稀磁半导体Cr掺杂CdS纳米结构及磁性能研究

doi:10.19964/j.issn.1006-4990.2024-0095

Abstract

Abstract:

In response to the widespread application of dilute magnetic semiconductor nanomaterials in electronic components，semiconductor chips，integrated circuits，and other fields，based on solvent thermal method，a dilute magnetic semiconductor with room temperature ferromagnetic Cr-doped CdS nanostructures was synthesized by solvothermal method using CdO，S powder，hexahydrate chromium chloride（CrCl₃·6H₂O） as raw materials，ethanolamine，and ethylenediamine as organic solvents at 180 ℃.The crystal structure，morphology，optical properties，and magnetic properties of the samples were detected using X-ray diffraction（XRD），transmission electron microscopy（TEM），electron energy scattering spectroscopy（EDS），ultraviolet visible absorption spectroscopy（UV-Vis），and superconducting magnet vibration sample magnetometer（VSM）.The results indicated that Cr-doped CdS nanostructures had a wurtzite structure，and the average particle size of Cd_1-_x Cr _x S（x=3.94%） nanoparticles with regular morphology in the range of 30~40 nm.The synthetic product，composed of Cr，Cd，and S，was observed，the highest content of Cr-doped CdS nanoparticles was 7.16%（Cr atomic）.At room temperature，Cr-doped CdS produced enhanced ferromagnetism，while undoped CdS produced weak ferromagnetism.The saturation magnetization $M s$ of the Cd₁_-x Cr _x S（x=3.94%） nanoparticles was 9.258×10^-6A·m²/g，and the coercivity of $H c$ was 73.25 Oe（1 Oe=10³/4π A/m）.The ferromagnetic origin of Cr-doped CdS was related to the structural defects generated by Cr doping in the CdS lattice.The ferromagnetic origin of Cr-doped CdS was related to the structural defects generated by Cr doping in the CdS lattice，the origin of Cr-doped CdS ferromagnetism was attributed to the double exchange mechanism.

Key words: Cr-doped CdS, nanostructure, ferromagnetism, solvothermal

CLC Number:

TQ136.1

ZHANG Zhufeng, REN Yinshuan. Study on diluted magnetic semiconductor Cr-doped CdS nanostructures and magnetic properties[J]. Inorganic Chemicals Industry, 2025, 57(3): 50-57.

Figures/Tables 7

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

Fig.7

References 41

1	冯彬，刘晓凤，姚鹏飞，等.白光SrMoO₄：Eu³⁺，K⁺@g-C₃N₄荧光粉的合成及其性能研究［J］.无机盐工业，2023，55（8）：95-101.
	FENG Bin， LIU Xiaofeng， YAO Pengfei，et al.Syudy on synthesis and properties of white light SrMoO₄：Eu³⁺，K⁺@g-C₃N₄ phospho-rs［J］.Inorganic Chemicals Industry，2023，55（8）：95-101.
2	HE Weidong， WANG Chenggang， ZHUGE Fuwei，et al.Flexible and high energy density asymmetrical supercapacitors based on core/shell conducting polymer nanowires/manganese dioxide nanoflakes［J］.Nano Energy，2017，35：242-250.
3	ZHANG Ke， FUJITSUKA M， DU Yukou，et al.2D/2D heterostructured CdS/WS₂ with efficient charge separation improving H₂ evolution under visible light irradiation［J］.ACS Applied Materials & Interfaces，2018，10（24）：20458-20466.
4	WANG Sheng， ZHU Bicheng， LIU Mingjin，et al.Direct Z-scheme ZnO/CdS hierarchical photocatalyst for enhances photocatalytic H₂-production activity［J］.Applied catalysis B：Environmental，2019，243：19-26.
5	韩新兰，李金花，李亚瑜，等.Pb-MoF的制备过程对MAPbBr₃@MoF复合材料光性能的影响［J］.山东化工，2023，52（16）： 62-66.
	HAN Xinlan， LI Jihua， LI Yayu，et al.The preparation process of Pb MoF affects MAPbBr₃@MoF influence of optical properties of composite materials［J］.Shandong Chemical Industry，2023，52（16）： 62-66.
6	周嵬，张云龙，崔朝军.硫化铋材料的水热与溶剂热制备进展［J］.兵器材料科学与工程，2023，46（4）：142-147.
	ZHOU Wei， ZHANG Yunlong， CUI Chaojun.Progress in hydrothermal and solvothermal preparation of bismuth sulfide materi-als［J］.Ordnance Material Science and Engineering，2023，46（4）：142-147.
7	李典韬，盖广清.溶剂热法制备BiOI材料及其光催化性能研究［J］.化工技术与开发，2023，52（4）：24-27.
	LI Diantao， GAI Guangqing.Photocatalytic properties of BiOI materials prepared by solvothermal method［J］.Technology & Development of Chemical Industry，2023，52（4）：24-27.
8	张晓勇，张琰春，张晓玉，等.化学水浴沉积法制备硫化镉薄膜的微结构和性能［J］.人工晶体学报，2021，50（2）：310-317.
	ZHANG Xiaoyong， ZHANG Yanchun， ZHANG Xiaoyu，et al.Microstructure and properties of cadmium sulfide thin films prepared by chemical bath deposition［J］.Journal of Synthetic Crystals，2021，50（2）：310-317.
9	李宝珠，高彦昭，王健，等.高质量CdSe单晶生长及其OPO性能研究［J］.人工晶体学报，2020，49（8）：1517-1522.
	LI Baozhu， GAO Yanzhao， WANG Jian，et al.Growth and optical parametric oscillator properties of high quality CdSe single cryst-al［J］.Journal of Synthetic Crystals，2020，49（8）：1517-1522.
10	陈俊雪，莫建欣，周治宇，等.NaFe _x Cr _y （SO₄）₂（OH）₆的合成及电化学性能研究［J］.无机盐工业，2023，55（8）：71-76.
	CHEN Junxue， MO Jianxin， ZHOU Zhiyu，et al.Study on synthesis of NaFe _x Cr _y （SO₄）₂（OH）₆ and their electrochemical properti-es［J］.Inorganic Chemicals Industry，2023，55（8）：71-76.
11	CHEN Lin， DE ANGELIS F， JIN Song，et al.Energy research outlook：What to look for in 2018［J］.ACS Energy Letters，2018，3（1）：261-263.
12	SHAO Zhuwang， HE Yinna， ZENG Tiantian，et al.Highly efficient photocatalytic H₂ evolution using the Ni₂P-Zn_0.5Cd_0.5S photocatalyst under visible light irradiation［J］.Journal of Alloys and Compounds，2018，769：889-897.
13	王建芳，杨和平，李凯斌，等.C₃N₄/MnCo₂S₄复合材料的制备及其电容性能研究［J］.无机盐工业，2023，55（7）：70-74.
	WANG Jianfang， YANG Heping， LI Kaibin，et al.Study on preparation of C₃N₄/MnCo₂S₄ composites and their capacitive properties［J］.Inorganic Chemicals Industry，2023，55（7）：70-74.
14	COUNIO G， GACOIN T， BOILOT J P.Synthesis and photoluminescence of Cd_1- _x Mn _x S（x≤5） nanocrystals［J］.The Journal of Physical Chemistry B，1998，102（27）：5257-5260.
15	LEVY L， FELTIN N， INGERT D，et al.Three dimensionally diluted magnetic semiconductor clusters Cd_1- _y Mn _y S with a range of sizes and compositions：ependence of spectroscopic properties on the synthesis mode［J］.The Journal of Physical Chemistry B，1997，101（45）：9153-9160.
16	ELANGO M， GOPALAKRISHNAN K， VAIRAM S，et al.Structural，optical and magnetic studies on non-aqueous synthesized CdS：Mn nanomaterials［J］.Journal of Alloys and Compounds，2012，538：48-55.
17	陈旭，杨刚，李海涛，等.多级孔纳米SAPO-34分子筛制备及甲醇制性能烯烃性能研究［J］.无机盐工业，2024，56（1）： 134-140.
	CHEN Xu， YANG GANG， LI Haitao，et al.Study on preparation of multistage pore nano-SAPO-34 molecular sieves and its methanol to olefin performance［J］.Inorganic chemicals industry，2024，56（1）： 134-140.
18	JIANG Fengxian， XU Xiaohong， ZHANG Jun，et al.Role of carrier and spin in tuning ferromagnetism in Mn and Cr-doped In₂O₃ thin films［J］.2010，96（5）：052503.
19	ZHANG S X， OGALE S B， KUNDALIYA D C，et al.Search for ferromagnetism in conductive Nb：SrTiO₃ with magnetic transition element（Cr，co，Fe，Mn） dopants［J］.2006，89（1）：012501.
20	MADHU C， SUNDARESAN A， RAO C N R.Room-temperature ferromagnetism in undoped GaN and CdS semiconductor nano-particles［J］.Physical Review B，2008，77（20）：201306.
21	AL-DOURI Y， RESHAK A H.Analytical investigations of CdS nanostructures for optoelectronic applications［J］.Optik，2015，126（24）：5109-5114.
22	ZHANG Zhufeng， LI Jin， JIAN Jikang，et al.Preparation of Cr-doped ZnS nanosheets with room temperature ferromagnetism via a solvothermal route［J］.Journal of Crystal Growth，2013，372：39-42.
23	LIU H X， WU S Y， SINGH R K，et al.Observation of ferromagnetism above 900K in Cr-GaN and Cr-AlN［J］.2004，85（18）：4076-4078.
24	GOEL S， SINHA N， YADAV H，et al.Experimental investigation on the structural，dielectric，ferroelectric and piezoelectric properties of La doped ZnO nanoparticles and their application in dye-sensitized solar cells［J］.Physica E：Low-Dimensional Systems and Nanostructures，2017，91：72-81.
25	GUPTA R， CHAUHAN R P， CHAKARVARTI S K，et al.Effect of SHI on properties of template synthesized Cu nanowires［J］.Ionics，2019，25（1）：341-352.
26	ELAVARTHI P， KUMAR A A， MURALI G，et al.Room temperature ferromagnetism and white light emissive CdS：Cr nanoparticles synthesized by chemical co-precipitation method［J］.Journal of Alloys and Compounds，2016，656：510-517.
27	FU Xianliang， ZHANG Li， LIU Lihua，et al. In situ photodeposition of MoS _x on CdS nanorods as a highly efficient cocatalyst for photocatalytic hydrogen production［J］.Journal of Materials Che-mistry A，2017，5（29）：15287-15293.
28	WANG Qingsheng， XU Zhude， YUE Linhai，et al.Characteristics and optical properties of Cd_1- _x Mn _x S nanorods prepared through hydrothermal route［J］.Optical Materials，2004，27（3）：453-458.
29	KAYANUMA Y.Quantum-size effects of interacting electrons and holes in semiconductor microcrystals with spherical shape［J］.Physical Review B，1988，38（14）：9797-9805.
30	金声势，刘凯杰，刘秋文，等.磷酸改性CeO₂纳米棒负载Pt催化剂催化丙烷燃烧性能的研究［J］.无机盐工业，2024，56（1）：141-148.
	JIN Shengshi， LIU Kaijie， LIU Qiuwen，et al.Study on catalytic performance of phosphoric acid modified CeO₂ nanorod supported Pt catalyst for propane combustion［J］.Inorganic Chemicals Industry，2024，56（1）：141-148.
31	SUNDARESAN A， BHARGAVI R， RANGARAJAN N，et al.Ferromagnetism as a universal feature of nanoparticles of the otherwise nonmagnetic oxides［J］.Physical Review B，2006，74（16）：161306.
32	NIWAYAMA Y， KURA H， SATO T，et al.Room temperature ferromagnetism in diluted magnetic semiconductor Zn_1- _x Cr _x Te nano-particles synthesized by chemical method［J］.Applied Physics Letters，2008，92（20）：202502.
33	REN Yinshuan， ZHANG Zhufeng， HU Hai，et al.Solvothermal synthesis of Cr-doped MS（M=Zn，Cd） nanostructures with room-temperature ferromagnetic property［J］.Physica E：Low-Dimensional Systems and Nanostructures，2019，114：113643.
34	LI Yafei， ZHOU Zhen， JIN Peng，et al.Achieving ferromagnetism in single-crystalline ZnS wurtzite nanowires via chromium do-ping［J］.The Journal of Physical Chemistry C，2010，114（28）：12099-12103.
35	CHEN Hongxia， XIE Jianming， LIU Chenglin，et al.Structures and magnetic properties of ZnS nanotubes doped with Cr at-om［J］.Chinese Journal of Computational Physics，2016，33：98.
36	ZENER C.Interaction between the d-shells in the transition metals.II.ferromagnetic compounds of manganese with perovskite structure［J］.Physical Review，1951，82（3）：403-405.
37	CUI J B， RISTEIN J， LEY L.Electron affinity of the bare and hydrogen covered single crystal diamond（111） surface［J］.Physical Review Letters，1998，81（2）：429-432.
38	SLUITER M H F， KAWAZOE Y， SHARMA P，et al.First principles based design and experimental evidence for a ZnO-based ferromagnet at room temperature［J］.Physical Review Letters，2005，94（18）：187204.
39	杨坤，任启霞，黄永刚，等.煅烧温度对ZnGaZrO _x /SAPO-34催化性能的影响［J］.无机盐工业，2024，56（2）： 136-145.
	YANG Kun， REN Qixia， DONG Yonggang，et al.Effect of calcintion temperture on catalytic performance of ZnGaZrO _x /SAPO-34［J］.Inorganic chemicals industry，2024，56（2）： 136-145.
40	KHAMZIN A A， NIGMATULLIN R R.Thermodynamics of ising rare-earth magnet in the static fluctuation approximation［J］.Optics and Spectroscopy，2014，116（6）：842-848.
41	REN Yinshuan， ZHANG Zhufeng， XIE Guoya，et al.Investigation of optical and magnetic properties of nanostructured CdS-and Cr-doped CdS nanorods dilute magnetic semiconductor［J］.Nano，2023，18（1）：2250095.

[1]	YUAN Shuai, FANG Yangfei, YANG Xiangguang, ZHANG Yibo. Study on synthesis of rare earth-doped CeO₂ and its CMP properties [J]. Inorganic Chemicals Industry, 2024, 56(12): 35-41.
[2]	LU Xiaomin,LI Xuemei,LIU Lanjun,SHEN Xiaofang,MEI Yi,LIAN Peichao. Research progress in preparation of black phosphorus by liquid phase method [J]. Inorganic Chemicals Industry, 2022, 54(3): 31-37.
[3]	WU Zhaoguo,CAO Jun,YANG Zeheng. Preparation of LiNi_0.8Co_0.1Mn_0.1O₂ cathode materials with different morphologies based on hydrothermal/solvothermal method [J]. Inorganic Chemicals Industry, 2022, 54(2): 72-77.
[4]	LI Yalin, HUANG Yu, Li Dongao, SUI Zhaoyi, HE Haiyang, LIU Haozhao. Preparation of Fe-impregnated biochar from food waste by solvothermal method [J]. Inorganic Chemicals Industry, 2022, 54(11): 96-103.
[5]	Gui Yanghai,Wang Xinghui,Tian Kuan,Qian Linlin. Study on preparation of flower-like WSe₂ nanomaterial by solvothermal method and its gas sensing properties [J]. Inorganic Chemicals Industry, 2021, 53(5): 47-50.
[6]	XIONG Yun,CHEN Xin,ZHANG Jing,DENG Niyan,ZHANG Quan,LIU Shengpeng,SUN Guofeng. Preparation and photocatalytic properties of BiOBr/UiO-66-（COOH）₂ composite materials [J]. Inorganic Chemicals Industry, 2021, 53(12): 150-155.
[7]	Qin Liqin,Yang Huanggen,Chen De,Tao Pingfang. Assistanted solvothermal synthesis of nanocrystalline self-assembled CaWO₄:Tb ³⁺ microspheres and luminescence properties [J]. Inorganic Chemicals Industry, 2021, 53(1): 36-39.
[8]	QIN Li-Qin, TAO Ping-Fang, WANG Rong-Fang, WEI Qing-Min, HUANG Shao-Yan. Solvothermal synthesis and luminescence properties of flower-like rare-earth-doped CaWO4 nanostructures [J]. INORGANICCHEMICALSINDUSTRY, 2016, 48(6): 41-.
[9]	Zhao Fenghua;Lan Bang;Huo Yanping. Preparation of ZnS:Cu by solvothermal method and optical properties thereof [J]. INORGANICCHEMICALSINDUSTRY, 2010, 0(8): 0-0.
[10]	Li Hao;Zhang Xibin. Effect of complexing agents/surfactants on flowery Co microcrystals prepared by solvothermal method [J]. INORGANICCHEMICALSINDUSTRY, 2010, 0(6): 0-0.
[11]	Wei Mingzhen;Huo Jianzhen. Synthesis and characterization of cuprous oxide nanorods [J]. INORGANICCHEMICALSINDUSTRY, 2009, 0(7): 0-0.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on diluted magnetic semiconductor Cr-doped CdS nanostructures and magnetic properties

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 41

Related Articles 11

Metrics

Comments

Recommended 0