无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (12): 55-.

• 论文 • 上一篇    下一篇

用氟硅酸制备高纯氟化钾联产白炭黑工艺研究

李 霞   

  1. 多氟多化工股份有限公司,河南焦作 454006
  • 出版日期:2016-12-10 发布日期:2016-12-08

Preparation of high purity potassium fluoride and silica by fluorosilicic acid

 LI   Xia   

  1. Do-Fluoride Chemicals Co.,Ltd.,Jiaozuo 454006,China
  • Published:2016-12-10 Online:2016-12-08

摘要: 以工业副产氟硅酸为原料制备氟化钾,会造成磷酸根和硫酸根在氟化钾产品中的累积从而影响产品质量,而且在使用氢氧化钾碱解的过程中碱的用量不好控制,稍过量就会使二氧化硅溶解从而影响氟化钾的产品质量。重点研究了使用工业副产氟硅酸制备高纯氟化钾联产白炭黑的工艺,解决了杂质累积问题,并从实验原理、实验方法、关键点控制、产品质量及成本等方面进行了深度剖析。该工艺具有生产成本低、产品质量好、工艺合理、环境污染小的特点,符合国家倡导的节能减排和资源综合利用的产业政策。

关键词: 氟硅酸, 氟化钾, 白炭黑, 产品质量

Abstract: Using industrial by-product fluorosilicic acid as raw material for preparing potassium fluoride,phosphate,and sul- fate will accumulate in the product therefore affecting the quality of products.The use of potassium hydroxide solution is diffi- cult in the process of quantity control,slightly excessive will dissolve silica,thus affecting the quality of potassium fluoride. This process mainly studied the preparation of high purity potassium fluoride and silica with industrial by-product fluorosili- cic acid,solved the impurity accumulation,and deep analysis was also made from the experimental principle,experimental methods,key points of control,product quality,and cost etc..The process had the characteristics of low production cost,good product quality,reasonable technology,and little environmental pollution.It is in line with the China′s environmental protec- tion policy of energy conservation,emission reduction,and comprehensive utilization of resources.

Key words: fluorosilicic acid, potassium fluoride, silica, product quality

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