无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (7): 77-.

• 论文 • 上一篇    

磷酸银-介孔炭复合光催化材料性能的研究

胡 洁1,2,祝建中1,2,丁 莹1,2,凌小佳1,2,吉栋梁1,2   

  1. 1.浅水湖泊综合治理与资源开发教育部重点实验室,江苏南京 210098;2.河海大学环境学院
  • 出版日期:2016-07-10 发布日期:2016-07-25

Study on properties of Ag3PO4-mesoporous  carbon photocatalytic composite

Hu Jie1,2,Zhu Jianzhong1,2,Ding Ying1,2,Ling Xiaojia1,2,Ji Dongliang1,2   

  1. 1.Key Laboratory for Integrated Treatment & Resources Development on Shallow Lakes,Ministry of Education,
    Nanjing 210098,China;2.College of Environment,Hohai University
  • Published:2016-07-10 Online:2016-07-25

摘要: 采用共沉淀法将介孔炭与磷酸银结合,制备出磷酸银-介孔炭复合光催化材料。利用扫描电子显微镜(SEM)、透射电子显微镜(TEM)和X射线衍射等技术手段对所制备材料进行表征,结果表明随着介孔炭负载量的增大,生成的磷酸银粒子尺寸减小。所制备材料中的磷酸银为立方体型,介孔炭的加入不会影响其晶体结构,可以制得性能稳定的复合材料。采用氮气吸-脱附测试对复合光催化材料进行光催化性能的评价,主要考察了不同介孔炭负载量对材料的光催化性能的影响。同时,通过光催化实验发现,当介孔炭负载量为10%时,所得的磷酸银-介孔炭复合光催化材料光催化效果最佳,并且所制备的复合光催化材料具有再循环使用的能力。

关键词: 介孔炭, 磷酸银, 复合光催化材料, 硝基苯

Abstract: Ag3PO4-mesoporous carbon photocatalytic composite was synthesized by coprecipitation method and with silver phosphate and mesoporous carbon.Physicochemical properties of the materials were characterized by SEM,TEM,and XRD etc..The analysis results showed that with the increasing of loading amount of mesoporous carbon,the size of silver phosphate granule got smaller.The samples of silver phosphate were showed as a body-centered cubic silver phosphate.The results also illustrated that the addition of mesoporous carbon into Ag3PO4 did not influence its crystal structure.It showed that the compo- site photocatalysts with the stable function could be obtained.Photocatalytic performances of the materials were also investi- gated by the way of N2 adsorption-desorption.The effect of different loading amounts of mesoporous carbon on photocatalytic activities was mainly investigated. It was also found that Ag3PO4-mesoporous carbon photocatalytic composite showed a better photo-degradation efficiency when the loading amount of mesoporous carbon was 10%.And the photocatalytic composites could be recycled.

Key words: mesoporous carbon, Ag3PO4, photocatalytic composite, nitrobenzol

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