xDLVO理论解析磷精矿陶瓷过滤过程中膜污染问题的研究

doi:10.19964/j.issn.1006-4990.2023-0285

Abstract

Abstract:

The membrane fouling behavior of alumina ceramic membrane in the process of phosphorus concentrate filtration was analyzed using xDLVO（Extend Derjaguin Landau Verweek Overbeek） theory.Based on xDLVO theory，the interaction energy between primary membrane（N-AM），cleaning regeneration membrane（C-AM） and phase out membrane（F-AM） and pollutants（MP）（mixture of fluorapatite，dolomite and silica） was calculated.The contribution of Van der Waals interaction energy（LW），electrostatic interaction energy（EL） and polar interaction energy（AB） in the process of membrane pollution was analyzed.The results indicated that AB dominated the N-AM membrane，exhibiting a repulsive effect，which was beneficial for alleviating membrane fouling；for C-AM and F-AM membranes，the LW interaction energy was the main interaction energy，manifested as attraction，exacerbating membrane fouling.In all pollution processes，the difference in Van der Waals interaction energy was relatively small，while the absolute value of electrostatic interaction energy was extremely small and its contribution was weak.The membrane fouling experiment and calculation results were consistent，indicating that the xDLVO theory had guiding significance for the analysis of membrane fouling behavior and membrane fouling control in the membrane separation process of phosphorus concentrate.

Key words: phosphorus concentrate, ceramic membrane, membrane pollution, xDLVO, interaction energy

CLC Number:

TQ126.3

XUE Jin, TIAN Mengkui, LIU Hai. Study on membrane fouling in ceramic filtration of phosphorus concentrate based on xDLVO theory[J]. Inorganic Chemicals Industry, 2024, 56(6): 55-60.

Figures/Tables 10

Table 1

Surface energy data of testing agent mJ/m2"

测试剂	γ^LM	$γ +$	$γ -$	γ^AB	γ^TOT
纯水	21.8	25.5	25.5	51.0	72.8
甘油	34.0	3.9	57.4	30.0	64.0
二碘甲烷	50.8	0.0	0.0	0.0	50.8

Table 1

Fig.1

Table 2

Fig.2

Table 3

Table 4

Table 5

Surface tension parameters of membraneand pollutants"

膜和污染物	$γ L W$	$γ +$	$γ -$	$γ A B$	$γ T O T$
N-AM	32.36	3.96	31.26	11.12	43.48
C-AM	35.16	3.32	28.7	9.76	44.92
F-AM	34.71	3.33	28.55	9.75	44.46
MP	32.19	1.88	25.67	6.95	39.14

Table 5

Table 6

Viscous free energy between membraneand pollutant（KT）"

膜名称	污染物	$∆ G d 0 L W$	$∆ G d 0 A B$	$Δ G d 0 E L$	$Δ G d 0 T O T$
N-AM	MP	-2.05	4.12	0.02	2.09
C-AM	MP	-2.53	2.36	0.03	-0.14
F-AM	MP	-2.36	0.26	0.06	-2.04

Table 6

Fig.3

Fig.4

References 25

1	CEVALLOS-MENDOZA J， AMORIM C G， RODRÍGUEZ-DÍAZ J M，et al.Removal of contaminants from water by membrane filtration：A review［J］.Membranes，2022，12（6）：570.
2	林钰青，张以任，邱宇隆，等.膜技术在盐湖提锂中的进展和展望［J］.无机盐工业，2023，55（1）：33-45.
	LIN Yuqing， ZHANG Yiren， QIU Yulong，et al.Progress and prospect of membrane technology in lithium extraction from salt lake brine［J］.Inorganic Chemicals Industry，2023，55（1）：33-45.
3	DONG Yingchao， WU Hui， YANG Fenglin，et al.Cost and efficiency perspectives of ceramic membranes for water treatment［J］.Water Research，2022，220：118629.
4	SHI Yaoke， WANG Zhiwen， DU Xianjun，et al.Membrane fouling diagnosis of membrane components based on multi-feature information fusion［J］.Journal of Membrane Science，2022，657：120670.
5	TIAN Jiayu， PAN Hui， BAI Zhaoyu，et al.Alleviated membrane fouling of corundum ceramic membrane in MBR：As compared with alumina membrane［J］.Journal of Environmental Chemical Engineering，2022，10（6）：108949.
6	MENG Shujuan， ZHANG Minmin， YAO Meng，et al.Membrane fouling and performance of flat ceramic membranes in the application of drinking water purification［J］.Water，2019，11（12）：2606.
7	WU Haichao， KANORA A， SCHWARTZ D K.Fouling of microfiltration membranes by bidisperse particle solutions［J］.Journal of Membrane Science，2022，641：119878.
8	ZHANG Bing， TANG Heli， SHEN Yu，et al.Comparative analysis of membrane fouling mechanisms induced by colloidal polymer：Effects of sodium and calcium ions［J］.Journal of Colloid and Interface Science，2022，608（Pt 1）：780-791.
9	YANG Haiyan， YU Xuri， LIU Junxia，et al.A concise review of theoretical models and numerical simulations of membrane fouli- ng［J］.Water，2022，14（21）：3537.
10	LIN Tao， LU Zijian， CHEN Wei.Interaction mechanisms and predictions on membrane fouling in an ultrafiltration system，using the XDLVO approach［J］.Journal of Membrane Science，2014，461：49-58.
11	LI Haigang， XIA Huanjin， MEI Yingxin.Modeling organic fouling of reverse osmosis membrane：From adsorption to fouling layer formation［J］.Desalination，2016，386：25-31.
12	MA Zhun， ZHANG Lu， LIU Ying，et al.Influential mechanism of natural organic matters with calcium ion on the anion exchange membrane fouling behavior via xDLVO theory［J］.Membranes，2021，11（12）：968.
13	BAI Zhaoyu， ZHANG Ruijun， WANG Songxue，et al.Membrane fouling behaviors of ceramic hollow fiber microfiltration（MF） membranes by typical organic matters［J］.Separation and Purification Technology，2021，274：118951.
14	周鸣天，张干伟，寇朝卫，等.XDLVO理论分析混合有机污染物的膜污染［J］.水处理技术，2020，46（4）：73-77，96.
	ZHOU Mingtian， ZHANG Ganwei， KOU Chaowei，et al.XDLVO theory analysis of membrane fouling by mixture organic pollutan-ts［J］.Technology of Water Treatment，2020，46（4）：73-77，96.
15	LI Renjie， LOU Yang， XU Yanchao，et al.Effects of surface morphology on alginate adhesion：Molecular insights into membrane fouling based on XDLVO and DFT analysis［J］.Chemosphere，2019，233：373-380.
16	唐和礼，张冰，黄冬梅，等.XDLVO理论在膜污染解析中的应用研究［J］.化工学报，2021，72（3）：1230-1241.
	TANG Heli， ZHANG Bing， HUANG Dongmei，et al.Advances in membrane fouling analysis based on XDLVO theory［J］.CIESC Journal，2021，72（3）：1230-1241.
17	ZHANG Tong， ZHANG Jie， WANG Qiaoying，et al.Evaluating of the performance of natural mineral vermiculite modified PVDF membrane for oil/water separation by membrane fouling model and XDLVO theory［J］.Journal of Membrane Science，2022，641：119886.
18	LIU Junxia， FAN Yaqian， SUN Yuhui，et al.Modelling the critical roles of zeta potential and contact angle on colloidal fouling with a coupled XDLVO-collision attachment approach［J］.Journal of Membrane Science，2021，623：119048.
19	ZHANG Jun， WANG Pengfei， BORG M K，et al.A critical assessment of the line tension determined by the modified Young′s equation［J］.Physics of Fluids，2018，30（8）：82003.
20	屈晓璐.任意粗糙膜表面的构建及其与膜污染界面作用力的关系研究［D］.金华：浙江师范大学，2018.
	QU Xiaolu.Construction of random rough membrane surface and its relationship with interfacial interactions in membrane fouli-ng［D］.Jinhua：Zhejiang Normal University，2018.
21	KRUPP H， SPERLING G.Theory of adhesion of small particles［J］.Journal of Applied Physics，1966，37（11）：4176-4180.
22	赵应许，纵瑞强，高欣玉，等.XDLVO理论解析不同离子条件下海藻酸钠微滤膜污染［J］.环境科学，2014，35（4）：1343-1350.
	ZHAO Yingxu， ZONG Ruiqiang， GAO Xinyu，et al.Fouling behavior of sodium alginate during microfiltration at various ionic co-mpositions：XDLVO approach［J］.Environmental Science，2014，35（4）：1343-1350.
23	YUAN Xiaotong， WU Lei， GENG Hongzhang，et al.Polyaniline/polysulfone ultrafiltration membranes with improved permeability and anti-fouling behavior［J］.Journal of Water Process Engineering，2021，40：101903.
24	王可，樊华，侯得印，等.XDLVO理论解析有机物在膜蒸馏过程中的膜污染行为机制［J］.膜科学与技术，2022，42（2）：25-33.
	WANG Ke， FAN Hua， HOU Deyin，et al.Mechanism of membrane fouling in membrane distillation process by organic compounds：XDLVO theory［J］.Membrane Science and Technology，2022，42（2）：25-33.
25	吴欢欢，沈飞，万印华，等.XDLVO理论解析膜蒸馏回收离子液体过程中的膜污染研究［J］.膜科学与技术，2019，39（5）：9-17.
	WU Huanhuan， SHEN Fei， WAN Yinhua，et al.Analysis of membrane fouling by XDLVO theory in vacuum membrane distillation for ionic liquid recycling［J］.Membrane Science and Technology，2019，39（5）：9-17.

膜名称	平均孔径/μm	膜厚度/mm	孔隙率/%
N-AM	31.42±2.5	28±1.0	41.52±2.51
C-AM	27.8±1.9	28.4±1.2	36.48±1.19
F-AM	23.83±0.9	29±0.8	14.63±2.25

膜和污染物	Zeta电位/mV	θ_w/（°）	θ_g/（°）	θ_d/（°）
N-AM	-16.8±7.34	38.6±2.2	31.6±2.3	53.4±1.8
C-AM	-17.5±6.91	40.8±1.9	32.7±2.7	48.4±1.3
F-AM	-20.9±5.83	41.4±2.3	33.5±1.6	49.2±1.6
MP	-7.53±4.43	51.6±2.9	47.9±2.3	53.7±1.7

[1]	LI Yang, ZANG Yihua, YUAN Biao, SHENG Chunguang. Modification of antifouling ceramic membrane and its application of oily wastewater treatment [J]. Inorganic Chemicals Industry, 2023, 55(9): 33-42.
[2]	Peng Wenbo,Yun Jianjun,Ding Bangchao,Bai Zuguo,Xiao Weiyi,Wang Xiaohu. Study on membrane integration technology in treatment of wastewater from chlorinated titanium dioxide [J]. Inorganic Chemicals Industry, 2020, 52(6): 76-79.
[3]	Peng Wenbo,Li Tengfei,Bai Zuguo,Chen Daokang,Yun Jianjun. Application of membrane technology in resource recovery of cobalt-containing saline wastewater [J]. Inorganic Chemicals Industry, 2020, 52(5): 65-67.
[4]	CUI Ji-Chao, LI Zhan-Chuan, Hu-Yong-Qi. Application of automatic ceramic membrane thickener in production of precipitated calcium carbonate [J]. INORGANICCHEMICALSINDUSTRY, 2016, 48(5): 58-.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on membrane fouling in ceramic filtration of phosphorus concentrate based on xDLVO theory

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 10

References 25

Related Articles 4

Metrics

Comments

Recommended 0