氮掺杂碳纳米材料在氧还原反应催化剂中的研究进展

doi:10.19964/j.issn.1006-4990.2021-0164

Abstract

Abstract:

For a long time,carbon supported highly dispersed platinum catalysts and their alloys have been the most effective catalysts for oxygen reduction and hydrogen oxidation in commercial proton exchange membrane fuel cells（PEMFCs）.Howe-ber,due to a series of problems,such as high cost,poor stability under electrochemical conditions,CO poisoning and slow kinetics of oxygen reduction reaction（ORR）,the Pt-based catalyst has been hindered in its further application and large-scale production in fuel cells.In contrast,nitrogen-doped carbon nanomaterials have the characteristics of low cost,high activity,high stability and environmental friendliness,which make them have broad application prospects in the field of fuel cells.In this paper,based on the research status at home and abroad in recent years,the preparation methods of nitrogen-doped carbon nanomaterials,such as in-situ doping method,post doping synthesis method and direct pyrolysis method were reviewed,and their advantages and disadvantages were analyzed,as well as their research progress of ORR catalysts.Finally,the main development direction of nitrogen-doped carbon nanomaterials catalysts in the future was prospected.

Key words: nitrogen-doped carbon nanomaterials, oxygen reduction reaction, fuel cells

CLC Number:

TQ126.2

Du Miao,Ma Zhiyuan,Ji Changjian,Wang Lei. Research progress of nitrogen-doped carbon nanomaterials for ORR catalyst[J]. Inorganic Chemicals Industry, 2021, 53(6): 72-78.

Figures/Tables 6

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氧还原反应路径	四电子反应	二电子反应
酸性电解液	O₂+4H⁺+4e^-→2H₂O E⁰=1.23 V（vs.RHE）	O₂+2H⁺+2e^-→H₂O₂
		E⁰=0.67 V（vs.RHE）
		H₂O₂+2H⁺+2e^-→2H₂O
		E⁰=1.77 V（vs.RHE）
碱性电解液	O₂+2H₂O+4e^-→4OH^- E⁰=0.40 V（vs.RHE）	O₂+H₂O+2e^-→HO₂^-+OH^-
		E⁰=0.07 V（vs.RHE）
		H₂O+ HO₂^-+2e^-→3OH^-
		E⁰=0.87 V（vs.RHE）

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Research progress of nitrogen-doped carbon nanomaterials for ORR catalyst

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