赤泥在回收金属和建筑材料领域的研究进展
收稿日期: 2022-03-05
网络出版日期: 2023-02-16
基金资助
国家科学自然基金项目(1908085QE190);安徽工业大学校级基金项目(RD19200254)
Research progress of red mud in field of recycled metals and building materials
Received date: 2022-03-05
Online published: 2023-02-16
徐文珍 , 李灿华 , 季洪峰 , 李子木 , 吴朝阳 , 李明晖 . 赤泥在回收金属和建筑材料领域的研究进展[J]. 无机盐工业, 2023 , 55(2) : 10 -18 . DOI: 10.19964/j.issn.1006-4990.2022-0100
Red mud is the polluting waste residue discharged from the aluminum industry to extract alumina.Improper treatment will cause great harm to the ecological environment.The chemical composition，phase composition and production path of red mud were introduced and the main processes and characteristics of recovering iron，aluminum，titanium，scandium and other metal resources from red mud were analyzed.It was elaborated that adding appropriate amount of red mud could enhance the mechanical properties and fire resistance of building materials，solidify the radioactive elements in red mud，and reduce environmental pollution.In addition，the preparation of geopolymer materials，glass-ceramics，composite materials and other processes were not yet mature.It was still necessary to seek efficient target metal purification technology and efficient and rational disposal method of waste residue and waste liquid，and develop a complete set of red mud development and application process.
Key words： red mud; metal resources; building materials; resource utilization
| 1 | DENG Bona， LI Guanghui， LUO Jun，et al.Enrichment of Sc2O3 and TiO2 from bauxite ore residues[J].Journal of Hazardous Materials，2017，331：71-80. |
| 2 | NAJAR P A M， KARN A， DWIVEDI S，et al.Autogenous dissolution and nano-processing of iron in red mud：Green chemistry for value addition and recovery of materials[J].Materials Today：Proceedings，2020，26：69-76. |
| 3 | NARAYANAN R P， PALANTAVIDA S.An initial screening of commercial phosphorus ligands on the recovery of metal ions from red mud[J].Materials Today：Proceedings，2021，41：692-697. |
| 4 | 薛生国，李玉冰，郭颖.氧化铝工业赤泥环境影响研究进展[J].中国科学院大学学报，2017，34（4）：401-412. |
| 4 | XUE Shengguo， LI Yubing， GUO Ying.Environmental impact of bauxite residue：A comprehensive review[J].Journal of University of Chinese Academy of Sciences，2017，34（4）：401-412. |
| 5 | VENKATESH C， NERELLA R， RAMA CHAND M SRI.Comparison of mechanical and durability properties of treated and untreated red mud concrete[J].Materials Today：Proceedings，2020，27：284-287. |
| 6 | 李彬，王枝平，曲凡，等.赤泥中有价金属的回收现状与展望[J].昆明理工大学学报：自然科学版，2019，44（2）：1-10. |
| 6 | LI Bin， WANG Zhiping， QU Fan，et al.Present situation and prospect of recovery of valuable metals from red mud[J].Journal of Kunming University of Science and Technology：Natural Science，2019，44（2）：1-10. |
| 7 | 李红涛.洛阳市洛华粉体工程特种耐火材料有限公司：赤泥治理如何才能“吃干榨净”[J].中国高新科技，2021（20）：24-27. |
| 7 | LI Hongtao.Luoyang luohua powder engineering special refractories Co.，Ltd.：how to“eat dry and squeeze clean” red mud treatment[J].China High and New Technology，2021（20）：24-27. |
| 8 | 顾汉念.赤泥中放射性元素U和Th的赋存状态研究[D].贵州：中国科学院大学，2013. |
| 8 | GU Hannian.Study on the occurrence state of radioactive elements U and Th in red mud[D].Guizhou：University of Chinese Academy of Sciences，2013 |
| 9 | QU Yang， LIAN Bin.Bioleaching of rare earth and radioactive elements from red mud using Penicillium tricolor RM-10[J].Bioresource Technology，2013，136：16-23. |
| 10 | HUA Yumei， HEAL K V， FRIESL-HANL W.The use of red mud as an immobiliser for metal/metalloid-contaminated soil：A review[J].Journal of Hazardous Materials，2017，325：17-30. |
| 11 | NIKBIN I M， ALIAGHAZADEH M， CHARKHTAB SH，et al.Environmental impacts and mechanical properties of lightweight concrete containing bauxite residue（red mud）[J].Journal of Cle- aner Production，2018，172：2683-2694. |
| 12 | 肖慧霞，徐美玲，李风海，等.赤泥综合利用的研究进展[J].应用化工，2015，44（10）：1930-1933. |
| 12 | XIAO Huixia， XU Meiling， LI Fenghai，et al.Review on the comprehensive utilization of red mud[J].Applied Chemical Industry，2015，44（10）：1930-1933. |
| 13 | LI Yuancheng， MIN Xiaobo， KE Yong，et al.Utilization of red mud and Pb/Zn smelter waste for the synthesis of a red mud-based cementitious material[J].Journal of Hazardous Materials，2018，344：343-349. |
| 14 | 王克勤，李爱秀，邓海霞，等.山西氧化铝赤泥的物化性质[J].轻金属，2012（4）：25-28. |
| 14 | WANG Keqin， LI Aixiu， DENG Haixia，et al.Physicochemical properties of red mud in Shanxi[J].Light Metals，2012（4）：25-28. |
| 15 | 苏泽林，王东波，黄纤晴，等.高碱性拜耳法赤泥碳酸化脱碱及其机理研究[J].硅酸盐通报，2020，39（5）：1547-1552. |
| 15 | SU Zelin， WANG Dongbo， HUANG Xianqing，et al.Research on dealkalization and mechanism of high-alkaline bayer process red mud by carbonation[J].Bulletin of the Chinese Ceramic Society，2020，39（5）：1547-1552. |
| 16 | 丛云伶.赤泥微波碳热还原-磁选回收铁工艺研究[D].鞍山：辽宁科技大学，2018. |
| 16 | CONG Yunling.Study on iron recovery process of red mud on microwave carbon thermal reduction and magnetic separation methods[D].Anshan：University of Science and Technology Liaoning，2018. |
| 17 | AGRAWAL S， DHAWAN N.Evaluation of red mud as a polymetallic source-A review[J].Minerals Engineering，2021，171.Doi：10.1016/j.mineng.2021.107084 . |
| 18 | MOMBELLI D， MAPELLI C， BARELLA S，et al.Characterization of cast iron and slag produced by red muds reduction via Arc Transferred Plasma（ATP） reactor under different smelting conditions[J].Journal of Environmental Chemical Engineering，2020，8（5）.Doi：10.1016/j.jece.2020.104293 . |
| 19 | 刘邦煜，张伟，林华.贵州铝厂拜耳赤泥综合利用探讨[J].无机盐工业，2014，46（10）：8-13. |
| 19 | LIU Bangyu， ZHANG Wei， LIN Hua.Discussion on comprehensive utilization of red mud from bayer process in Guizhou Aluminum Works[J].Inorganic Chemicals Industry，2014，46（10）：8-13. |
| 20 | MAIHATCHI AHAMED A， PONS M N， RICOUX Q，et al.Production of electrolytic iron from red mud in alkaline media[J].Journal of Environmental Management，2020，266.Doi：10.1016/j.jenvman.2020.110547 . |
| 21 | 李德贵，阮素云，覃铭，等.赤泥原料及其对吸附剂吸附性能的影响[J].当代化工，2015，44（1）：41-44. |
| 21 | LI Degui， RUAN Suyun， QIN Ming，et al.Red mud raw materials and their influence on adsorption properties for prepared adsorbents[J].Contemporary Chemical Industry，2015，44（1）：41-44. |
| 22 | 伊元荣，韩敏芳，于立安.利用赤泥捕获CO2反应特性[J].化工学报，2011，62（9）：2635-2642. |
| 22 | YI Yuanrong， HAN Minfang， YU Lian.Reaction characteristics of CO2 captured by red mud[J].CIESC Journal，2011，62（9）：2635-2642. |
| 23 | 刘继东，任杰，陈娟，等.酸雨淋溶条件下赤泥中重金属在土壤中的迁移特性及其潜在危害[J].农业环境科学学报，2017，36（1）：76-84. |
| 23 | LIU Jidong， REN Jie， CHEN Juan，et al.Migration characteristics and potential hazards of heavy metals from bauxite residue to soil under simulated acid rain[J].Journal of Agro-Environment Science，2017，36（1）：76-84. |
| 24 | WANG Mengfan， LIU Xiaoming.Applications of red mud as an environmental remediation material：A review[J].Journal of Hazardous Materials，2021，408.Doi：10.1016/j.jhazmat.2020.124420 . |
| 25 | HERTEL T， VAN DEN BULCK A， BLANPAIN B，et al.An integrated process for iron recovery and binder production from bauxite residue（red mud）[J].Materials Letters，2020，264.Doi：10.1016/j.matlet.2019.127273 . |
| 26 | 范艳青，朱坤娥，蒋训雄.赤泥中铁资源的回收利用研究[J].有色金属：冶炼部分，2019（9）：72-76，102. |
| 26 | FAN Yanqing， ZHU Kune， JIANG Xunxiong.Study on comprehensive utilization of iron from red mud[J].Nonferrous Metals：Extractive Metallurgy，2019（9）：72-76，102. |
| 27 | 孙永升.高磷鲕状赤铁矿石深度还原基础研究[D].沈阳：东北大学，2015. |
| 27 | SUN Yongsheng.Fundamentals for coal-based reduction of high-phosphorus oolitic iron ore[D].Shenyang：Northeastern University，2015. |
| 28 | LI Dongsheng， CHUN Tiejun， WANG Zhen，et al.Recovery of iron from carbon bearing briquettes of high-phosphorus iron ore by direct reduction and magnetic separation[J].Guocheng Gon-gcheng Xuebao/The Chinese Journal of Process Engineering，2018，18（2）：375-381. |
| 29 | 吴道洪，古明远，曹志成，等.赤泥直接还原资源化利用中试研究[J].中国废钢铁，2017（6）：35-40. |
| 29 | WU Daohong， GU Mingyuan， CAO Zhicheng，et al.Theresearch of direct reduction and pilot plant test of resourceutilization of red mud[J].Iron & Steel Scrap of China，2017（6）：35-40. |
| 30 | 王健月，崔卫华，张以河，等.拜耳法赤泥中铁的强磁选预富集-深度还原-弱磁选试验[J].金属矿山，2016（1）：60-64. |
| 30 | WANG Jianyue， CUI Weihua， ZHANG Yihe，et al.Iron recovering from bayer process red mud with high intensity magnetic pre-concentration-deep reduction-low intensity magnetic separation method[J].Metal Mine，2016（1）：60-64. |
| 31 | 刘邦煜，叶春，林华.工业废盐酸浸出拜耳赤泥中铁、铝的试验研究[J].矿产综合利用，2016（5）：92-96. |
| 31 | LIU Bangyu， YE Chun， LIN Hua.Experimental research on leaching of iron，aluminum from bayer red mud by using the industrial waste hydrochloric acid[J].Multipurpose Utilization of Mineral Resources，2016（5）：92-96. |
| 32 | 丁冲，周卫宁，单志强，等.还原焙烧赤泥-综合回收铁铝研究[J].矿冶工程，2016，36（5）：103-106. |
| 32 | DING Chong， ZHOU Weining， SHAN Zhiqiang，et al.Recovery of iron and aluminum from red mud by reduction roasting[J].Mining and Metallurgical Engineering，2016，36（5）：103-106. |
| 33 | 朱晓波，李望，管学茂.赤泥酸浸提钒[J].过程工程学报，2014，14（5）：792-796. |
| 33 | ZHU Xiaobo， LI Wang， GUAN Xuemao.Leaching of red mud with different acids for extraction of vanadium[J].The Chinese Journal of Process Engineering，2014，14（5）：792-796. |
| 34 | 杨涛，王志坚，肖劲，等.赤泥和钛白废液中提钪的浸出工艺研究[J].矿冶，2015，24（5）：37-40. |
| 34 | YANG Tao， WANG Zhijian， XIAO Jin，et al.Study on leaching technology of extracting scandium from red mud and titanium white waste liquid[J].Mining and Metallurgy，2015，24（5）：37-40. |
| 35 | 王璐，郝彦忠，郝增发.赤泥中有价金属提取与综合利用进展[J].中国有色金属学报，2018，28（8）：1697-1710. |
| 35 | WANG Lu， HAO Yanzhong， HAO Zengfa.Progress in valuable metal element recovery and utilization of red mud-A review[J].The Chinese Journal of Nonferrous Metals，2018，28（8）：1697-1710. |
| 36 | LI Siwei， PAN Jian， ZHU Deqing，et al.A new route for separation and recovery of Fe，Al and Ti from red mud[J].Resources，Conservation and Recycling，2021，168.Doi：10.1016/j.resconrec.2020.105314 . |
| 37 | 龙琼，路坊海，周登凤，等.磁场下硫酸浸出赤泥回收钛的研究[J].广东化工，2016，43（17）：32-33. |
| 37 | LONG Qiong， LU Fanghai， ZHOU Dengfeng，et al.Experimental investigation on leaching titanium from red mud by sulphuric acid under magnetic fields[J].Guangdong Chemical Industry，2016，43（17）：32-33. |
| 38 | BORRA C R， BLANPAIN B， PONTIKES Y，et al.Recovery of rare earths and major metals from bauxite residue（red mud） by alkali roasting，smelting，and leaching[J].Journal of Sustainable Metallurgy，2017，3（2）：393-404. |
| 39 | 罗星，马荣锴，李勇，等.从广西某赤泥中盐酸浸出钪实验研究[J].矿冶工程，2020，40（2）：98-100. |
| 39 | LUO Xing， MA Rongkai， LI Yong，et al.Experimental study on hydrochloric acid leaching of scandium from red mud in Guan-gxi[J].Mining and Metallurgical Engineering，2020，40（2）：98-100. |
| 40 | 刘蕊，陈金珠，刘子琪，等.从拜耳法赤泥中提取钪[J].应用化工，2021，50（6）：1743-1745. |
| 40 | LIU Rui， CHEN Jinzhu， LIU Ziqi，et al.Extraction of scandium from Bayer red mud[J].Applied Chemical Industry，2021，50（6）：1743-1745. |
| 41 | LEI Qingyuan， HE Dewen， ZHOU Kanggen，et al.Separation and recovery of scandium and titanium from red mud leaching liquor through a neutralization precipitation-acid leaching approach[J].Journal of Rare Earths，2021，39（9）：1126-1132. |
| 42 | ZHANG Jian， LI Shucai， LI Zhaofeng，et al.Properties of red mud blended with magnesium phosphate cement paste：Feasibility of grouting material preparation[J].Construction and Building Materials，2020，260.Doi：10.1016/j.conbuildmat.2020.119704 . |
| 43 | KRIVENKO P， KOVALCHUK O， PASKO A，et al.Development of alkali activated cements and concrete mixture design with high volumes of red mud[J].Construction and Building Materials，2017，151：819-826. |
| 44 | SETHY K， SITHA R K， BARPANDA S，et al.Experimental investigation of strength properties of red mud concrete[J].AIP Conference Proceedings，2019，2158（1）.Doi：10.1063/1.5127139 . |
| 45 | TANG W C， WANG Z， DONNE S W，et al.Influence of red mud on mechanical and durability performance of self-compacting con-crete[J].Journal of Hazardous Materials，2019，379.Doi：10.1016/j.jhazmat. 2019.120802. |
| 46 | SINGH S， ASWATH M U， RANGANATH R V.Performance assessment of bricks and prisms：Red mud based geopolymer composite[J].Journal of Building Engineering，2020，32.Doi：101016/j.jobe .2020.101462. |
| 47 | KIM S Y， Yubin JUN， JEON D，et al.Synthesis of structural binder for red brick production based on red mud and fly ash activated using Ca（OH）2 and Na2CO3 [J].Construction and Building Materials，2017，147：101-116. |
| 48 | WANG Wei， CHEN Weijie， LIU Haitao.Recycling of waste red mud for fabrication of SiC/mullite composite porous ceramics[J].Ceramics International，2019，45（8）：9852-9857. |
| 49 | 魏红姗，马小娥，管学茂，等.拜耳法赤泥基轻质保温陶瓷的制备[J].硅酸盐通报，2019，38（3）：749-751，761. |
| 49 | WEI Hongshan， MA Xiaoe， GUAN Xuemao，et al.Preparation of bayer red mud light-weight thermal insulation ceramics[J].Bulletin of the Chinese Ceramic Society，2019，38（3）：749-751，761. |
| 50 | 余泽峰，宋卫锋，王超，等.CTAB改性地聚合物同时去除Cu（Ⅱ）和Cr（Ⅵ）[J].环境科学学报，2020，40（3）：968-975. |
| 50 | YU Zefeng， SONG Weifeng， WANG Chao，et al.Simultaneous remo-val of Cu（Ⅱ） and Cr（Ⅵ） with CTAB modified geopolymer[J].Acta Scientiae Circumstantiae，2020，40（3）：968-975. |
| 51 | YANG Zhaotong， MOCADLO R， ZHAO Mengxuan，et al.Preparation of a geopolymer from red mud slurry and class F fly ash and its behavior at elevated temperatures[J].Construction and Building Materials，2019，221：308-317. |
| 52 | LI Yuancheng， MIN Xiaobo， KE Yong，et al.Preparation of red mud-based geopolymer materials from MSWI fly ash and red mud by mechanical activation[J].Waste Management，2019，83：202-208. |
| 53 | 张默，王诗彧.常温制备赤泥-低钙粉煤灰基地聚物的试验和微观研究[J].材料导报，2019，33（6）：980-985. |
| 53 | ZHANG Mo， WANG Shiyu.Experimental investigation and microstructural analysis of ambient temperature cured red mud-class F fly ash based geopolymer[J].Materials Reports，2019，33（6）：980-985. |
| 54 | ZHAO Jiling， WANG Yanling， KANG Junfeng，et al.Effect of SnO2 on the structure and chemical durability of the glass prepared by red mud[J].Journal of Non-Crystalline Solids，2019，509：54-59. |
| 55 | PARK H S， PARK J H.Vitrification of red mud with mine wastes through melting and granulation process-preparation of glass ball[J].Journal of Non-Crystalline Solids，2017，475：129-135. |
| 56 | KIM Y， KIM M， SOHN J，et al.Applicability of gold tailings，waste limestone，red mud，and ferronickel slag for producing glass fibers[J].Journal of Cleaner Production，2018，203：957- 965. |
| 57 | PANWAR N， CHAUHAN A， SINGH PALI H，et al.Fabrication of aluminum 6061 red-mud composite using stir casting and micro structure observation[J].Materials Today：Proceedings，2020，21：2014-2023. |
| 58 | LI Yunshang， WEI Guangtao， SHAO Luhua，et al.Green synthesis of red mud based ZnO-Fe2O3 composite used for photo-Fenton reaction under visible light[J].Journal of Cleaner Production，2019，207：717-727. |
| 59 | LIU Zhiyong， ZHANG Shu， HU Dan，et al.Paraffin/red mud phase change energy storage composite incorporated gypsum-based and cement-based materials：Micro-structures，thermal and mechanical properties[J].Journal of Hazardous Materials，2019，364：608-620. |
/
| 〈 |
|
〉 |
