无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ
综述与专论

铬渣资源化利用研究进展

  • 蒋子文 ,
  • 全学军 ,
  • 李纲 ,
  • 鹿存房 ,
  • 郭毅军 ,
  • 陈号 ,
  • 周彦阔 ,
  • 程治良
展开
  • 重庆理工大学化学化工学院,重庆 400054
蒋子文(1997— ),男,硕士研究生,研究方向为资源环境化工;E-mail:1351989003@qq.com

收稿日期: 2022-04-07

  网络出版日期: 2023-02-16

基金资助

重庆英才创新项目(CQYC20210309538)

Research progress of resource utilization of chromium slag

  • Ziwen JIANG ,
  • Xuejun QUAN ,
  • Gang LI ,
  • Cunfang LU ,
  • Yijun GUO ,
  • Hao CHEN ,
  • Yankuo ZHOU ,
  • Zhiliang CHENG
Expand
  • School of Chemistry and Chemical Engineering,Chongqing University of Technology,Chongqing 400054,China

Received date: 2022-04-07

  Online published: 2023-02-16

摘要

为解决目前铬渣无害化处理不彻底且未对其中的铬进行资源化利用的问题,综述了国内外铬渣处理现状,介绍了铬渣来源和成分,重点梳理和分析了有钙焙烧渣在钢铁行业的应用、无钙焙烧渣中金属回收以及液相氧化渣的资源利用。通过总结和比较,提出了采用烧结炼铁工艺处理有钙焙烧渣、采用碱浸法回收无钙焙烧渣中金属以及液相氧化渣直接用作炼铁原料的建议,指出了铬盐行业在未来发展的同时,应该加强源头创新,实现工业共生,最终达到清洁生产的目的。

本文引用格式

蒋子文 , 全学军 , 李纲 , 鹿存房 , 郭毅军 , 陈号 , 周彦阔 , 程治良 . 铬渣资源化利用研究进展[J]. 无机盐工业, 2023 , 55(2) : 26 -35 . DOI: 10.19964/j.issn.1006-4990.2022-0172

Abstract

In order to solve the problem that the harmless treatment of chromium slag was not complete and the chromium in chromium slag was not recycled,the status quo of chromium slag treatment at home and abroad was described,the source and composition of chromium slag were introduced,and the application of calcined slags with calcium in iron and steel industry,metal recovery from calcined slags without calcium and resource utilization of liquid-phase oxidized slags were emphatically combed and analyzed.Through summarizing and comparing,the suggestions of treating calcium slag by sintering iron-making process,recovering metal from calcium-free slag by alkali leaching and using liquid phase oxidized slag as iron making material were put forward.It was pointed out that the chromite industry should strengthen the source innovation,realize industrial symbiosis and finally achieve the goal of clean production while developing in the future.

参考文献

1 Liu Zhangbin, Zheng Jiayi, Liu Weizhen,et al.Identification of the key host phases of Cr in fresh chromite ore processing residue(COPR)[J].Science of The Total Environment,2020,703.Doi:10.1016/j.scitotenv.2019.135075 .
2 MOLINARI S, MAGRO M, CARBONE C,et al.Environmental implications of one-century COPRs evolution in a single industrial site:From leaching impact to sustainable remediation of CrVI polluted groundwater[J].Chemosphere,2021,283.Doi:10.1016/j. chemosphere.2021.131211 .
3 MATERN K, WEIGAND H, SINGH A,et al.Environmental status of groundwater affected by chromite ore processing residue (COPR) dumpsites during pre-monsoon and monsoon seasons[J].Environmental Science and Pollution Research,2017,24(4):3582-3592.
4 SUN Qianzhe, LIU Feng, YUAN Yanjie,et al.Cellulose mediated reduction and immobilization of Cr(Ⅵ) in chromite ore processing residue[J].Journal of Hazardous Materials,2020,394.Doi:10.1016/j.jhazmat.2020.122538 .
5 BAI Z T, ZHANG Z A, GUO M,et al.Magnetic separation and extraction chrome from high carbon ferrochrome slag[J].Materials Research Innovations,2015,19(sup2):S2-113.
6 YANG Zhihui, ZHANG Xiaoming, JIANG Zhi,et al.Reductive materials for remediation of hexavalent chromium contaminated soil-A review[J].Science of the Total Environment,2021,773.Doi:10.1016/j.scitotenv.2021.145654 .
7 庆朋辉,董玉明,王兴润,等.铬铁矿无钙焙烧铬渣的深度提铬与无害化处理[J].无机盐工业,2020,52(6):63-67,104.
7 QING Penghui, DONG Yuming, WANG Xingrun,et al.Chromium extraction and detoxification of processing residue from lime-free roasting process of chromite ore[J].Inorganic Chemicals Industry,2020,52(6):63-67,104.
8 封承飞.微波强化焙烧铬铁矿加压氧化浸出及铬酸钠的制备研究[D].重庆:重庆理工大学,2021.
8 FENG Chengfei.Study on pressure oxidation leaching of chromite roasted by microwave and preparation of sodium chromate[D].Chongqing:Chongqing University of Technology,2021.
9 康春生.铬铁矿焙烧渣贮存对渣性能影响研究[J].铁合金,2021,52(3):28-30.
9 KANG Chunsheng.Study on the effect of chromite roasting slag storage on slag properties[J].Ferro-Alloys,2021,52(3):28-30.
10 吴俊.铬铁矿无钙焙烧渣的解毒及浸出研究[D].重庆:重庆理工大学,2018.
10 WU Jun.Detoxification and leaching behaviour of chromite ore processing residue(COPR)[D].Chongqing:Chongqing University of Technology,2018.
11 闫潇.湿法解毒后复溶铬渣堆场污染特征及复合微生物修复研究[D].北京:北京有色金属研究总院,2021.
11 YAN Xiao.Pollution pattern and bioremediation by microbes of chromium smelting slags with re-dissolution after wet detoxification[D].Beijing:Beijing General Research Institute for Non-ferrous Metals,2021.
12 QI Quan, LI Liang, WEI Liangyu,et al.Study on leaching kinetics of hexavalent chromium from aged calcium-free chromium slag[J].Main Group Chemistry,2021,20(3):317-329.
13 叶鹏.铬铁矿无钙焙烧渣中铁铝铬的资源化利用[D].重庆:重庆理工大学,2020.
13 YE Peng.The recycling technology of ferrum,aluminum,chromium in chromite ore processing residue[D].Chongqing:Chong-qing University of Technology,2020.
14 杨浦.铬盐返渣陈放-二次分选的铬形态特征及减排研究[D].武汉:武汉工程大学,2019.
14 YANG Pu.Study on the chromium returned slag aging-morphological characteristics in two sorting and emission reduction of chromium[D].Wuhan:Wuhan Institute of Technology,2019.
15 牛健.铬渣烧结炼铁的应用研究[J].商品与质量,2020(8):64.
15 NIU Jian.Application research of chrome slag sintering ironmaking[J].The Merchandise and Quality,2020,(8):64.
16 党俊.铬渣烧结杯试验研究[J].酒钢科技,2020(2):14-18.
16 Dang JUN.The experiment study on the chromium slag sintering pot[J].Jiugang Technology,2020(2):14-18.
17 高鹏冲.高铬铸铁轧辊差温热处理工艺研究[D].石家庄:河北科技大学,2020.
17 GAO Pengchong.Study on differential heating heat treatment of high chromium cast iron rolls[D].Shijiazhuang:Hebei University of Science and Technology,2020.
18 WU Junnian, LI Chengliang, YANG Fan.The disposition of chromite ore processing residue(COPR) incorporating industrial symbiosis[J].Journal of Cleaner Production,2015,95:156-162.
19 荆涛.化工企业铬渣无害化处理及资源再利用技术[J].化工设计通讯,2020,46(7):227-228.
19 JING Tao.Harmless treatment of chromium slag and resource reuse technology in chemical enterprises[J].Chemical Engineering Design Communications,2020,46(7):227-228.
20 HEYNS M W, MOSTAFA M M H, MUKANDILA E.Suitability of chrome slag as an aggregate for asphalt in south africa[J].J Civil Engg ID,2021,2(1):1-9.
21 谭建红.铬渣治理及综合利用途径探讨[D].重庆:重庆大学,2005.
21 TAN Jianhong.Study on disposal and maltiparpose atilization of chromium residues[D].Chongqing:Chongqing University,2005.
22 何力为,周学进,宁平.一氧化碳脱毒铬渣制备水泥矿物掺合料[J].无机盐工业,2021,53(5):73-77.
22 HE Liwei, ZHOU Xuejin, NING Ping.Preparation of cement mineral admixture from chromium slag detoxified by carbon monoxide[J].Inorganic Chemicals Industry,2021,53(5):73-77.
23 YANG Liyuan, MA Haixiao.Experimental study on the effect of clinker mineral composition on the properties of Portland ce-ment[J].Integrated Ferroelectrics,2021,217(1):1-10.
24 朱凌颖,张志远.一种以碳铬渣为主要骨料的高强混凝土及其制备方法:中国,109251004A[P].2019-01-22.
25 CHENG Shukai, SHUI Zhonghe, YU Rui,et al.Durability and environment evaluation of an eco-friendly cement-based material incorporating recycled chromium containing slag[J].Journal of Cleaner Production,2018,185:23-31.
26 SALIHPASAOGLU F, SENGUL O.Use of waste ferrochromium slag as aggregate in concrete[J].Journal of Material Cycles and Waste Management,2020,22(6):2048-2058.
27 张潇,水中和,汪发红.以硅铬渣为细骨料的混凝土性能研究[J].混凝土与水泥制品,2016(3):13-16.
27 ZHANG Xiao, SHUI Zhonghe, WANG Fahong.Research on performance of concrete with silicon chromium slag(SCS) as fine aggregate[J].China Concrete and Cement Products,2016(3):13-16.
28 HE Liwei, LI Bin, LIN Zhang,et al.Mechanism of dry detoxification of chromium slag by carbon monoxide[J].Environmental Chemistry Letters,2019,17(3):1375-1381.
29 GENCEL O, SUTCU M, ERDOGMUS E,et al.Properties of bricks with waste ferrochromium slag and zeolite[J].Journal of Cleaner Production,2013,59:111-119.
30 马兵,张后虎,闫佳莉,等.一种铬渣的干法解毒并资源化制砖的制备方法:中国,110723934A[P].2020-01-24.
31 CHEN Ziwei, WANG Hao, WANG Minghao,et al.Investigation of cooling processes of molten slags to develop multilevel control method for cleaner production in mineral wool[J].Journal of Clean- er Production,2022,339.Doi:10.1016/j.jclepro.2022.130548 .
32 赵贵清,陈亚团.酒钢生产矿棉可行性探析[J].酒钢科技,2019(4):11-16.
32 ZHAO Guiqing, CHEN Yatuan.Feasibility analysis of mineral wool production in JISCO[J].Jiugang Technology,2019(4):11-16.
33 宋瑞珉.利用铬渣制矿棉制品[J].无机盐工业,1987,19(5):26-30.
33 SONG Ruimin.Making mineral wool products from chromium slag[J].Inorganic Chemicals Industry,1987,19(5):26-30.
34 ZHAO Guizhou, ZHANG Lingling, CANG Daqiang.Pilot trial of detoxification of chromium slag in cyclone furnace and production of slag wool fibres[J].Journal of Hazardous Materials,2018,358:122-128.
35 CHEN Zhiliang, ZHANG Peng, BROWN K G,et al.Development of a geochemical speciation model for use in evaluating leaching from a cementitious radioactive waste form[J].Environmental Science & Technology,2021,55(13):8642-8653.
36 张瑞锋.包头市固体废弃物综合利用的探讨[J].内蒙古水利,2015(5):171-172.
36 ZHANG Ruifeng.Discussion on comprehensive utilization of solid waste in Baotou city[J].Inner Mongolia Water Resources,2015(5):171-172.
37 LIU Chuanbei, LIU Laibao, TAN Kefeng,et al.Fabrication and characterization of porous cordierite ceramics prepared from ferrochromium slag[J].Ceramics International,2016,42(1):734-742.
38 GE Xuexiang, ZHOU Mingkai, WANG Huaide,et al.Preparation and characterization of ceramic foams from chromium slag and coal bottom ash[J].Ceramics International,2018,44(10):11888-11891.
39 LI Bin, CHEN Caizhu, ZHANG Yuwei,et al.Preparation of glass-ceramics from chromite-containing tailings solidified with red mud[J].Surfaces and Interfaces,2021,25.Doi:10.1016/j.surfin.2021.101210 .
40 LIAO Changzhong, TANG Yuanyuan, LEE Poheng,et al.Detoxification and immobilization of chromite ore processing residue in spinel-based glass-ceramic[J].Journal of Hazardous Materials,2017,321:449-455.
41 LIU Shiquan, MISHRA S B, ZHANG Yun,et al.Uptake of hexavalent chromium in electroplating wastewater by hydrothermally treated and functionalized sand and its sustainable reutilization for glass production[J].ACS Sustainable Chemistry & Engineering,2017,5(2):1509-1516.
42 方久华,左明扬,杨峰,等.以废渣配制玻璃着色剂的研究[J].硅酸盐通报,2015,34(9):2731-2734.
42 FANG Jiuhua, ZUO Mingyang, YANG Feng,et al.Glass colorant prepared with waste residue[J].Bulletin of the Chinese Ceramic Society,2015,34(9):2731-2734.
43 XU Tengteng, XU Yibiao, LI Yawei,et al.Corrosion mechanisms of magnesia-chrome refractories in copper slag and concurrent formation of hexavalent chrom ium[J].Journal of Alloys and Compounds,2019,786:306-313.
44 任中山.利用铬渣制备致密耐火材料的方法及其专用系统:中国,106278333A[P].2017-01-04.
45 GAYO G X, LAVAT A E.Green ceramic pigment based on chromium recovered from a plating waste[J].Ceramics International,2018,44(18):22181-22188.
46 张本曰,刘丹,郭锐,等.含镍蛇纹石的综合利用现状[J].矿产综合利用,2020(4):13-20.
46 ZHANG Benyue, LIU Dan, GUO Rui,et al.Comprehensive utilization status of nickel-containing serpentine[J].Multipurpose Utilization of Mineral Resources,2020(4):13-20.
47 何芳华.铬渣无害化处理处置和综合利用研究:以陆良某公司为例[D].昆明:昆明理工大学,2015.
47 HE Fanghua.The research on harmless treatment and comprehensive utilization of chromium slags:An example from Luliang chemical limited coporation[D].Kunming:Kunming University of Science and Technology,2015.
48 赵青.碱式硫酸铬清洁制备工艺的基础研究[D].沈阳:东北大学,2015.
48 ZHAO Qing.Fundamental research on the cleaner preparation process of basic chromium sulfate[D].Shenyang:Northeastern University,2015.
49 毛运秋.煤化工与钢铁行业协同发展趋势分析[J].河南化工,2021,38(6):4-7.
49 MAO Yunqiu.Analysis on the collaborative development trend of coal chemical industry and steel industry[J].Henan Chemical Industry,2021,38(6):4-7.
50 刘继军,林红梅,胡国荣,等.利用铬铁合金生产铬盐的新工艺研究[J].无机盐工业,2021,53(6):156-159.
50 LIU Jijun, LIN Hongmei, HU Guorong,et al.Study on new process of producing chromium salt with ferrochrome alloy[J].Inorganic Chemicals Industry,2021,53(6):156-159.
51 赵备备,王少娜,郑诗礼,等.铬盐无钙焙烧渣加压硫酸浸出[J].过程工程学报,2014,14(6):915-922.
51 ZHAO Beibei, WANG Shaona, ZHENG Shili,et al.Pressure leaching of chromium-containing slag from non-calcium roasting with sulfuric acid[J].The Chinese Journal of Process Engineering,2014,14(6):915-922.
52 叶鹏,全学军,秦险峰,等.铬铁矿无钙焙烧渣盐酸浸出[J].化工学报,2019,70(11):4428-4436.
52 YE Peng, QUAN Xuejun, QIN Xianfeng,et al.Leaching of chromite ore processing residue from non-calcium roasting with hydrochloric acid[J].CIESC Journal,2019,70(11):4428-4436.
53 YU Kaiping, CHEN Bo, ZHANG Hongling,et al.An efficient method of chromium extraction from chromium-containing slag with a high silicon content[J].Hydrometallurgy,2016,162:86-93.
54 HU Shaoyan, WANG Deyong, LI Xianglong,et al.Enrichment characteristics of Cr in chromium slag after pre-reduction and melting/magnetic separation treatment[J].Materials:Basel,Switzerland,2021,14(17).Doi:10.3390/ma14174937 .
55 王贞,袁守谦,张忠元,等.从铬、钒渣中提取有价金属[J].矿冶工程,2016,36(3):84-86,90.
55 WANG Zhen, YUAN Shouqian, ZHANG Zhongyuan,et al.Recovery of valuable metals from chromium and vanadium slag[J].Mining and Metallurgical Engineering,2016,36(3):84-86,90.
56 韩登仑,马晓君,宋春林,等. 一种用无钙铬渣生产 15Cr彩色合金钢板的生产方法:中国,107557648A[P].2018-01-09.
57 贺真,刘文莉,马强,等.一种利用铬渣协同处置焚烧飞灰的无害化处理方法:中国,110586612A[P].2019-12-20.
58 陈东辉,李兰杰,白瑞国,等.一种铬渣资源化清洁利用的方法:中国,104674014B[P].2015-06-03.
59 LONG Hongming, MENG Qingmin, WANG Ping,et al.Preparation of chromium-iron metal powder from chromium slag by reduction roasting and magnetic separation[J].Journal of Iron and Steel Research,International,2015,22(9):771-776.
60 张胜全,王子仁,王胜,等.一种铬渣解毒综合利用前处理方法:中国,110904329A[P].2020-03-24.
61 李秉正,邓勇.利用喷煤工艺形式进入冶金高炉的无害化处理铬渣的方法:中国,101775449A[P].2011-06-08.
文章导航

/