无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2015, Vol. 47 ›› Issue (7): 32-.

• 论文 • 上一篇    下一篇

低浓度环保型硅酸锂水基防锈液的研究

郑典模1,陈 创1,陈骏驰1,文本华2   

  1. 1.南昌大学环境与化学工程学院,江西南昌 330031;2.江西赣锋锂业股份有限公司
  • 出版日期:2015-07-10 发布日期:2015-09-24

Research on low concentration environmental friendly lithium silicate aqueous protective fluids

Zheng Dianmo1,Chen Chuang1,Chen Junchi1,Wen Benhua2   

  1. 1.School of Environment and Chemical Engineering, Nanchang University,Nanchang 330031,China;
    2.Jiangxi Ganfeng Lithium Co.,Ltd.
  • Published:2015-07-10 Online:2015-09-24

摘要: 金属件通常防锈的手段为镀镍、镀铬等,但由于成本等因素,电镀企业一般会尽量减少镀层厚度,造成镀件防锈性能降低,需借助涂覆防锈剂补充防锈。研究了以低浓度硅酸锂溶液为主,与多种不同的助剂复配,配制低浓度环保型水基防锈液。并采用正交实验确定了防锈液的最佳配比为:硅酸锂浓度为0.012 mol/L,有机酸添加量为0.5 mL/L,有机胺添加量为0.2 g/L,磷酸盐添加量为0.15 g/L,OP-10添加量为0.3 mL/L。在最佳配比条件下,防锈液防锈性能良好,无毒环保,性能稳定,60 d后仍有理想的防锈效果。

关键词: 水基防锈剂, 硅酸锂, 有机酸

Abstract: Metal parts usually prevent rust by means of nickel and chrome plating etc.,but due to cost and other factors, electroplating enterprises will generally try to reduce the thickness of the coating,cause plated parts′rust proof performance decrease,thereby anti rust agent is required to be coated to supplement the antirust performance.A low concentration environmental friendly aqueous rust inhibitor was prepared by taking the low concentration of lithium silicate solution as the main material,to mix with a variety of different types of auxiliary agents.Using the orthogonal method to optimize the process,and the optimum conditions were confirmed as follows: concentration of lithium silicate was 0.012 mol/L,addition amount of organic acid was 0.5 mL/L,addition amount of organic amine 0.2 g/L,amount of phosphate 0.15 g/L,and addition amount of OP-10 0.3 mL/L.Under the best proportion of conditions,aqueous protective fluids had good antirust performance,non-toxic,environmental friendly,and stable,and they still had well rust resistance after 60 d.

Key words: aqueous rust inhibitor, lithium silicate solution, organic acid

中图分类号: