基于硫电极设计实现贫电解液锂硫电池的最新研究进展

doi:10.19964/j.issn.1006-4990.2024-0329

Abstract

Abstract:

Lithium sulfur batteries（LSBs） have attracted considerable attention as promising next-generation energy storage devices due to their high theoritical energy density.Although the electrochemical performance of LSBs has been significantly enhanced over the past decade，most of their test condition is based on excessive electrolyte usage.High electrolyte usage not only increases the manufacturing cost of batteries but also reduces their actual energy density，Which is detrimental to commercial applications of LSBs.Therefore，it is especially critical to develop LSBs that combine low electrolyte usage with excellent electrochemical performance.The challenges faced by LSBs under lean electrolyte conditions were outlined and the approaches based on sulfur electrode design to reduce electrolyte usage were discussed in detail：1）optimizing electrode porosity and ion conduction to shorten the transport path of lithium ions and enhance their conductivity；2）introducing meta-based or nonmetallic-based catalysis to enhance the reaction kinetics of active materials under lean electrolyte conditions；3）developing novel active materials to avoid the degradation of battery performance caused by the large amount of lithium polysulfides dissolved in the electrolyte under lean electrolyte conditions.Finally，the perspectives on further optimizing the design of sulfur cathode to develop high-energy-density LSBs with lean electrolyte were proposed.

Key words: lithium sulfur batteries, sulfur electrode design, lean electrolyte

CLC Number:

TQ152

CHEN Xue, JIANG Guanghui, OUYANG Quansheng, SHAO Jiaojing. Recent research progress of lithium sulfur batteries under lean electrolyte based on sulfur electrode design[J]. Inorganic Chemicals Industry, 2025, 57(2): 1-13.

Figures/Tables 7

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Table 1

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采用策略和实施方法		硫载量/ （mg·cm^-2）	E/S	循环次数	比容量初/末/ （mA·h·g^-1）	能量密度初/末/ （W·h·kg^-1）	文献
降低电极迂曲度	冰模板法	6.00	1.2	1	1 200/－	481/－	［10］
降低电极迂曲度	冰模板法	8.80	2.0	50	984/－	338/－	［11］
降低电极孔隙率	采用大颗粒尺寸电极	4.00	4.0	30	1 001/－	－	［14］
创建离子传输通道	P-10黏结剂	6.00	4.0	100	1 182/749	344.5/271.4	［16］
	HMT-PMBI（TFSI）黏结剂	3.00	6.0	440	796/500	172/－	［17］
	CWPU黏结剂	6.68	8.0	35	739/617	－	［18］
	BVIM黏结剂	5.50	6.4	50	745/600	－	［20］
引入金属基催化剂	MoP	6.00	6.0	50	/830	－	［27］
	TiN/TiO₂@NMPC	8.20	4.7	200	811/572	－	［28］
	CNTs@TiN-TiO₂	15.00	10.0	100	1 433/1326	－	［29］
	Co_0.9Zn_0.1Te₂@NC	7.70	4.0	30	1 662/998	－	［32］
	Li _x MoS₂	7.50	2.4	200	1 094/932	441/350	［31］
	CoNiFePdV	4.50	5.0	100	710/572	－	［33］
	FeCoNiZnCu	4.52	7.0	80	637/467	－	［34］
	MnP-MnO₂@C	7.10	5.0	11	1 199/1 015	429/362.3	［47］
	TiO₂/TiS₂	7.50	2.5	30	773/703	331/301	［48］
	CuBr QDs/rGO	8.00	3.0	50	1 075/750	375/261	［50］
引入非金属基催化剂	PCNF/BPQD	8.00	6.5	200	618/550	－	［37］
	NF@VG	13.00	4.8	100	984/826	－	［38］
	WLC-CNTs	52.40	6.0	100	1 245/692	－	［41］
	g-C₃N₄/rGO/S@PPy	5.00	10.0	100	723/600	－	［42］
	rGO/g-C₃N₄ QDs	16.10	6.0	100	1 006/820	－	［39］
新型活性材料	PAN@S	5.75	2.14	25	448.4/396	822.5/798 基于正/负极计算	［44］
	PAN@S_0.96Te_0.04	3.11	6.00	100	－/870	－	［45］
	STI-5	4.50	8.00	130	－/817	－	［46］

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Inorganic Acid-Base-Salt Committee of CIESC

Recent research progress of lithium sulfur batteries under lean electrolyte based on sulfur electrode design

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