盐酸法钛白粉新工艺副产氯化亚铁制备四氧化三铁

doi:10.19964/j.issn.1006-4990.2022-0136

Abstract

Abstract:

An enlarged process for preparing ferrous tetroxide magnetic powder from the by-product ferrous chloride of the new process of titanium dioxide by hydrochloric acid method was explored.The by-product hazardous waste ferrous chloride was prepared into widely used ferrous tetroxide magnetic powder to realize comprehensive utilization of resources.The research results showed that calcium oxide was used as precipitant to react with ferrous chloride to obtain ferrous hydroxide，Ferrous hydroxide was oxidized to trivalent ferric hydroxide by passing air under the aid of dispersant.The calcium oxide and dispersant feeding time interval was 1.5 h，the oxidation temperature was 80 ℃，and the oxidation time was 8.5 h.The ferric hydroxide and ferrous hydroxide were uniformly mixed with molar ratio of 2∶1.The solid was obtained by positive pressure separation，and the pH before separation was controlled to be 6.5.The ferrite tetroxide magnetic powder was obtained by post-processing of drying and grinding.The process was scaled up to 50 kg to obtain ferric oxide products，and the yield reached 97%.This process converted by-product hazardous waste into products with certain economic benefits，and further improved the new process of titanium dioxide by hydrochloric acid method.

Key words: titanium dioxide by hydrochloric acid method, by-product of new process, ferrous chloride, iron oxide

CLC Number:

TQ138.11

HU Luoxing,HUANG Qimao,QU Hongyou. Preparation of Fe₃O₄ from FeCl₂ by-product of new process of titanium dioxide by hydrochloric acid[J]. Inorganic Chemicals Industry, 2023, 55(1): 118-123.

Figures/Tables 6

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References 18

1	夏渊, 王婉婧, 周磊, 等. 2020年中国钛白粉行业发展现状分析[J].涂层与防护, 2021, 42（9）：56-62.
	XIA Yuan, WANG Wanjing, ZHOU Lei, et al. Current status and development of China's titanium dioxide industry in 2020[J].Coating and Protection, 2021, 42（9）：56-62.
2	李亚东, 徐征, 张汉平, 等. 钛白粉可持续发展能力探究[J].化工设计通讯, 2021, 47（9）：89-90.
	LI Yadong, XU Zheng, ZHANG Hanping, et al. Study on the sustainable development ability of titanium dioxide[J].Chemical Engineering Design Communications, 2021, 47（9）：89-90.
3	刘红星. 我国氯化钛白行业发展面临的竞争与挑战[J].有色金属设计, 2021, 48（2）：125-128.
	LIU Hongxing. Competition and challenges faced by China in the development of titanium chloride industry[J].Nonferrous Metals Design, 2021, 48（2）：125-128.
4	吴健春, 路瑞芳. 钛白副产废酸和七水硫酸亚铁制备一水硫酸亚铁的研究[J].无机盐工业, 2018, 50（6）：75-77.
	WU Jianchun, LU Ruifang. Study on preparation of FeSO₄·H₂O from titanium white waste acid and FeSO₄·7H₂O[J].Inorganic Chemicals Industry, 2018, 50（6）：75-77.
5	彭荣华, 李晓湘. 用钛白副产的硫酸亚铁浸锰制备高纯二氧化锰[J].无机盐工业, 2006, 38（12）：48-50.
	PENG Ronghua, LI Xiaoxiang. Preparation of highpurity manganese dioxide by leaching manganese ore with ferrous sulfate from by-product of titanium white[J].Inorganic Chemicals Industry, 2006, 38（12）：48-50.
6	丁杰. 盐酸法生产钛白废液制取高纯Fe₂O₃实验研究[J].化工生产与技术, 2007, 14（4）：39-40, 1.
	DING Jie. Experiment study on preparation of Fe₂O₃ from the waste water in titanium dioxide production by hydrochloric acid[J].Chemical Production and Technology, 2007, 14（4）：39-40, 1.
7	谢晓翠, 胡仰栋, 张伟涛, 等. 氯化亚铁生产高品质氧化铁红的工艺研究[J].无机盐工业, 2015, 47（5）：41-44.
	XIE Xiaocui, HU Yangdong, ZHANG Weitao, et al. Study on manufacture technology of high quality red iron oxide from ferrous chloride[J].Inorganic Chemicals Industry, 2015, 47（5）：41-44.
8	GRÜTTNER C, RUDERSHAUSEN S, TELLER J. Improved properties of magnetic particles by combination of different polymer materials as particle matrix[J].Journal of Magnetism and Magnetic Materials, 2001, 225（1/2）：1-7.
9	MAURYA C S, SARKAR C. Dynamic and creep and recovery performance of Fe₃O₄ nanoparticle and carbonyl iron microparticle water-based magnetorheological fluid[J].Journal of Intelligent Material Systems and Structures, 2022, 33（6）：743-755.
10	QU Shengchun, YANG Haibin, REN Dawei, et al. Magnetite nanoparticles prepared by precipitation from partially reduced ferric chloride aqueous solutions[J].Journal of Colloid and Interface Science, 1999, 215（1）：190-192.
11	苏欣悦, 丁欣欣, 闫良国. Fe₃O₄磁性纳米材料的制备及水处理应用进展[J].中国粉体技术, 2020, 26（6）：1-10.
	SU Xinyue, DING Xinxin, YAN Liangguo. Research progress of preparation of Fe₃O₄ magnetic nanomaterials and applications in wastewater treatment[J].China Powder Science and Technology, 2020, 26（6）：1-10.
12	罗维, 郭茹瑶, 薛冰纯, 等. Fe₃O₄磁性纳米材料在水处理中的应用研究进展[J].分析科学学报, 2020, 36（5）：690-694.
	LUO Wei, GUO Ruyao, XUE Bingchun, et al. Research progress of Fe₃O₄ magnetic nanomaterial in water treatment[J].Journal of Analytical Science, 2020, 36（5）：690-694.
13	陈赞, 李银辉. 磁性四氧化三铁制备及对废水重金属离子净化[J].无机盐工业, 2015, 47（6）：20-22.
	CHEN Zan, LI Yinhui. Preparation of magnetic ferriferous oxide and its application in purification of heavy metal ions in waste water[J].Inorganic Chemicals Industry, 2015, 47（6）：20-22.
14	张鑫, 李鑫钢, 姜斌. 四氧化三铁纳米粒子合成及表征[J].化学工业与工程, 2006, 23（1）：45-48.
	ZHANG Xin, LI Xingang, JIANG Bin. Preparation and characterization of nanometer magnetite[J].Chemical Industry and Engineering, 2006, 23（1）：45-48.
15	王力霞, 于云秋, 姚文生. 纳米四氧化三铁制备及其吸附刚果红的性能研究[J].无机盐工业, 2017, 49（4）：37-40, 45.
	WANG Lixia, YU Yunqiu, YAO Wensheng. Preparation of nanocrystalline Fe₃O₄ and study on their adsorption performance for Congo red[J].Inorganic Chemicals Industry, 2017, 49（4）：37-40, 45.
16	黄智淼, 林君, 张洋, 等. 钛铁矿制四氧化三铁/二氧化钛及其光催化性能[J].无机盐工业, 2018, 50（3）：69-73.
	HUANG Zhimiao, LIN Jun, ZHANG Yang, et al. Synthesis of Fe₃O₄/TiO₂ composites from ilmenite and the photocatalytic performance thereof[J].Inorganic Chemicals Industry, 2018, 50（3）：69-73.
17	黄齐茂, 屈泓佑. 一种高纯度人造金红石及其制备方法：中国, 113582225A[P].2021-11-02.
18	黄齐茂, 胡骆兴, 刘衡. 利用钛白粉盐酸法副产物制备磁铁粉的方法：中国, 113896247A[P].2022-01-07.

[1]	TANG Yifu, CAO Changchun, LÜ Peng. Study on adsorption of cadmium-humic acid by hydroxyiron oxide [J]. Inorganic Chemicals Industry, 2023, 55(8): 124-131.
[2]	LI Yuhang, WANG Yinbin, WEI Qiang. Preparation of Fe₂O₃-Co₃O₄ heterojunction by molten salt method and its hydrogen evolution performance [J]. Inorganic Chemicals Industry, 2023, 55(8): 51-58.
[3]	ZHOU Kai,PAN Guoxiang,LI Jinhua,XIA Shengjie,XU Minhong,SHEN Hui,KOSO Aoki. Study on preparation and heat resistance of iron oxide yellow coated with double layer Al（OH）₃@Zn（OH）₂ [J]. Inorganic Chemicals Industry, 2022, 54(2): 50-53.
[4]	CAO Xuechen,ZHOU Dongjie,YAO Haiwei,JU Dianchun. Study on preparation of nanometer iron oxide and its kinetics by CC-OA DES treatment of iron-containing dust [J]. Inorganic Chemicals Industry, 2021, 53(11): 100-106.
[5]	Su Hang, Zuo Haibin, Zhao Jun. Desulphurization of gypsum at high temperature [J]. Inorganic Chemicals Industry, 2019, 51(7): 68-73.
[6]	SHI Xiao-Lu, ZHAO Ling, WANG Jin-Yun, CHU Cheng-Yi, SUN Ai-Hua. Synthesis and heat-resistant property of iron oxide yellow pigment coated with aluminium phosphate [J]. INORGANICCHEMICALSINDUSTRY, 2016, 48(10): 29-.
[7]	XIE Xiao-Cui, HU Yang-Dong, ZHANG Wei-Tao, LI Hua. Study on manufacture technology of high quality red iron oxide from ferrous chloride [J]. INORGANICCHEMICALSINDUSTRY, 2015, 47(5): 41-.
[8]	XIAO Jing-Bo, XIA Jiao-Bin, CHEN Ju-Ling. Preparation of high purity ferric oxide from serpentine [J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(11): 30-.
[9]	YAO Zuo-Sheng, SUN Xiao-Qing, DU Song-Song. Study on iron oxide yellow prepared by liquid phase soda ash process [J]. INORGANICCHEMICALSINDUSTRY, 2014, 46(10): 46-.
[10]	KONG De-Shun, FAN Jia-Xin, SHI Kai-Yi, LI Zhi. Experimental study on preparation of iron oxide red from acid leaching solution of high-iron coal gangue [J]. INORGANICCHEMICALSINDUSTRY, 2013, 45(7): 56-.
[11]	ZHANG Ya-Qing, LI Jun, LUO Jian-Hong, SUN Yi. Study on new manufacture technology of high quality red iron oxide from ferrous sulfate [J]. INORGANICCHEMICALSINDUSTRY, 2013, 45(1): 44-.
[12]	GE Qi-Long, WANG Xiao-Jun, HE Yao-Zhong, LI Zhao-Zhong. Study on preparation of crystal seed of iron oxide red with wastewater from red iron oxide plant [J]. INORGANICCHEMICALSINDUSTRY, 2012, 44(12): 48-.
[13]	CAO Ren-Bo- , CHEN Xiao-Quan, SHEN Wen-Hao. Synthesis progress of nano-sized ferric oxide [J]. INORGANICCHEMICALSINDUSTRY, 2011, 43(8): 6-.
[14]	Zhang Mei;Yang Haining;Zhang Xiaoxia;Wang Chuanying. Preparation of polyaluminium ferrous chloride by using cryolite mother liquor [J]. INORGANICCHEMICALSINDUSTRY, 2010, 0(3): 0-0.
[15]	Zhang Haiyan;Li Jun;Wang Shaodong;Wang Tao. New technology for comprehensive recovery and utilization of ferrophosphorus [J]. INORGANICCHEMICALSINDUSTRY, 2009, 0(10): 0-0.

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Preparation of Fe₃O₄ from FeCl₂ by-product of new process of titanium dioxide by hydrochloric acid

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