无机盐工业
主管:中海油天津化工研究设计院有限公司
主办:中海油天津化工研究设计院有限公司
   中海油炼油化工科学研究院(北京)有限公司
   中国化工学会无机酸碱盐专业委员会
ISSN 1006-4990 CN 12-1069/TQ

无机盐工业 ›› 2008, Vol. 0 ›› Issue (1): 0-0.

• •    

锂离子二次电池正极材料锰酸锂的研究进展

李 萍,李 琪,徐宏志,乔庆东,梁 莉   

  • 出版日期:2008-01-10 发布日期:2008-01-10

Research progress on rare earth-doped lithium manganate as cathode material for rechargeable lithium ion batteries

Li Ping,Li Qi,Xu Hongzhi,Qiao Qingdong,Liang Li   

  • Published:2008-01-10 Online:2008-01-10

摘要: <FONT face=Verdana>锂离子电池正极材料锰酸锂的理论比容量较高,但由于多次循环过程中衰减严重,阻碍其商业化应用。综述了近年来其发展状况,总结了尖晶石型锰酸锂正极材料具备比容量较高、原料资源丰富、价格便宜、环境友好等特点,以及各方面应用情况。论述了其结构特点、工作原理、存在缺陷等。着重总结了近期的材料制备方法和稀土掺杂改性研究的进展情况,分类指出了一元稀土掺杂及多元稀土掺杂对材料改性的影响并指出了存在的问题,同时提出了未来的研究方向和发展前景。<BR>中图分类号:TQ131.11&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; 文献标识码:A&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp; 文章编号:1006-4990(2008)01-0001-04<BR></FONT>

Abstract: Lithium manganate (LiMn↓2O↓4) is a kind of cathode material for rechargeable lithium ion batteries,which has very high theoretical specific capacity.But its commercialization was baffled due to its serious specific capacity attenuation during the charge-discharge cycles.Therefore,it is very necessary to do research on its modification.This paper has summarized the development of this material in recent years and summed up its characteristics,such as high specific capacity,abundant raw material resources,low price and small environment pollution etc.as well as its applications in different fields.In addition,the structure features,principle and limitations of LiMn↓2O↓4 were also introduced in this paper.Especially,the recent synthesizing methods of this material and the research progress on its modification by rare earth were summarized emphatically.Moreover,the author classified and pointed out the influences of unitary rare earth-doping and multivariate rare earth-doping on the modification of the material as well as the existing problems.At the same time,the author also put forward the research&nbsp; direction and development prospect in the future. <BR>