锂离子电池正极预锂化技术研究进展
收稿日期: 2024-05-22
网络出版日期: 2024-07-08
基金资助
国家重点研发计划项目(2023YFB4103502)
Research progress of cathode pre-lithiation technology for lithium-ion batteries
Received date: 2024-05-22
Online published: 2024-07-08
锂离子电池近几年在许多行业的应用呈现爆发式增长，几乎每个领域都对锂离子电池的能量密度提出了更高的要求，以满足不断提升的动力和储能需求。锂离子电池在首次充放电过程中，负极表面会形成固态电解质界面（SEI）膜，并消耗正极材料中的活性锂，造成电池容量不可逆的损失，降低了电池的首次库仑效率。研究发现，预锂化技术是解决该问题的有效途径之一，并且正极预锂化相对于负极预锂化更有优势。主要阐述了二元含锂化合物、三元含锂化合物和有机锂盐等几种常见的补锂技术，并综述了正极预锂化添加剂材料对性能优化的进展，指出面临的一些亟待解决的问题，并对未来预锂化技术进行展望。
张珊珊 , 曾雨乐 , 张婷 , 林森 , 刘程琳 . 锂离子电池正极预锂化技术研究进展[J]. 无机盐工业, 2025 , 57(1) : 1 -13 . DOI: 10.19964/j.issn.1006-4990.2024-0284
In recent years，the application of lithium-ion batteries has seen explosive growth in various fields，and almost every field has placed higher demands on the energy density of lithium-ion batteries to meet the ever-increasing demand for power and energy storage.Nevertheless，during the initial charge/discharge cycle of a lithium-ion battery，a solid electrolyte interface（SEI） film forms on the surface of the anode，resulting in the depletion of active lithium ions in the cathode materials.This phenomenon leads to an irreversible loss of battery capacity and a reduction in the first-time coulombic efficiency of the battery.Research has demonstrated that the pre-lithiation technique represents a viable solution to the issue at hand.The findings indicate that pre-lithiation of the cathode confers greater benefits than pre-lithiation of the anode.The common lithium replenishment technologies were mainly described，such as binary lithium-containing compounds，ternary lithium-containing compounds and organic lithium salts，etc.The progress of cathode pre-lithiation additive materials in optimising performance was also reviewed.It was pointed out that there were some urgent problems to be solved，and looked forward to the future of pre-lithiation technology.
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