无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2014, Vol. 46 ›› Issue (9): 26-.

• 论文 • 上一篇    下一篇

锂云母碱溶法提锂新工艺研究

王 丁,陈 树,刘昕昕,程 斌,季清荣   

  1. 江西省科学院应用化学研究所,江西南昌 330000
  • 出版日期:2014-09-10 发布日期:2014-09-22

New process of lithium extraction from lepidolite by alkali dissolution

 WANG   Ding, CHEN   Shu, LIU  Xin-Xin, CHENG   Bin, JI  Qing-Rong   

  1. Institute of Applied Chemistry,Jiangxi Academy of Science,Nanchang 330000,China
  • Published:2014-09-10 Online:2014-09-22

摘要: 研究了锂云母碱溶法提锂新工艺。通过对碱液浓度、固液比、反应温度、反应时间等因素对锂云母中锂的转化率影响的研究,确立了碱溶法处理锂云母的最佳条件:强碱溶液质量分数为50%,锂云母与强碱液质量体积比(g/mL)为1∶3.5,反应温度为190 ℃,反应时间为4 h。在该条件下锂云母中锂的转化率可以达到98.2%。该方法主要优点:1)锂云母中的锂100%进入溶液;2)可以使提钾、提铯、提铷转化工序一次完成;3)因为是在碱性液体环境下反应,锂云母中的氟不会生成强腐蚀性的氢氟酸腐蚀设备;4)副产品是具有广泛用途的铝硅溶胶,通过铝硅溶胶的直接销售可以大大降低提锂成本。

关键词: 锂云母, 碱溶法, 提取锂

Abstract: The new process of extracting lithium from lepidolite by alkali dissolution was studied.Based on the research for the influences of alkali concentration,solid-liquid ratio,reaction temperature,and reaction time etc.on the conversion rate of lithium in the lepidolite,the optimum conditions for processing lepidolite by alkali dissolution were established,i.e.the mass fraction of alkali was 50%,the solid-liquid ratio(lepidolite powder to alkali solution) was 1∶3.5,the reaction temperature was 190 ℃,and the reaction time was 4 h.The conversion rate of lepidolite was 98.2% under above conditions.The main advantages of this method include:1)The lithium in lepidolite 100% into the solution;2)Extracting lithium/cesium/rubidium from lepidolite can be completed in one operation;3)Do not generate hydrofluoric acid corrosion for equipment due to the environment of alkaline liquid ;4)As the by-product is the wide-applied aluminum-silica sol,through the by-product sales can greatly reduced the cost of extracting lithium.

Key words: lepidolite, alkali dissolution, lithium extraction