磷石膏煅烧工艺进展分析
收稿日期: 2022-07-25
网络出版日期: 2023-06-14
基金资助
云南省工业领域科技计划项目重点研发计划(202103AA080012)
Analysis on calcination process progress of phosphogypsum
Received date: 2022-07-25
Online published: 2023-06-14
磷石膏作为主要的工业副产石膏,通过煅烧制备得到建材石膏粉体。归纳了国内外现有磷石膏煅烧工艺特点及利弊,针对现有的炒锅、回转窑、沸腾炉、彼得磨、FC-沸腾炉、锤式粉碎等煅烧工艺存在的产品质量不稳定、可控性差、功能单一、能耗高、投资高等技术及装备问题,提出流化床煅烧工艺。重点介绍了流化床煅烧磷石膏工艺技术具有大型化、流态化、产品多元化、干法净化、绿色环保的特点及技术创新优势。并与目前主流煅烧工艺产品性能指标分析进行对比,得出流化床煅烧磷石膏工艺产品质量稳定性好、可控性强、性能指标优越,必然成为未来磷石膏制备建材石膏粉体的主流技术手段,为中国磷石膏的煅烧资源化利用提供指导价值。
李恒 , 张晖 , 资学民 . 磷石膏煅烧工艺进展分析[J]. 无机盐工业, 2023 , 55(6) : 27 -35 . DOI: 10.19964/j.issn.1006-4990.2022-0451
As the primary industrial by-product of gypsum,phosphogypsum could be prepared by calcination to obtain building material gypsum powder.The characteristics and advantages as well as the disadvantages of existing phosphogypsum calcination processes at home and abroad were summarized.In view of the existing calcination processes such as frying pan,rotary kiln,boiling furnace,Peter grinding,FC-boiling furnace,hammer crushing and so on,there were some technical and equipment problems,such as unstable product quality,poor controllability,single function,high energy consumption and high investment,thereby the fluidized bed calcination process was proposed.The characteristics and technological innovation advantages with large-scale fluidization,product diversification,dry purification green and environmental protection were highlighted.Moreover,it was also compared with the current mainstream calcination process product performance index.It was analyzed that quality stability,controllability and performance index of the fluidized bed calcination phosphogypsum technology product were superior,which would become the future phosphogypsum preparation of building materials gypsum powder mainstream technology means.And it could provide guidance value for the calcination and resource utilization of phosphogypsum eventually in China.
| 1 | DEGIRMENCI N.The using of waste phosphogypsum and natural gypsum in adobe stabilization[J].Construction and Building Materials,2008,22(6):1220-1224. |
| 2 | RASHAD A M.Phosphogypsum as a construction material[J].Journal of Cleaner Production,2017,166:732-743. |
| 3 | ZHANG Linchun, ZHANG Ailian, LI Ke,et al.Research on the pretreatment and mechanical performance of undisturbed phosphogypsum[J].Case Studies in Construction Materials,2020,13:e00400. |
| 4 | HUANG Yongbo, QIAN Jueshi, LU Lingchao,et al.Phosphogypsum as a component of calcium sulfoaluminate cement:Hazardous elements immobilization,radioactivity and performances[J].Journal of Cleaner Production,2020,248:119287. |
| 5 | CHERNYSH Y, YAKHNENKO O, CHUBUR V,et al.Phosphogypsum recycling:A review of environmental issues,current trends,and prospects[J].Applied Sciences,2021,11(4):1575. |
| 6 | CAO Wenxiang, YI Wei, LI Jing,et al.A facile approach for large-scale recovery of phosphogypsum:An insight from its performan-ce[J].Construction and Building Materials,2021,309:125190. |
| 7 | BANDGAR G S, KUMTHEKAR M B, LANDAGE A B.A review of effective utilization of waste phosphogypsum as a building mate-rial[J].International Journal of Engineering Research,2016,5(SP1):277-280. |
| 8 | CUI Yong, WANG Qiang, XUE Junfeng.Novel foam insulation material produced by calcined phosphogypsum and H2O2 [J].Journal of Materials in Civil Engineering,2020,32(12):04020379. |
| 9 | LI Xianbo, ZHANG Qin, KE Baolin,et al.Insight into the effect of maleic acid on the preparation of α-hemihydrate gypsum from phosphogypsum in Na2SO4 solution[J].Journal of Crystal Growth,2018,493:34-40. |
| 10 | ZHI Zhenzhen, HUANG Jian, GUO Yanfei,et al.Effect of chemical admixtures on setting time,fluidity and mechanical properties of phosphorus gypsum based self-leveling mortar[J].KSCE Journal of Civil Engineering,2017,21(5):1836-1843. |
| 11 | BUMANIS G, ZORICA J, BAJARE D,et al.Technological properties of phosphogypsum binder obtained from fertilizer production waste[J].Energy Procedia,2018,147:301-308. |
| 12 | LI Xianbo, ZHANG Qin.Dehydration behaviour and impurity change of phosphogypsum during calcination[J].Construction and Building Materials,2021,311:125328. |
| 13 | GUAN Qingjun, SUI Ying, ZHANG Fang,et al.Preparation of α-calcium sulfate hemihydrate from industrial by-product gypsum:A review[J].Physicochemical Problems of Mineral Processing,2020,57(1):168-181. |
| 14 | YANG Min, QIAN Jueshi.Activation of anhydrate phosphogypsum by K2SO4 and hemihydrate gypsum[J].Journal of Wuhan University of Technology-Mater.Sci.Ed.,2011,26(6):1103-1107. |
| 15 | 段爱萍.脱硫石膏煅烧工艺及其砌块的研究与展望[J].河南建材,2013(5):6-9. |
| DUAN Aiping.Research and prospect of desulfurization gypsum calcination process and its block[J].Henan Building Materials,2013(5):6-9. | |
| 16 | 周建中,冯菊莲,周梦文,等.煅烧设备对建筑石膏性能影响的探索研究[J].新型建筑材料,2010,37(6):72-73,91. |
| ZHOU Jianzhong, FENG Julian, ZHOU Mengwen,et al.Influence of different calcining devices on building plaster performance[J].New Building Materials,2010,37(6):72-73,91. | |
| 17 | 彭卓飞,宋小霞.磷石膏生产β型石膏工艺流程的研究[J].硫磷设计与粉体工程,2021(1):35-38,6. |
| PENG Zhuofei, SONG Xiaoxia.Study of process flow for production of β type gypsum from phosphogypsum[J].Sulphur Phosphorus & Bulk Materials Handling Related Engineering,2021(1):35-38,6. | |
| 18 | 闫友静,张贺,于世峰.脱硫石膏煅烧工艺及煅烧设备浅析[J].新型建筑材料,2018,45(2):100-102. |
| YAN Youjing, ZHANG He, YU Shifeng.Discussion on FGD gypsum calcination process and calcination equipment[J].New Bu- | |
| Materials ilding,2018,45(2):100-102. | |
| 19 | 赵建国,张应虎,李崇贵,等.国内磷石膏煅烧技术评析[J].云南化工,2013,40(1):20-23. |
| ZHAO Jianguo, ZHANG Yinghu, LI Chonggui,et al.Domestic phosphogypsum calcined technical analysis[J].Yunnan Chemical Technology,2013,40(1):20-23. | |
| 20 | 李玉山.石膏粉煅烧技术与节能工艺设计探索[J].非金属矿,1999,22(3):23-25,9. |
| LI Yushan.Exploration of gypsum powder calcination technology and energy-saving process design[J].Non-Metallic Mines,1999,22(3):23-25,9. | |
| 21 | LUSHNIKOVAN,DVORKINL.Sustainability of gypsum products as a construction material[M]//Sustainability of Construction Materials.Amsterdam:Elsevier,2016:643-681. |
| 22 | 巴太斌,徐亚中,王利娜,等.磷石膏的改性及煅烧工艺研究综述[J].河南建材,2018(1):22-24. |
| BA Taibin, XU Yazhong, WANG Lina,et al.Review on modification and calcination technology of phosphogypsum[J].Henan Building Materials,2018(1):22-24. | |
| 23 | 李玉山,宋树峰,富丽娥.流态化煅烧石膏技术的进展:FC分室石膏煅烧炉[J].非金属矿,2005,28(6):34-36,49. |
| LI Yushan, SONG Shufeng, FU Lie.Development of fluidized calcination technology for gypsum—FC multi-chamber calcinator[J].Non-Metallic Mines,2005,28(6):34-36,49. | |
| 24 | 冯金煌,江水.磷石膏新型煅烧炉:锤式烘干机[J].磷肥与复肥,2001,16(6):62-63. |
| FENG Jinhuang, JIANG Shui.A new type calcinator for phosphogypsum-hammer-swinging rotary dryer[J].Phosphate & Compound Fertilizer,2001,16(6):62-63. | |
| 25 | 吴佩芝.湿法磷酸[M].北京:化学工业出版社,1987:356-359. |
| 26 | 李恒,郭旭东,钟晋,等.磷石膏杂质及净化研究现状[J].磷肥与复肥,2022,37(5):22-26. |
| LI Heng, GUO Xudong, ZHONG Jin,et al.Research status of phosphogypsum impurities and purification[J].Phosphate & Com-Fertilizer pound,2022,37(5):22-26. | |
| 27 | TANG Yongbo, GAO Jianming, LIU Chuanbei,et al.Dehydration pathways of gypsum and the rehydration mechanism of soluble anhydrite γ-CaSO4 [J].ACS Omega,2019,4(4):7636-7642. |
| 28 | KAZRAGIS A.High‐temperature decontamination and utilization of phosphogypsum[J].Journal of Environmental Engineering and Landscape Management,2004,12(4):138-145. |
| 29 | CAO Wenxiang, YI Wei, PENG Jiahui,et al.Preparation of anhydrite from phosphogypsum:Influence of phosphorus and fluorine impurities on the performances[J].Construction and Building Materials,2022,318:126021. |
| 30 | 林洲,邓铃夕,李凤玲,等.快烧对磷石膏可溶磷杂质及其脱水产物的影响[J].非金属矿,2013,36(5):1-3. |
| LIN Zhou, DENG Lingxi, LI Fengling,et al.Transformation of soluble phosphate impurities and dehydration product in phosphogypsum after fast firing[J].Non-Metallic Mines,2013,36(5):1-3. | |
| 31 | 焦叶宏,杨林,李贺军,等.流态化热处理对磷石膏杂质及胶凝性能的影响[J].建筑材料学报,2019,22(3):401-407,439. |
| JIAO Yehong, YANG Lin, LI Hejun,et al.Effect of fluidized heat treatment on impurities and gelling properties of phosphogyps-um[J].Journal of Building Materials,2019,22(3):401-407, 439. | |
| 32 | LIU Shuhua, OUYANG Jiayi, REN Jun.Mechanism of calcination modification of phosphogypsum and its effect on the hydration properties of phosphogypsum-based supersulfated cement[J].Construction and Building Materials,2020,243:118226. |
| 33 | CAO Wenxiang, YI Wei, PENG Jiahui,et al.Recycling of phosphogypsum to prepare gypsum plaster:Effect of calcination temperature[J].Journal of Building Engineering,2022,45:103511. |
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