无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2011, Vol. 43 ›› Issue (5): 30-.

• 论文 • 上一篇    下一篇

水热法合成碱式硫酸镁晶须

薛建荣1,钟宏2,高俊3,符剑刚2   

  1. 1.湖南科技大学化学与化工学院,湖南湘潭 411201;2.中南大学化学化工学院;3.内蒙古工业大学化工学院
  • 发布日期:2011-05-12

Hydrothermal-controlled synthesis of basic magnesium sulfate whiskers

Xue Jianrong1,Zhong Hong2,Gao Jun3,Fu Jiangang2   

  1. 1.School of Chemistry and Chemical Engineering,Hunan University of Science and Technology,Xiangtan 411201,China;2.School of Chemistry and Chemical Engineering,Central South University;3.School of Chemical Engineering,Inner Mongolia University of Technology
  • Online:2011-05-12

摘要: 以硫酸镁和氢氧化镁为原料,利用水热法制备了碱式硫酸镁晶须,对其制备工艺和表征方法进行了研究。通过实验得到合成晶须产品的适宜水热条件:硫酸镁料浆浓度为1.28 mol/L、硫酸镁和氢氧化镁的物质的量比为1~4、搅拌强度为450 r/min、反应温度为200 ℃、反应时间为6 h。在此条件下合成的碱式硫酸镁晶须的化学式为:MgSO4•5Mg(OH)2•2H2O,平均长度为20~45 μm,长径比在31以上,该产品表面光滑,纤细均匀且无弯曲,纯度较高。

关键词:  , 碱式硫酸镁晶须;水热法;镁盐

Abstract: Basic magnesium sulfate whiskers were synthesized by hydrothermal method with MgSO4 and Mg(OH)2 as raw materials.Preparation process and characterization method were also studied.Experimental results indicated optimum technological conditions for preparing basic magnesium sulfate whiskers were as follows:concentration of MgSO4 was 1.28 mol/L,amount-of-substance ratio of MgSO4 to Mg(OH)2 was 1~4,the stir intensity is 450 r/min,reaction temperature was 200 ℃,and reaction time was 6 h.Results showed that high purity MgSO4•5Mg(OH)2•2H2O whiskers with smooth surface were obtained under those conditions.Furthermore,the product was delicate,uniform and without bending with about 20~45 μm in length and more than 31 in slenderness ratio.

Key words: basic magnesium sulfate whiskers;hydrothermal method; magnesium salt 

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