g
GR分散体^［36］	20 mA/g	8.67 F/g
CNT^［37］	1 A/g	316 F/g
生物质炭^［38］	1 A/g	255 F/g
PPy^［40］	0.5 A/cm²	527.5 mF/cm²
PHQ^［41］	0.08 mA/cm²	129.4 F/m²
PPy^［42］	0.25 A/g	190 F/g
MnO₂^［44］	1.4 mA/cm²	832 mF/cm²
NiCo₂O₄^［45］	2 mA/g	243.1 mA∙h/g
Co₂（OH）₂CO₃与Ni-P^［46］	1 mA/cm²	1 360 mF/cm²
Co（OH）₂与Ni（OH）₂^［47］	5 mA/cm²	567.6 F/g
MXene （Ti₃C₂T _x ）^［48］	0.25 A/g	55.4 F/g
MnCo氧化物^［49］	2 A/g	854 F/g
FePO₄与PANI^［50］	1 mA/cm²	2 606.8 mF/cm²
V₂O₅与PIn^［51］	1 mA/cm²	2 254 mF/cm²
Co²⁺掺杂PANI^［52］	0.2 A/g	562 F/g
PPy与MnO₂^［53］	0.5 A/g	821.3 F/g
PPy与NiCoSe₂^［54］	0.025 A/cm³	5.21 F/cm³
GR与MnO₂^［55］	4 A/g	129 F/g

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Research progress of supercapacitors based on surface modified graphite felt composite materials

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