铜离子掺杂CsPbCl3量子点光学性能及稳定性探究

doi:10.19964/j.issn.1006-4990.2022-0049

Abstract

Abstract:

In recent years,perovskites have attracted extensive attention because of their special structure.Among them,all inorganic perovskite quantum dots,as the next generation of luminescent materials,have received abroad research and attention because of their excellent luminescent properties.However,due to the toxicity and poor stability of Pb,perovskite quantum dots still face many obstacles in production and application.In order to solve these problems,a Cu²⁺ ion B-site doped CsPbCl₃ perovskite quantum dot was introduced.Cu²⁺ was successfully doped into CsPbCl₃ perovskite quantum dots by hot injection.It was found that Cu²⁺-doped CsPbCl₃ quantum dots still maintained the initial tetragonal crystal structure.Due to the doping of Cu²⁺ ions,the surface defects of CsPbCl₃ quantum dots were effectively eliminated,which promoted exciton recombination through radiation and improved the luminescence properties of CsPbCl₃ quantum dots.Through the stability test,it was revealed that the luminescence intensity of Cu²⁺-doped CsPbCl₃ quantum dots in water was significantly higher than that of CsPbCl₃ quantum dots in certain time.

Key words: Cu²⁺-doped, CsPbCl₃, quantum dot, optical properties

CLC Number:

TB34

JIANG Mouce,PAN Chunyang. Study on optical properties and stability of Cu²⁺-doped CsPbCl₃ quantum dots[J]. Inorganic Chemicals Industry, 2022, 54(10): 116-120.

Figures/Tables 6

Fig.1

Fig.2

Fig.3

Fig.4

Fig.5

Fig.6

References 15

[1]	朱梦梦, 白珏垚, 陈人杰, 等. B位离子掺杂全无机钙钛矿量子点的合成及性能研究进展[J].应用化学, 2021, 38(12): 1541-1555.
	ZHU Mengmeng, BAI Jueyao, CHEN Renjie, et al.Synthesis and properties of B-site doped all-inorganic perovskite quantum dots[J].Chinese Journal of Applied Chemistry, 2021, 38(12): 1541-1555.
[2]	胡驰.石墨烯/二氧化钛的制备及钙钛矿太阳能电池性能研究[J].无机盐工业, 2018, 50(8): 49-51.
	HU Chi.Preparation of graphene/TiO₂ and performance of perovs-kite solar cells[J].Inorganic Chemicals Industry, 2018, 50(8): 49-51.
[3]	贾磊.钙钛矿太阳能电池性能研究新进展[J].无机盐工业, 2016, 48(1): 78.
	JIA Lei.New development in performance study of perovskite solar cells[J].Inorganic Chemicals Industry, 2016, 48(1): 78.
[4]	曾凡菊, 谭永前, 胡伟, 等. Ba²⁺离子掺杂CsPbBr₃蓝光量子点合成及其光学性能[J].发光学报, 2022, 43(1): 69-76.
	ZENG Fanju, TAN Yongqian, HU Wei, et al.Synthesis and optical properties of barium doped CsPbBr₃ blue luminescence quantum dots[J].Chinese Journal of Luminescence, 2022, 43(1): 69-76.
[5]	ZHANG Feng, ZHONG Haizheng, CHEN Cheng, et al.Brightly luminescent and color-tunable colloidal CH₃NH₃PbX₃（X=Br,I,Cl） quantum dots:Potential alternatives for display technology[J].ACS Nano, 2015, 9(4): 4533-4542.
[6]	SWARNKAR A, CHULLIYIL R, RAVI V K, et al.Colloidal CsPbBr₃ perovskite nanocrystals:Luminescence beyond traditional quantum dots[J].Angewandte Chemie（International Ed.in English）, 2015, 54(51): 15424-15428.
[7]	TONG Yu, BLADT E, AYGÜLER M F, et al.Highly luminescent cesium lead halide perovskite nanocrystals with tunable composition and thickness by ultrasonication[J].Angewandte Chemie（International Ed.in English）, 2016, 55(44): 13887-13892.
[8]	殷录桥, 张豆豆, 王胜, 等. 基于CsPbBr₃钙钛矿量子点的白光LED器件的电流稳定性研究[J].光学学报, 2021, 41(19): 200-207.
	YIN Luqiao, ZHANG Doudou, WANG Sheng, et al.Research on current stability of white LED devices based on CsPbBr₃ perovs-kite quantum dots[J].Acta Optica Sinica, 2021, 41(19): 200-207
[9]	徐蔚姌, 蔡园园.全无机钙钛矿CsPbX₃在发光显示领域的研究进展[J].新型工业化, 2021, 11(9): 1-4, 17.
	XU Weiran, CAI Yuanyuan.Research progress of all inorganic perovskite CsPbX₃ in the field of luminescence display[J].The Journal of New Industrialization, 2021, 11(9): 1-4, 17.
[10]	朱雨轩, 杨波波, 郭春凤, 等. Bi基无铅钙钛矿的制备及其应用研究综述[J].照明工程学报, 2021, 32(5): 90-96.
	ZHU Yuxuan, YANG Bobo, GUO Chunfeng, et al.A review of the preparation and application of Bi-based lead-free perovskite[J].China Illuminating Engineering Journal, 2021, 32(5): 90-96.
[11]	王栋, 兰月梅, 刘劝, 等. 白光LED用CsPbBr₃钙钛矿量子点玻璃制备及其稳定性[J].发光学报, 2021, 42(12): 1863-1871.
	WANG Dong, LAN Yuemei, LIU Quan, et al.Preparation and stability of CsPbBr₃ perovskite quantum dots glass for white LED[J].Chinese Journal of Luminescence, 2021, 42(12): 1863-1871.
[12]	胡泽浩, 陈婷, 徐彦乔, 等. 表面包覆策略:提高全无机铯铅卤钙钛矿纳米晶的稳定性及其在照明显示领域的应用[J].化学进展, 2021, 33(9): 1614-1626.
	HU Zehao, CHEN Ting, XU Yanqiao, et al.Surface coating strategy:From improving the luminescence stability to lighting and display applications of all-inorganic cesium lead halide perovs- kite nanocrystals[J].Progress in Chemistry, 2021, 33(9): 1614-1626.
[13]	JELLICOE T C, RICHTER J M, GLASS H F J, et al.Synthesis and optical properties of lead-free cesium tin halide perovskite nanocrystals[J].Journal of the American Chemical Society, 2016,138(9): 2941-2944.
[14]	PROTESESCU L, YAKUNIN S, BODNARCHUK M I, et al.Nanocrystals of cesium lead halide perovskites（CsPbX₃,X=Cl,Br,and I）:Novel optoelectronic materials showing bright emission with wide color gamut[J].Nano Letters, 2015, 15(6): 3692-3696.
[15]	LIU Wenyong, LIN Qianglu, LI Hongbo, et al.Mn²⁺-doped lead halide perovskite nanocrystals with dual-color emission controlled by halide content[J].Journal of the American Chemical Society, 2016, 138(45): 14954-14961.

National Inorganic Salts Information Center

Inorganic Acid-Base-Salt Committee of CIESC

Study on optical properties and stability of Cu²⁺-doped CsPbCl₃ quantum dots

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 6

References 15

Related Articles 4

Metrics

Comments

Recommended 0

[1]	ZHANG Lijie, LI Degang, HAN Wenyuan, XU Huijun, ZHANG Weimin, YU Chen. Preparation of phosphorus-doped carbon quantum dots and activation of peroxymonosulfate for degradation of methylene blue [J]. Inorganic Chemicals Industry, 2024, 56(1): 126-133.
[2]	LI Hongyuan,HARI Bala. Research progress of preparation and photocatalytic application of metal halide perovskite quantum dots [J]. Inorganic Chemicals Industry, 2023, 55(2): 36-44.
[3]	HOU Yan,GAO Chengjuan,WU Xizhe,ZI Xuechi,XIE Lu,YANG Haizheng,YAN Yuxing. Theoretical study on effect of nitrogen doping on photoelectric properties of rutile TiO₂ [J]. Inorganic Chemicals Industry, 2022, 54(6): 90-95.
[4]	LIU Ying-Bo, LI Zhen, ZHANG Yuan, ZHOU Di, ZHENG Zhong, ZHANG De-Wen. Synthesis of water-soluble ZnS:Mn²⁺ quantum dots and photoluminescence thereof [J]. INORGANICCHEMICALSINDUSTRY, 2012, 44(6): 27-.

Study on optical properties and stability of Cu2+-doped CsPbCl3 quantum dots