无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (9): 68-.

• 论文 • 上一篇    下一篇

改性拜耳法赤泥两段酸溶法制备 聚合氯化铝铁研究

孟铁宏,李春荣,刘仕云   

  1. 黔南民族医学高等专科学校,贵州都匀 558000
  • 出版日期:2014-09-10 发布日期:2014-09-22

Study on preparation of PAFC from modified Bayer red mud by two stage acid leaching

 MENG  Tie-Hong, LI  Chun-Rong, LIU  Shi-Yun   

  1. Qiannan Medical College for Nationalities,Duyun 558000,China
  • Published:2014-09-10 Online:2014-09-22

摘要: 拜耳法赤泥是拜耳法生产氧化铝所产生的碱性废渣,含有大量未被溶出的铝、铁等金属元素,直接筑坝堆存处理既污染环境又造成资源浪费。以改性拜耳法赤泥为原料,采用两段酸溶法制备高效絮凝剂聚合氯化铝铁(PAFC),并对制备的聚合氯化铝铁进行絮凝性能实验,结果表明絮凝效果良好。该法与传统工艺比较省去了加碱调节盐基度过程,最大程度地利用了盐酸,节约了生产成本。该研究为无机高分子絮凝剂聚合氯化铝铁的制备提供了一套新的工艺流程,为解决拜耳法赤泥筑坝堆存所造成的环境污染和资源浪费问题提供了一条新途径。

关键词: 改性拜耳法赤泥, 两段溶出法, 聚合氯化铝铁

Abstract: The Bayer red mud is alkaline residue from alumina production by Bayer method.It contains a lot of aluminum, iron,and other metal elements which were not leached.It pollutes the environment and wastes resources to deal with dam stockpiling.High efficient flocculant polymeric aluminum ferric chloride(PAFC) was prepared by two the stage acid leaching method with the modified Bayer red mud as raw materials.Flocculation experiment results of PAFC showed that the product had better flocculating effect.Compared with traditional craft the new technique which omitted the process of adding alkali to regulate the basicity,made full use of hydrochloric acid and saved the cost of producing the PAFC.This study of inorganic polymer flocculant PAFC preparation provided a new process to resolve the environmental pollution and resource waste caused by the Bayer red mud damming up.

Key words: modified Bayer red mud, two stage acid leaching, PAFC