钠离子电池正极材料Na3V2（PO4）3研究进展
收稿日期: 2021-10-20
网络出版日期: 2022-05-31
基金资助
国家自然科学基金项目(11765010);国家重点研发计划项目(2019YFC1907900);云南省科技厅应用基础研究计划项目(202001AW070004);云南省院士自由探索基金资助项目(202005AA160008);资源化学教育部重点实验室资助项目(KLRC_ME2001)
Research progress on Na3V2（PO4）3 cathode materials for sodium ion batteries
Received date: 2021-10-20
Online published: 2022-05-31
作为新一代可充电钠离子电池（SIBs）正极材料，Na3V2（PO4）3（NVP）具有理论容量大、化学稳定性好、使用寿命长、天然丰度高、价格低廉等优点，因此，受到了广泛的关注。综述了近年来NVP正极材料的储钠机理、制备方法和改性研究的最新进展。基于固有的晶体结构和离子迁移机制，总结了NVP正极材料的储钠机理。评价了不同制备方法对NVP正极材料的形貌、粒度分布、结晶度等的影响规律。此外，针对NVP正极材料严重的体积效应、电子导电率低、界面兼容性差等问题，总结了主流的改性方法。最后，展望了NVP正极材料在未来大规模储能领域的应用前景，阐述了其在电子导电率低以及体积效应等方面的挑战，并指明了在可控制备NVP以及开发高压电解液等方面的潜在研究方向。
关键词： Na3V2（PO4）3; 钠离子电池; 正极材料; 可逆容量; 电导率
东鹏 , 周英杰 , 侯敏杰 , 杨冬荣 , 戴永年 , 梁风 . 钠离子电池正极材料Na3V2（PO4）3研究进展[J]. 无机盐工业, 2022 , 54(5) : 1 -10 . DOI: 10.19964/j.issn.1006-4990.2021-0629
As a new generation of rechargeable sodium ion battery（SIBs） cathode material，Na3V2（PO4）3（NVP） has attracted extensive attention due to its advantages of large theoretical capacity，good chemical stability，long service life，high natural abundance and low price.The latest advances in sodium storage mechanism，preparation methods and modification of NVP cathode materials were reviewed.Based on the inherent crystal structure and ion migration mechanism，the sodium storage mechanism of NVP cathode material was summarized.The effect law of different preparation methods on the morphology，particle size distribution，and crystallinity of NVP cathode materials was evaluated.In addition，the main modification methods of NVP cathode materials were summarized for serious volume effect，low electronic conductivity，poor interface compatibility and other problems.Finally，the future application prospects of NVP cathode materials in large?scale energy storage were prospected，the challenges of low electronic conductivity and volume effect were discussed.The potential research directions in controllable preparation of NVP and development of high pressure electrolyte were pointed out.
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