钯基催化剂应用于甲酸电氧化反应的研究进展
收稿日期: 2020-08-29
网络出版日期: 2021-05-12
基金资助
国家重点研发计划项目(2017YFB0102900);国家重点研发计划项目(2016YFB0101201);国家自然科学基金项目(21476088);国家自然科学基金项目(21776105);广东省自然科学基金项目(2015B010106012);茂名市科技计划项目(2019472)
Research progress on application of palladium-based catalyst in electrooxidation of formic acid
Received date: 2020-08-29
Online published: 2021-05-12
陈少峰 , 侯兰凤 , 廖世军 . 钯基催化剂应用于甲酸电氧化反应的研究进展[J]. 无机盐工业, 2021 , 53(5) : 33 -38 . DOI: 10.11962/1006-4990.2020-0306
Formic acid is a promising material for chemical hydrogen storage,which can be used as direct fuel for cryogenic liquid fuel cell.As anode materials for direct formic acid fuel cell（DFAFC）,Pd-based catalysts have good catalytic activity for formic acid oxidation,which can overcome the poisoning of CO and carry out via direct route of the electrochemical oxida-tion of formic acid.Reducing noble metal content,improving catalytic activity and stability are the main directions in the re-search field of Pd-based catalytic materials.The electrooxidation and catalytic mechanism of Pd-based catalyst for formic acid at present was mainly introduced.The preparation of Pd alloy catalyst,the control of special morphology and the enhancement of carbon loading on formic acid oxidation activity in recent five years were reviewed.It has practical significance for the continuous development of Pd-based catalyst.
Key words： formic acid; fuel cell; palladium catalyst; carbon loading
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