无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2016, Vol. 48 ›› Issue (11): 38-.

• 论文 • 上一篇    下一篇

高纯超薄氧化铝制备

吕东芸,杜立永,丁玉强   

  1. 江南大学,江苏无锡 214122
  • 出版日期:2016-11-10 发布日期:2016-11-28

Preparation of high-purity aluminum oxide ultrathin film

 Lu Dong-Yun , DU  Li-Yong, DING  Yu-Qiang   

  1. Jiangnan University,Wuxi 214122,China
  • Published:2016-11-10 Online:2016-11-28

摘要: 随着科学技术的迅猛发展以及各行业要求的不断提升,薄膜类Al2O3开始受到瞩目,其需求不断增长。选择价廉易得的无机盐AlCl3为铝前驱体,利用其与水共同作用通过ALD技术沉积制备得到的Al2O3薄膜。该方法沉积温度范围广,在50~400 ℃均能得到致密均一的薄膜(通过SEM表征),相应的沉积速率为0.03~ 0.11 nm/次,能够满足各种不同工艺需求。通过XPS对薄膜成分进行分析,经过刻蚀之后,各沉积温度下Al与O的原子百分数之比为2∶(2.89~3.2),与Al2O3十分吻合。所得薄膜杂质总含量小,最低可达1.3%(原子百分数),纯度高。

关键词: Al2O3, 薄膜, 前驱体, ALD

Abstract: With the rapid development of technology and increasingly high requirements of industry,Al2O3 in the form of thin films begin to draw attention with increasing needs.Inorganic AlCl3,which was cheap and easily obtained,was chosen as alu- minum precursor.Al2O3 thin film was obtained by the reaction of AlCl3 with H2O through ALD.Dense and uniform films can be obtained at a wide temperature range(50~40 ℃),and with corresponding deposition rate varying at 0.03~0.11 nm/cycle.This enabled the method in this work to meet various technological requirements.Film components were analyzed by XPS.After etching,atomic percent ratio of Al and O were 2∶(2.89~3.2),which is quite coincident with Al2O3.Total contents of the impurities can be as low as 1.3%(atomic percent ratio),illustrating the high purity of these films.

Key words: aluminum oxide, thin film, precursor, ALD