金属有机骨架在吸附式制冷/热泵中的应用
收稿日期: 2022-07-04
网络出版日期: 2023-04-13
基金资助
国家自然科学基金项目(51906232);国家自然科学基金项目(51876015)
Application of MOFs in adsorption refrigeration/heat pump
Received date: 2022-07-04
Online published: 2023-04-13
刘子涵 , 席国君 , 雷广平 . 金属有机骨架在吸附式制冷/热泵中的应用[J]. 无机盐工业, 2023 , 55(4) : 20 -26 . DOI: 10.19964/j.issn.1006-4990.2022-0405
As a new kind of porous materials，metal-organic frameworks（MOFs） have received extensive research and attention in the field of medium and low temperature adsorption refrigeration and adsorption heat storage in recent years due to their unique and adjustable pore structure，high specific surface area and high porosity.The application status of different MOFs materials in the field of adsorption heat conversion and the methods to further improve the performance of the materials from the perspectives of the adsorption capacity of MOFs to the heat transfer medium，the thermal efficiency and stability were compared and analyzed.Through the analysis，it could be found that the modification of MOFs materials and the composite with other materials were effective methods to improve the adsorption thermal storage performance，and it was also a signifiacnt direction for the development of novel MOFs materials in the future.At the same time，the efficient matching between the adsorption heat conversion system and MOFs heat storage materials was also a crucial index for the practicality of MOFs heat storage materials in the future.
Key words： MOFs; adsorption property; adsorption heat conversion; thermodynamic cycle
| 1 | XU Zhenyuan， WANG Ruzhu.Absorption heat pump for waste heat reuse：Current states and future development[J].Frontiers in Energy，2017，11（4）：414-436. |
| 2 | 英国石油公司.BP世界能源统计年鉴[R].伦敦：英国石油公司，2021. |
| BP Amoco.BP statistical review of world energy[R].London：BP Amoco，2021. | |
| 3 | International Energy Agency.World energy outlook 2021[R].Paris：IEA，2021. |
| 4 | CIAN E， WING I SUE.Correction to：Global energy consumption in a warming climate[J].Environmental and Resource Economics，2019，72：365-410. |
| 5 | 中国建筑节能协会.中国建筑能耗与碳排放研究报告 2021[R].北京：中国建筑节能协会，2021. |
| China Association of Building Energy Efficiency.China building energy consumption and carbon emission research report 2021[R].Beijing：CABEE，2021. | |
| 6 | JEREMIAS F， KHUTIA A， HENNINGER S K，et al.MIL-100（Al，Fe） as water adsorbents for heat transformation purposes：A promising application[J].Journal of Materials Chemistry，2012，22（20）：10148-10151. |
| 7 | MOGHADAM P Z， LI A， WIGGIN S B，et al.Development of a Cambridge structural database subset：A collection of metal-organic frameworks for past，present，and future[J].Chemistry of Materials，2017，29（7）：2618-2625. |
| 8 | DEMIR H.Development of microwave assisted zeolite-water adsorption heat pump[J].International Journal of Refrigeration，2013，36（8）：2289-2296. |
| 9 | CANIVET J， FATEEVA A， GUO Youmin，et al.Water adsorption in MOFs：Fundamentals and applications[J].Chemical Society Reviews，2014，43（16）：5594-5617. |
| 10 | SARKISOV L， CENTINEO A， BRANDANI S.Molecular simulation and experiments of water adsorption in a high surface area activated carbon：Hysteresis，scanning curves and spatial organization of water clusters[J].Carbon，2017，118：127-138. |
| 11 | FURUKAWA H， GáNDARA F， ZHANG Yuebiao，et al.Water adsorption in porous metal-organic frameworks and related materials[J].Journal of the American Chemical Society，2014，136（11）：4369-4381. |
| 12 | HENNINGER S K， SCHMIDT F P， HENNING H M.Water adsorption characteristics of novel materials for heat transformation applications[J].Applied Thermal Engineering，2010，30（13）：1692-1702. |
| 13 | VISHNYAKOV A， RAVIKOVITCH P I， NEIMARK A V，et al.Nanopore structure and sorption properties of Cu-BTC metal-organic framework[J].Nano Letters，2003，3（6）：713-718. |
| 14 | KüSGENS P， ROSE M， SENKOVSKA I，et al.Characterization of metal-organic frameworks by water adsorption[J].Microporous and Mesoporous Materials，2009，120（3）：325-330. |
| 15 | VAN ASSCHE T R C， DUERINCK T， GUTIERREZ-SEVILLANO J J，et al.High adsorption capacities and two-step adsorption of polar adsorbates on Cu-BTC metal-organic framework[J].Journal of Physic Chemistry C，2013，117（35）：18100-18111. |
| 16 | DANTAS S， NEIMARK A V.Coupling structural and adsorption properties of metal-organic frameworks：From pore size distribution to pore type distribution[J].ACS Applied Materials & Interfaces，2020，12（13）：15595-15605. |
| 17 | W?LLNER M， KLEIN N， KASKEL S.Measuring water adsorption processes of metal-organic frameworks for heat pump applications via optical calorimetry[J].Microporous and Mesoporous Materials，2019，278：206-211. |
| 18 | HE Wenling， GUO Xiaohui， ZHENG Jing，et al.Structural evolution and compositional modulation of ZIF-8-derived hybrids comprised of metallic Ni nanoparticles and silica as interlayer[J].Inorganic Chemistry，2019，58（11）：7255-7266. |
| 19 | ZHANG K， LIVELY R P， DOSE M E，et al.Alcohol and water adsorption in zeolitic imidazolate frameworks[J].Chemical Communications，2013，49（31）：3245-3247. |
| 20 | 苏亭宇，王丽伟，吴韶飞，等.锌基-MOFs 对氨吸附制冷性能的分子模拟研究[J].制冷学报，2022，43（4）：120-128. |
| SU Tingyu， WANG Liwei， WU Shaofei，et al.Molecular simulation study on ammonia adsorption refrigeration performance of zinc-based-MOFs[J].Chinese Journal of Refrigeration，2022，43（4）：120-128. | |
| 21 | 吴选军，杨旭，宋杰，等.ZIF-8材料中CH4/H2吸附与扩散的分子模拟[J].化学学报，2012，70（24）：2518-2524. |
| WU Xuanjun， YANG Xu， SONG Jie，et al.Molecular simulation of adsorption and diffusion of CH4 and H2 in ZIF-8 material[J].Acta Chimica Sinica，2012，70（24）：2518-2524. | |
| 22 | PARK K S， NI Z， C?Té A P，et al.Exceptional chemical and thermal stability of zeolitic imidazolate frameworks[J].PNAS，2006，103（27）：10186-10191. |
| 23 | FéREY G， MELLOT-DRAZNIEKS C， SERRE C，et al.A chromium terephthalate-based solid with unusually large pore volumes and surface area[J].Science，2005，309（5743）：2040-2042. |
| 24 | EHRENMANN J， HENNINGER S K， JANIAK C.Water adsorption characteristics of MIL-101 for heat-transformation applications of MOFs[J].European Journal of Inorganic Chemistry， 2011（4）：471-474. |
| 25 | JEREMIAS F， FR?HLICH D， JANIAK C，et al.Water and methanol adsorption on MOFs for cycling heat transformation process-es[J].New Journal of Chemistry，2014，38（5）：1846-1852. |
| 26 | LIU Zhilu， AN Guoliang， XIA Xiaoxiao，et al.The potential use of metal-organic framework/ammonia working pairs in adsorption chillers[J].Journal of Materials Chemistry A，2021，9（10）：6188-6195. |
| 27 | DE LANGE M F， VEROUDEN K J F M， VLUGT T J H，et al.Adsorption-driven heat pumps：The potential of metal-organic frameworks[J].Chemical Reviews，2015，115（22）：12205-12250. |
| 28 | YAN Jian， YU Ying， MA Chen，et al.Adsorption isotherms and kinetics of water vapor on novel adsorbents MIL-101（Cr）@GO with super-high capacity[J].Applied Thermal Engineering，2015，84：118-125. |
| 29 | LIU Zhongbao， GAO Jiayang， QI Xin，et al.Experimental study on activated carbon-MIL-101（Cr） composites for ethanol vapor adsorption[J].Materials，2021，14（14）.Doi：10.3390/ma14143811. |
| 30 | CANIVET J， BONNEFOY J， DANIEL C，et al.Structure-property relationships of water adsorption in metal-organic frameworks[J].New Journal of Chemistry，2014，38（7）：3102-3111. |
| 31 | KHUTIA A， RAMMELBERG H U， SCHMIDT T，et al.Water sorption cycle measurements on functionalized MIL-101Cr for heat transformation application[J].Chemistry of Materials，2013，25（5）：790-798. |
| 32 | JASUJA H， ZANG Ji， SHOLL D S，et al.Rational tuning of water vapor CO2 adsorption in highly stable Zr-based MOFs[J].The Journal of Physical Chemistry C，2012，116（44）：23526-23532. |
| 33 | CMARIK G E， KIM M， COHEN S M，et al.Tuning the adsorption properties of UiO-66 via ligand functionalization[J].Langmuir，2012，28（44）：15606-15613. |
| 34 | SONG Yan， XU Ning， LIU Guoliang，et al.High-yield solar-driven atmospheric water harvesting of metal-organic-framework-derived nanoporous carbon with fast-diffusion water channels[J].Nature Nanotechnology，2022，17（8）：857-863. |
| 35 | TANG Songyuan， WANG Yongsheng， YUAN Yafei，et al.Hydrophilic carbon monoliths derived from metal-organic frameworks@resorcinol-formaldehyde resin for atmospheric water harvest-ing[J].New Carbon Materials，2022，37（1）：237-244. |
| 36 | HAO Guangping， MONDIN G， ZHENG Zhikun，et al.Unusual ultra-hydrophilic，porous carbon cuboids for atmospheric-water cap- ture[J].Angewandte Chemie，2015，54（6）：1941-1945. |
| 37 | MAKHANYA N， OBOIRIEN B， REN Jianwei，et al.Recent advances on thermal energy storage using metal-organic frameworks（MOFs）[J].Journal of Energy Storage，2021，34. Doi：10.1016/j.est.2020.102179. |
| 38 | LIU Zhongbao， ZHAO Banghua， ZHU Longqian，et al.Performance of MIL-101（Cr）/water working pair adsorption refrigeration system based on a new type of adsorbent filling method[J].Materials，2020，13（1）.Doi：10.3390/ma13010195. |
| 39 | ZHAO Y J， WANG R Z， ZHANG Y N，et al.Development of SrBr2 composite sorbents for a sorption thermal energy storage system to store low-temperature heat[J].Energy，2016，115：129-139. |
| 40 | YU N， WANG R Z， WANG L W.Theoretical and experimental investigation of a closed sorption thermal storage prototype using LiCl/water[J].Energy，2015，93：1523-1534. |
| 41 | PALOMBA V， VASTA S， FRENI A.Experimental testing of AQSOA FAM Z02/water adsorption system for heat and cold storage[J].Applied Thermal Engineering，2017，124：967-974. |
/
| 〈 |
|
〉 |
