二硫化钼基全pH电催化析氢材料研究进展

doi:10.19964/j.issn.1006-4990.2020-0674

Abstract

Abstract:

As a green hydrogen production technology, electrolyzed water splitting has received lots of attention.Design and development of high-efficient and low-cost electrocatalysts,which are suitable for full pH（pH=0-14) media,can reduce ener-gy consumption,simplify device construction and optimize production process.MoS₂ has been considered as one of the pro-mising materials for electrochemical hydrogen evolution,due to its tunable electronic structure and the most suitable thermo-dynamic activity except for precious metals.The current research progress of MoS₂-based pH-universal catalysts for electro-chemical hydrogen evolution reaction was reviewed,such as modulating physical property of intrinsic MoS₂,surface engineer-ing with atom doping,and interface engineering.The corresponding catalytic mechanism was clarified.It was revealed that preparation of catalysts with both hydrogen evolution activity and stability at high current density in all-pH range would be the tendency of electrocatalytic materials.It was also proposed that activation of inert basal plane for multi-level structural MoS₂ materials,enhancement of the whole electroconductivity,anchor of single atoms precisely,and encapsulation of active materials with porous carbon would be the fundamental strategies for designing efficient pH-universal catalysts.

Key words: MoS₂, pH-universal, electrocatalytic hydrogen evolution, electrolysis of water

CLC Number:

TQ136.12

GONG Feilong,LIU Yuheng,LIU Mengmeng,WANG Guoqing. Research progress on pH-universal MoS₂-based materials for electrocatalytic hydrogen evolution[J]. Inorganic Chemicals Industry, 2021, 53(11): 1-9.

Figures/Tables 4

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Research progress on pH-universal MoS₂-based materials for electrocatalytic hydrogen evolution

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